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81.
Ziqing Duan Xiaofeng Wang Danfeng Yang Xiaoming Pan Pingchu Wang 《Solid State Communications》2005,134(8):559-563
0.65Pb(In1/2Nb1/2)O3-0.35PbTiO3 (PINT65/35) (starting composition) single crystals were grown successfully through the solution Bridgman technique using PbO flux and PMNT67/33 seed crystals. Because of the composition variation, the final composition of achievable crystals is in a range of 0.32-0.34 with the corresponding Tc range of 265-269 °C. The (001) plates of as-grown PINT66/34 single crystals show high Curie temperature (Tc=269 °C) and rhombohedral-tetragonal phase transition temperature (Trt=134 °C). Besides, good electrical properties with high dielectric constant (ε>3000), low dielectric loss (tan δ∼1.2%), high piezoelectric constant (d33∼2000 pC/N) and large electromechanical coupling factor (kt≈59%) at room temperature have been obtained on the (001) plates. The sound velocity, acoustic impedance and other piezoelectric parameters were also measured on the (001) plates in this study, which provide us more detailed information about PINT66/34 single crystals. 相似文献
82.
83.
84.
Xiaoming Wang 《纯数学与应用数学通讯》2004,57(10):1265-1282
We rigorously justify the infinite Prandtl number model of convection as the limit of the Boussinesq approximation to the Rayleigh‐Bénard convection as the Prandtl number approaches infinity. This is a singular limit problem involving an initial layer. © 2003 Wiley Periodicals, Inc. 相似文献
85.
We study an initial boundary value problem for the equations of plane magnetohydrodynamic compressible flows, and prove that
as the shear viscosity goes to zero, global weak solutions converge to a solution of the original equations with zero shear
viscosity. As a by-product, this paper improves the related results obtained by Frid and Shelukhin for the case when the magnetic
effect is neglected.
Supported by NSFC (Grant No. 10301014, 10225105) and the National Basic Research Program (Grant No. 2005CB321700) of China. 相似文献
86.
87.
A novel class of platinum-based initiating systems for the ring-opening polymerization of a wide variety of heterocyclic compounds including epoxides, oxetanes, and 1,3,5-trioxane have been discovered. In addition to a platinum complex as a catalyst, a cocatalyst, consisting of a compound or polymer containing silicon-hydrogen bonds must also be present. This article reports on a preliminary survey of the scope and limitations of these new initiator systems. Particular emphasis in this article has been placed on the ring-opening polymerization of epoxides which have been studied in some detail and which proceed rapidly and exothermically at room temperature. A number of mechanistic studies have been conducted and the best current evidence suggests that polymerization proceeds by a cationic mechanism. Evidence is also presented which suggests that platinum metal colloids may function as the active initiating species. 相似文献
88.
89.
叠层连续开口圆柱壳的精确解 总被引:2,自引:0,他引:2
抛弃任何有关位移和应力模式的假设,引入δ-函数,对正变异性连续开口圆柱壳建立状态方程.给出薄的、中厚的和强厚的叠层连续开口圆柱壳静力问题的统一的精确解.数值结果和SAPS解进行了对比. 相似文献
90.
Kan‐Yi Pu Yi Chen Xiao‐Ying Qi Chun‐Yang Qin Qing‐Quan Chen Hong‐Yu Wang Yun Deng Qu‐Li Fan Yan‐Qin Huang Shu‐Juan Liu Wei Wei Bo Peng Wei Huang 《Journal of polymer science. Part A, Polymer chemistry》2007,45(16):3776-3787
In this contribution, we demonstrate a new effective methodology for constructing highly efficient and durable poly(p‐phenyleneethynylene) (PPE) containing emissive material with nonaggregating and hole‐facilitating properties through the introduction of hole‐transporting blocks into the PPE system as the grafting coils as well as building the energy donor–acceptor architecture between the grafting coils and the PPE backbone. Poly(2‐(carbazol‐9‐yl)ethyl methacrylate) (PCzEMA), herein, is chosen as the hole‐transporting blocks, and incorporated into the PPE system as the grafting coils via atom transfer radical polymerization. The chemical structure of the resultant copolymer, PPE‐g‐PCzEMA, was characterized by NMR and gel permeation chromatography, showing that the desirable copolymer was obtained with the narrow polydispersity. The increased thermal stability of PPE‐g‐PCzEMA was confirmed by thermogravimetric analysis and differential scanning calorimetry along with its macroinitiator. The optoelectronic properties of this copolymer were studied in detail by ultraviolet‐visible absorption, photoluminescence emission and excitation spectra, and cyclic voltammogram (CV). The results indicate that PPE‐g‐PCzEMA exhibits the solid‐state luminescent property dominated by individual lumophores, and also the energy transfer process from the PCzEMA blocks to the PPE backbone with a relatively higher energy transfer efficiency in the solid‐state compared to that of the solution state. Additionally, the hole‐injection property is greatly facilitated due to the presence of PCzEMA, as confirmed by CV profiles. All these data indicate that PPE‐g‐PCzEMA is a good candidate for use in optoelectronic devices. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 3776–3787, 2007 相似文献