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961.
Jiming Wang Chao Feng Cheng Min Ge Shuhua Zhang Hong Hai 《Journal of Cluster Science》2016,27(6):2001-2011
Two tetranuclear complexes, [M(H3L)]4·X (1, M = Cu, X = 4,4′-dpdo; 2, M = Ni, X = DMF, H5L = 2-[(3,5-dibromo-2-hydroxybenzyl) amino]-2-(hydroxymethyl)propane-1,3-diol, 4,4′-dpdo is 4,4′-bipyridine-N,N′-dioxide, DMF = N,N′-dimethyl formamide), have been synthesized and characterized by elemental analysis, IR and X-ray single-crystal diffraction. Compound 1 features a centrosymmetric tetranuclear copper cluster which further constructed a 1D chain through a tetra-acceptor hydrogen bonds of 4,4′-dpdo molecule. Compound 2 having a P21 /n space group also exhibits a tetranuclear nickel cluster with a cubane topology in which the central Ni(II) ion and oxygen atoms from H3L2? occupy the alternate vertices of the cube. Magnetic properties of 1 and 2 in the 2–300 K have also been discussed. The tetranuclear cubanes cores display dominant ferromagnetic interactions. 相似文献
962.
无色散p-约化KP系列是无色散KP系列的约化形式.基于两个形式劳伦级数,由特殊的附加对称流,无色散p-约化KP系列的弦方程被给出. 相似文献
963.
Zhang Qun Ge Kun Duan Jianlei Chen Shizhu Zhang Ran Zhang Cuimiao Wang Shuxiang Zhang Jinchao 《Journal of nanoparticle research》2014,16(11):1-12
The sintering of a silver (Ag) nanoparticle film by laser beam irradiation was studied using a CW DPSS laser. The laser sintering of the Ag nanoparticle thin film gave a transparent conductive film with a thickness of ca. 10 nm, whereas a thin film sintered by conventional heat treatment using an electronic furnace was an insulator because of the formation of isolated silver grains during the slow heating process. The laser sintering of the Ag nanoparticle thin film gave a unique conductive network structure due to the rapid heating and quenching process caused by laser beam scanning. The influences of the laser sintering conditions such as laser scan speed on the conductivity and the transparency were studied. With the increase of scan speed from 0.50 to 5.00 mm/s, the surface resistivity remarkably decreased from 4.45 × 108 to 6.30 Ω/sq. The addition of copper (Cu) nanoparticles to silver thin film was also studied to improve the homogeneity of the film and the conductivity due to the interaction between the oxidized surface of Cu nanoparticle and a glass substrate. By adding 5 wt% Cu nanoparticles to the Ag thin film, the surface resistivity improved to 2.40 Ω/sq. 相似文献
964.
LIU Ge LU YuanRong YIN XueJun ZHANG XiaoHu DU Heng JIANG PeiYong LI ZhongShan LI XiaoNi HE Yuan WANG Zhi GAO ShuLi YANG YaQing ZHU Kun YAN XueQing CHEN JiaEr YUAN YouJin XIA JiaWen ZHAO HongWei 《中国科学:物理学 力学 天文学(英文版)》2014,57(7):1311-1317
The 53.667 MHz continuous-wave heavy ion RFQ has been designed and manufactured for the SSC-LINAC project.This four-rod RFQ accelerates ions with maximum mass to charge ratio of 7 from 3.728 keV/u to 143 keV/u.Measurements have been carried out to check the RF performance of the cavity and the quality of the electric field.The S11 of the power coupler is adjusted to better than-44 dB,and the Q0 of the cavity is 6440.The quality of the electric field is evaluated by the perturbation method.The measurement procedure and data analysis will be discussed in detail.The error due to gravity of the perturbation bead has been corrected by averaging the fields in different quadrants.As a result,the unflatness of the electric field is±2.5%,and the dipole field component distributes from 0%to 20%in different longitudinal positions,which indicates the asymmetry of the quadrupole field.The unflatness of the quadrupole field distribution represents a good agreement with the simulation results.High power RF test and beam commissioning of the RFQ are on schedule in early 2014. 相似文献
965.
Xinmin Ge Yiren Fan Yingchang Cao Yongjun Xu Xi Liu Yiguo Chen 《Applied magnetic resonance》2014,45(2):155-167
The carbonate reservoir has a number of properties such as multi-type pore space, strong heterogeneity, and complex pore structure, which make the classification of reservoir pore structure extremely difficult. According to nuclear magnetic resonance (NMR) T 2 spectrum characteristics of carbonate rock, an automatic pore structure classification and discrimination method based on the T 2 spectrum decomposition is proposed. The objective function is constructed based on the multi-variate Gaussian distribution properties of the NMR T 2 spectrum. The particle swarm optimization algorithm was used to solve the objective function and get the initial values and then the generalized reduced gradient algorithm was proposed for solving the objective function, which ensured the stability and convergence of the solution. Based on the featured parameters of the Gaussian function such as normalized weights, spectrum peaks and standard deviations, the combinatory spectrum parameters (by multiplying peak value and normalized weight for every peak) are constructed. According to the principle of fuzzy clustering, the carbonate rock pore structure is classified automatically and the discrimination function of each pore structure type is obtained using Fisher discrimination analysis. The classification results were analyzed with the corresponding casting thin section and scanning electron microscopy. The study shows that the type of the pore structure based on the NMR T 2 spectrum decomposition is strongly consistent with other methods, which provides a good basis for the quantitative characterization of the carbonate rock reservoir pore space and lays a foundation of the carbonate rock reservoir classification based on NMR logging. 相似文献
966.
