铁和锰的化学状态对 LaFexMnyAl12-x-yO19 催化剂上 N2O 分解的影响

 以共沉淀法制备了 LaFexMnyAl12-x-yO19 六铝酸盐催化剂, 并用 X 射线衍射、扫描电镜、N2 吸附-脱附、紫外-可见漫反射光谱和穆斯堡尔谱对催化剂进行了表征, 考察了催化剂上高浓度 N2O 分解反应的性能. 结果表明, 在所考察的条件下, Mn 比 Fe 更有利于促进六铝酸盐晶相的形成. LaFexAl12-xO19 (x = 0.5, 1) 中 Fe 以 Fe3+位于六铝酸盐尖晶石结构中的四面体位和镜面层结构中的三角双锥位, 其中后者为 N2O 分解的主要活性中心. LaMnyAl12-yO19 (y = 0.5, 1) 中 Mn 优先以 Mn2+进入四面体位, 然后以 Mn3+进入尖晶石结构中的八面体位, 并成为 N2O 分解的主要活性中心.     

Mn, Cr-co-doped MgAl2O4 phosphors for white LEDs

The Mn-, Cr-doped and Mn, Cr-co-doped MgAl₂O₄ powders have been synthesized via a gel-solid reaction method. Energy transfer from Mn²⁺ to Cr³⁺ has been observed for the first time in the co-doped MgAl₂O₄ phosphors. When excited with blue light with a wavelength of 450 nm at room temperature, both green emission from Mn²⁺ around 520 nm and red emission from Cr³⁺ around 675and 693 nm were generated. Moreover, the color of the emission can be modified by controlling the doping concentrations of Mn²⁺ and Cr³⁺. Therefore, MgAl₂O₄: Mn²⁺, Cr³⁺ could be used as a single-phased phosphor for white LED with a blue LED chip. The energy transfer in terms of Mn²⁺ to Cr³⁺ is determined by means of radiation and reabsorption.     

60 GHz Radio over Fiber Technology for Wireless Access by employing Narrow-Angle PSK Modulation

This paper investigates two key techniques used in 60 GHz Radio over Fiber (RoF) technology for wireless access, namely, the generation of 60 GHz signals and the distribution of 60 GHz local oscillator (LO). In the proposed model, a 60 GHz PSK signal is generated by a heterodyne of two subcarriers with narrow-angle PSK (NA-PSK) modulation, whose phase shift is equal to one half that of a normal PSK signal. Then we use a 60 GHz mixer to frequency mix two PSK signals in two different bands, 60 GHz and baseband. By doing this, the modulation information can be fully eliminated, resulting in a 60 GHz LO. In the wireless terminal, coherent demodulation is realized by a self-mixing of the transmitted 60 GHz PSK signal and LO. Thus no millimeter-wave (mm-wave) band oscillator is needed in the wireless terminal.     

The electric field modulation by three-dimensional crack on fused silica subsurface

The main factor of laser-induced damage is the modulation to electromagnetic field of laser by the crack on the subsurface. In this paper, a three-dimensional crack model on the exit surface is presented. Three-dimensional finite-difference time-domain (FDTD) method is employed to simulate the electric field intensity distribution in the vicinity of crack on fused silica subsurface. The roles of the crack width, depth, length and the gradient angle in the modulation to the incident light field are analyzed in detail. Results show that the crack size plays an important role in the electric modulation. With the increasing depth and width, the peak value of maximal electric field intensity appears in fused silica. However, the maximal electric field intensity tends to be a constant when the crack length reaches 1 μm. Besides, the enhancement of light intensity becomes obvious when total internal reflection occurs in fused silica. Our calculated results provide an advisable theoretical criterion to the corresponding experiment.     

QCW diode-pumped 654 W AO Q-switched Nd:YAG rod oscillator-amplifier laser

A diode laser-pumped acoustic-optic Q-switched Nd:YAG master-oscillator power amplifier laser is presented. The laser is quasi continuously pumped at 1.1 kHz with a pulse width of 172 μs, and the ultrasonic frequency of the AO Q-switcher is set at a higher value (53 kHz). The master oscillator is designed as a thermally near-unstable-resonator, which presents an average output power of 48 W with a beam quality value of M² = 1.41 and a Q-switching pulse duration of 121 ns. The maximum average power of the MOPA system is 654 W, and the beam quality is M² = 6.     

