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81.
We have created a one- (rather than two-) dimensional quasi-steady-state photorefractive spatial soliton induced by a laser beam instead of an applied electric field. The formation of this type of spatial soliton depends on the intensity of the self-trapped beam, which is different from quasi-steady-state spatial solitons reported in the literature. The optically induced spatial soliton can be exploited in all optical switching applications. 相似文献
82.
83.
纳米材料用于吸收电磁波的物理机制 总被引:1,自引:0,他引:1
本文从物理学的角度分析吸波材料与电磁波作用的影响因素和纳米材料在吸波应用上的微观机制,随着纳米材料和纳米科技的深入发展,纳米吸波材料将以更优异的性能广泛应用于军事装备和民用电磁波防护上. 相似文献
84.
Wenqing Yin Yongcheng Lin Zhigang She L. L. P. Vrijmoed E. B. Gareth Jones 《Chemistry of Natural Compounds》2008,44(1):3-5
A new metabolite xyloketal H (1), was isolated from mangrove fungus Xylaria sp. (No.2508) obtained from the South China Sea. By spectroscopic analyses, primarily 2D NMR methods and X-ray diffraction
experiments, its structure was elucidated.
Published in Khimiya Prirodnykh Soedinenii, No. 1, pp. 5–6, January–February, 2008. 相似文献
85.
Chunyuan Li Weijiang Ding Zhigang She Yongcheng Lin 《Chemistry of Natural Compounds》2008,44(2):163-165
A new biphenyl derivative 3,5′-dihydroxy-4′,5-dimethoxy-2′-methyl-[1,1′-biphenyl]-2-carboxylic acid methyl ester (1), was isolated from the culture broth of a fungus isolated from the rhizosphere soil of mangrove root on the South China
Sea. The structure of 1 was determined by comprehensive spectroscopic methods, primarily 2D NMR techniques.
Published in Khimiya Prirodnykh Soedinenii, No. 2, pp. 128–129, March–April, 2008. 相似文献
86.
Shan She Weimin Xuan Nicola L. Bell Robert Pow Eduard Garrido Ribo Zoe Sinclair De-Liang Long Leroy Cronin 《Chemical science》2021,12(7):2427
The precise control over the formation of complex nanostructures, e.g. polyoxometalates (POMs), at the sub-nanoscale is challenging but critical if non-covalent architectures are to be designed. Combining biologically-evolved systems with inorganic nanostructures could lead to sequence-mediated assembly. Herein, we exploit oligopeptides as multidentate structure-directing ligands via metal-coordination and hydrogen bonded interactions to modulate the self-assembly of POM superstructures. Six oligopeptides (GH, AH, SH, G2H, G4H and G5H) are incorporated into the cavities of Molybdenum Blue (MB) POM nanowheels. It is found that the helicity of the nanowheel can be readily switched (Δ to Λ) by simply altering the N-terminal amino acid on the peptide chain rather than their overall stereochemistry. We also reveal a delicate balance between the Mo-coordination and the hydrogen bonds found within the internal cavity of the inorganic nanowheels which results in the sequence mediated formation of two unprecedented asymmetrical nanowheel frameworks: {Mo122Ce5} and {Mo126Ce4}.Peptide sequence can be used to control the self-assembly and structures of nanoscale molybdenum blue polyoxometalate (POM) wheel-shaped clusters. 相似文献
87.
1,10‐Phenanthroline, a simple and cheap N,N′‐type ligand, was found to work well as the ligand of C? S coupling catalyzed by Cu2O. The corresponding coupling products were synthesized in good to excellent yields (75%–99%) in DMSO at 80°C. A variety of aryl halides and thiols were investigated and satisfactory results were obtained. 相似文献
88.
Nickel and potassium co-medified β-Mo2C catalysts were prepared and used for CO hydrogenation reaction. The major products over β-Mo2C were C1-C4 hydrocarbons, only few alcohols were obtained. Addition of potassium resulted in remarkable selectivity shift from hydrocarbons to alcohols at the expense of CO conversion over β-Mo2C. Moreover, it was found that potassium enhanced the ability of chain propagation with a higher C2+OH production. Modified by nickel, β-Mo-2C showed a relatively high CO conversion, however, the products were similar to those of pure β-Mo2C. When co-modified by nickel and potassium,β-Mo2C exhibited high activity and selectivity towards mixed alcohols synthesis, and also the whole chain propagation to produce alcohols especially for the stage of C1OH to C2OH was remarkably enhanced. It was concluded that the Ni and K had, to some extent, synergistic effect on CO conversion. 相似文献
89.
Changlun Shao Changyun Wang Meiyan Wei Zhenbin Jia Zhigang She Yongcheng Lin 《Chemistry of Natural Compounds》2009,45(6):779-781
Two new benzaldehyde derivatives, 6-ethyl-2-hydroxy-4-methoxy-3-methylbenzaldehyde (1), 6-ethyl-2,4-dihydroxy-3-methylbenzaldehyde (2), together with 2, 4-dihydroxy-3,6-dimethylbenzaldehyde (3) were isolated from mangrove fungus (No. ZZF 32#) from the South China Sea. The structures of compounds 1 and 2 were established by comprehensive analysis of the spectral data, especially 2D NMR spectral results. 相似文献
90.
Fan Liu Qing Li Hong Yang Xiao‐Ling Cai Xue‐Kui Xia Sheng‐Ping Chen Meng‐Feng Li Zhi‐Gang She Yong‐Cheng Lin 《Magnetic resonance in chemistry : MRC》2009,47(5):453-455
Two new natural products, tenelate A ( 1 ) and B ( 2 ), together with the known compound, tenellic acid C ( 3 ), were isolated from the mangrove endophytic fungus Talaromyces sp. (SBE‐14), from the South China Sea. Their structures were elucidated by spectroscopic methods, mainly 1D and 2D NMR techniques. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献