Ruixiang Peng Feng Yang Xinhua Ouyang Ying Liu Yong-Sang Kim Ziyi Ge 《Applied Physics A: Materials Science & Processing》2014,114(2):429-434
TiO2 based inverted polymer solar cells (PSCs) with a structure of fluorine-doped tin oxide (FTO)/TiO2/P3HT:PCBM/PEDOT:PSS/Ag presented excellent air stabilities,; the power conversion efficiency (PCE) of devices exhibited only 15 % decay as compared to the highest value while being exposed in air-condition for more than 20 days. Interestingly, an overall enhancement of PCE from 3.5 % to 3.9 % was observed while the PSCs were exposed in air-condition up to 3 days; the improvement of performance was attributed to the TiO2 films’ oxygen and water protection effect and the oxidation of Ag, which will benefit to form an effective work function match with the HOMO of P3HT leading to improved ohmic contact. However, the performance slowly decreased when the exposure time remains longer due to the physical adsorbed oxygen. UV–ozone treatment on the TiO2 films’ leads to the formation of a metal-deficient oxide that results in a decreased PCE for the devices. Finally, X-ray photo-emission spectroscopy (XPS) was used to analyze the compositional changes of the TiO2 films while they were exposed in air-condition or treated by UV–ozone. 相似文献
967.
Yuan Li Xiaotao Zhu Xiaoyan Zhou Bo Ge Suwen Chen Wangsuo Wu 《Applied Physics A: Materials Science & Processing》2014,115(3):765-770
Compared to superhydrophobic surfaces, superamphiphobic surfaces possess more potential applications but are difficult to fabricate. Herein, to address this problem, we describe a simple method to fabricate a superamphiphobic surface based on a CNTs–SiO2 hybrid material. The CNTs–SiO2 hybrid material obtained by a sol–gel approach was sprayed onto glass slides to form coatings. After surface fluorination, the sprayed coating displayed superamphiphobicity toward water and a number of organic liquids, such as dodecane. It was found that the time of fluorination slightly influenced the surface wettability of the sprayed coating. We also investigated the role of CNTs and SiO2 on superamphiphobicity establishment separately, and such information allowed us to engineer surfaces with specific wettability. 相似文献
968.
Tao Yang Xinxin Fu Qian Zhang Yushuang Cui Changsheng Yuan Weihua Zhang Haixiong Ge Yanfeng Chen 《Applied Physics A: Materials Science & Processing》2014,117(2):909-915
We demonstrated the fabrication of dense hexagonal arrays of Ag nanodots over a large area using a novel nanoimprint-based fabrication technique for surface-enhanced Raman spectroscopy. Flexible imprint molds with sub-10 nm features were duplicated from AAO templates using a novel hybrid mold technique. This method solves the nonflatness-induced defect issue in the conventional thermal nanoimprint technique, and allows high-quality duplications of nanometer features from rigid nonflat templates. Moreover, with the help of the excellent tunability of the size of nanoholes on AAO templates, we were able to tune the size of Ag nanodots, and consequently to tailor the resonance frequency of the Ag nanodot arrays. Finally, surface-enhanced Raman scattering of Rhodamine-123 on Ag nanodot arrays was measured, and large signal enhancement was observed on the 70 nm Ag nanodots. We numerically simulated the optical properties of those Ag nanodot arrays, and excellent agreement was found with the experimental results. 相似文献
969.
970.
制备了二氧化硅壳层修饰的ZnS:Mn量子点,基于聚乙烯吡咯烷酮(PVP)与二氧化硅表面硅羟基的作用,在纳米复合微粒表面进行了PVP的修饰,得到了在海水中荧光性能及胶体稳定性良好的ZnS:Mn/SiO2/PVP 量子点。在Pb2+对所制备纳米微粒具有荧光猝灭效应的基础上,建立了用ZnS:Mn/SiO2/PVP 量子点作为荧光探针检测海水中微量铅离子的新方法。研究表明,量子点浓度为10-3 mol/L时,海水中离子浓度在10~100 μmol/L范围内与ZnS:Mn/SiO2/PVP量子点荧光猝灭强度呈良好的线性关系,相关系数为0.994 6,检出限为8×10-7 mol/L。 相似文献