Mn-Cu合金成分对去合金化法制备纳米多孔铜的影响

 采用电弧熔炼制备出前驱体Mn-Cu合金,在稀盐酸溶液中自由腐蚀去合金化,制备出具有双连续结构的纳米多孔铜。研究了前驱体合金的成分对纳米多孔铜微观结构及Mn的选择性腐蚀程度的影响。结果表明：前驱体Mn-Cu合金的Cu原子分数为43%时,其去合金化受到抑制,存在明显的未完全去合金化的岛状结构;前驱体Mn-Cu合金的Cu原子分数为32%～23%时,可完全去合金化,形成平均孔径尺寸为20～100 nm,平均系带尺寸为30～80 nm,具有双连续结构的纳米多孔铜;前驱体Mn-Cu合金的Cu原子分数低至20%时,去合金化后存在大量裂纹,形成纳米颗粒聚集体。纳米多孔铜中存在少量的残余Mn,残余Mn的原子分数随着前驱体合金Mn原子分数的增高而降低。实验表明腐蚀液浓度对纳米多孔铜形貌也存在影响。     

Resolution enhancement with improved range Doppler algorithm in high numerical aperture OCT

The improved range Doppler algorithm is proposed to abate the trade-off between resolutions and depth of focus in spectral domain optical coherence tomography.By considering the finite beam width and the shape of the wavefronts produced by the Gaussian beam,a physical diffraction model is presented to simulate the light propagation process in the sample.The two-dimensional processing of the spectrum data is decomposed into two one-dimensional processings of Stolt transform and matched filter.Experimental results show that image reconstruction can be achieved.The transverse and axial resolutions are both improved significantly,especially in the out-of-focus range,and the resolutions are almost equivalent throughout the entire region of interest.     

N+2原子受简并双光子作用时的纠缠动力学

研究了N+2（其中N个原子与光场非共振作用,2个原子与光场共振作用）原子受简并双光子作用的纠缠动力学,得到2个共振原子的纠缠度的解析表达式。结果表明：在简并双光子作用下,纠缠度的时间演化出现有规则的崩塌回复现象,并且崩塌回复周期比单光子作用下时要短。此外,N+2原子与光场间的相对耦合系数对简并双光子情形下的纠缠度有更灵敏的影响。     

Co-contributions of the magnetostriction and magnetoresistance to the giant room temperature magnetodielectric response in multiferroic composite thin films

The magnetodielectric properties of BSPT/LSMO multiferroic composite thin films were investigated through the measurement of the frequency dependence of the dielectric constant under different magnetic fields at room temperature. The magnetodielectric (MD) response showed strong frequency dependence: at 100 Hz, the MD response remained negative and the maximum value of ?1.1% was obtained; at 52 kHz, the dielectric constant first decreased and then rose linearly with the magnetic field until the giant room temperature positive MD effect of 9.5% was derived under 7 T. The observed unique MD effects for BSPT/LSMO were attributed to the co-contributions of the magnetostriction and magnetoresistance.     

Laser plasma shockwave cleaning of SiO2 particles on gold film

A Nd:YAG laser (1064 nm) induces optical breakdown of the airborne above the gold-coated K9 glass surface and the created shockwave removes the SiO₂ particles contaminated on the gold films. The laser cleaning efficiency has been characterized by optical microscopy, dark field imaging, ultraviolet-visible-near infrared spectroscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and the Image-pro software. The relationships between removal ratio and particle position and laser gap distance have been studied in the case of single pulse laser cleaning. The results show that the 1064 nm laser induced plasma shockwave can effectively remove the SiO₂ particles. The removal ratio can reach above 90%. The effects of particle position and laser gap distance on the cleaning efficiency are simulated for the single pulse laser cleaning. The simulated results are consistent with the experimental ones.