PPY催化合成乙酸沉香酯

利用吡啶与二氯亚砜反应 ,制成双吡啶盐 ,进而与四氢吡咯反应 ,一步法合成 4 ( 1 四氢吡咯 )吡啶(PPY)。利用PPY为催化剂进行沉香醇的酰化反应 ,并对影响反应的诸因素进行了讨论 ,醇的转化率为 99% ,酯的收率为 88.2 %。     

An X‐shaped π‐conjugated polymer comprising of fluorene units and anthracene units with high efficiency. Synthesis and optical and electrochemical properties

A new X‐shaped π‐conjugated monomer comprising of fluorene units and anthracene units was synthesized, and it was used to fabricate the new X‐shaped π‐conjugated polymers and investigate the properties of the new polymers. Using different molar ratios between such monomer and a fluorene monomer gave three polymers that showed higher absolute PL quantum yields than the linear polyfluorene (PF) in the solid state. After thermal annealing at 200 °C for 4 h, the linear PF showed an additional bathochromic emission at about 550 nm, whereas such red‐shifted emission was fully eliminated for the X‐shaped polymers. The electroluminescent devices based on the X‐shaped polymers with a configuration of ITO/PEDOT:PSS/polymer/LiF/Ca/Al displayed blue emission with low turn‐on voltage and high brightness. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 5616–5625, 2008     

相对平坦模的$\aleph$-积

设$M$是右$R$-模, $\aleph$是一个无穷基数. 称右$R$-模$N$是$\aleph$-$M$-凝聚的,如果对任意的$B/A\hookrightarrow mR$,其中设$M$是右$R$-模, $\aleph$是一个无穷基数. 称右$R$-模$N$是$\aleph$-$M$-凝聚的,如果对任意的$B/A\hookrightarrow mR$,其中设$M$是右$R$-模, $\aleph$是一个无穷基数. 称右$R$-模$N$是$\aleph$-$M$-凝聚的,如果对任意的$B/A\hookrightarrow mR$,其中设$M$是右$R$-模, $\aleph$是一个无穷基数. 称右$R$-模$N$是$\aleph$-$M$-凝聚的,如果对任意的$B/A\hookrightarrow mR$,其中$0\leq A相似文献   

The steady Navier–Stokes/energy system with temperature‐dependent viscosity—Part 1: Analysis of the continuous problem

In this first part we propose and analyse a model for the study of two‐dimensional incompressible Navier–Stokes equations with a temperature‐dependent viscosity. The flow is supposed in a mixed convection regime and considers an outflow region, leading to a strongly coupled problem between the Navier–Stokes and energy equations, which will be justified theoretically. The coupling in the continuous problem is treated by an outer temperature fixed point strategy. Existence results for a particular variational formulation follows from this study. Further, a particular uniqueness result for small data is also obtained. Copyright © 2007 John Wiley & Sons, Ltd.     

Ytterbium triflate hydrate catalyzed Michael addition and cyclocondensation of α,β-unsaturated ketones with active methylene compounds

Catalyzed by ytterbium(Ⅲ) triflate hydrate [Yb(OTf)3.xH2O], the Michael addition and cycloeondensation of α,β-unsaturated ketones with active methylene compounds to afford the 1,4-adducts and benzo[b]pyran derivatives, respectively were studied.     

Toughening effect of ethylene‐vinyl acetate rubber on nylon 1010 compatibilized by maleated ethylene‐vinyl acetate copolymers

The toughening effect of ethylene‐vinyl acetate rubbers (EVM) with maleated ethylene‐vinyl acetate copolymers (EVA‐g‐MAH) on the nylon 1010 was investigated. The addition of 5 phr (per hundred nylon 1010) EVM increased the elongation at break of nylon 1010 to a great extent. The notched Izod impact strength of nylon/EVM blends increased with increasing EVM content. Scanning electron microscope showed that the EVM particle size was around 0.5 μm when the EVM content was 5 phr and increased with increasing EVM content. After the addition of EVA‐g‐MAH to nylon/EVM (100/20) blend, the average diameter of EVM particles decreased from more than 1 μm to 0.5–0.6 μm. EVA‐g‐MAH could improve the adhesion between nylon 1010 and EVM. A sharp brittle‐ductile transition (BDT) was observed when the interparticle distance was about 0.2 μm, independent of the addition of EVA‐g‐MAH. The notched Izod impact strength of nylon/EVM blends at low temperatures was measured and the BDT shifted toward low temperatures with increasing EVM or EVA‐g‐MAH content. © 2009 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 47: 434–444, 2009