全文获取类型
收费全文 | 109207篇 |
免费 | 6200篇 |
国内免费 | 4028篇 |
专业分类
化学 | 47595篇 |
晶体学 | 1092篇 |
力学 | 8362篇 |
综合类 | 229篇 |
数学 | 35235篇 |
物理学 | 26922篇 |
出版年
2024年 | 110篇 |
2023年 | 689篇 |
2022年 | 1190篇 |
2021年 | 1224篇 |
2020年 | 1369篇 |
2019年 | 1453篇 |
2018年 | 11400篇 |
2017年 | 11000篇 |
2016年 | 7601篇 |
2015年 | 2462篇 |
2014年 | 2224篇 |
2013年 | 2734篇 |
2012年 | 6687篇 |
2011年 | 13236篇 |
2010年 | 7554篇 |
2009年 | 7832篇 |
2008年 | 8580篇 |
2007年 | 10478篇 |
2006年 | 1897篇 |
2005年 | 2716篇 |
2004年 | 2672篇 |
2003年 | 2927篇 |
2002年 | 2105篇 |
2001年 | 1189篇 |
2000年 | 935篇 |
1999年 | 867篇 |
1998年 | 658篇 |
1997年 | 598篇 |
1996年 | 618篇 |
1995年 | 487篇 |
1994年 | 365篇 |
1993年 | 378篇 |
1992年 | 278篇 |
1991年 | 309篇 |
1990年 | 254篇 |
1989年 | 198篇 |
1988年 | 181篇 |
1987年 | 149篇 |
1986年 | 151篇 |
1985年 | 122篇 |
1984年 | 117篇 |
1983年 | 74篇 |
1982年 | 75篇 |
1981年 | 63篇 |
1980年 | 73篇 |
1979年 | 56篇 |
1978年 | 47篇 |
1914年 | 45篇 |
1909年 | 41篇 |
1908年 | 40篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
Myocardial infarction results from the rupture of an atherosclerotic plaque, which occurs in response to both mechanical stress
and inflammatory processes. In order experimentally observe flow into atherosclerotic coronary artery morphologies, a novel
technique for molding realistic compliant phantom featuring injection-molded inclusions and multiple layers has been developed.
This transparent phantom allows for particle image velocimetry (PIV) flow analysis and can supply experimental data to validate
computational fluid dynamics algorithms and hypothesis. 相似文献
92.
A new optical technique based on real time holographic interferometry in true colors has been implemented around the transonic
wind tunnel of the ONERA-Lille center to analyze 2D unsteady wake flows. Tests realized in color interferometry, real time
and double exposure, use simultaneously three wavelengths of a continuous waves laser (argon and krypton mixed) and holograms
are recorded on silver-halide single-layer panchromatic Slavich PFG03c plates. The very principle of real-time true color
holographic interferometry uses three primary wavelengths (red, green and blue) to record, under no-flow conditions, the interference
among the three measurement beams and the three reference beams simultaneously on a single reference hologram. After the holographic
plate is developed, it is placed on the test setup again in the position it occupied during exposure and the hologram is illuminated
again by the three reference beams and three measurement beams. A flat, uniform color can then be observed behind the hologram.
So a horizontal, vertical, or even circular fringe pattern can be formed and the achromatic central fringe can be made out
very clearly. The single color is used to determine the path difference zero on the interferograms. The flow studied was the
unsteady flow downstream of a cylinder placed crosswise in the test section. A sequence of hundred interferograms was recorded
on the flow around the cylinder at Mach 0.37. The vortex formation and dissipation phases can be seen very clearly, along
with the fringe beat to either side of the cylinder. 相似文献
93.
Hongchao Li Yufeng Hu Yanguang Zhang Dongge Ma Lixiang Wang Xiabin Jing Fosong Wang 《Journal of polymer science. Part A, Polymer chemistry》2004,42(16):3947-3953
A conjugated poly(p‐CN‐phenylenevinylene) (PCNPV) containing both electron‐donating triphenylamine units and electron‐withdrawing cyano groups was prepared via Knoevenagel condensation in a good yield. Gel permeation chromatography suggested that the soluble polymer had a very high weight‐average molecular weight of 309,000. A bright and saturated red emission was observed under UV excitation in solution and film. Cyclic voltammetry showed that the polymer presented quasi‐reversible oxidation with a relatively low potential because of the triphenylamine unit. A single‐layer indium tin oxide/PCNPV/Mg–Ag device emitted a bright red light (633 nm). © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3947–3953, 2004 相似文献
94.
The reversible nonlinear conduction (RNC) in of high‐density polyethylene/acetylene carbon black composites with different degrees of crosslinking was studied above room temperature and below the melting point of high‐density polyethylene (HDPE). The experimental current density‐electric field strength curves can be overlapped onto a master curve, suggesting that the microscopic mechanisms for the appearance of RNC exist regardless of the ambient temperature and the crosslinking degree of the HDPE matrix. The relationship between the crossover current density and the linear conductivity can be explained in the framework of the dynamic random‐resistor‐network model. According to these results, two electron‐tunneling models are suggested to interpret the microscopic conduction behavior. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1212–1217, 2004 相似文献
95.
A new method for the synthesis of exfoliated graphite and polyaniline (PANI)/graphite nanocomposites was developed. Exfoliated graphite nanosheets were prepared through the microwave irradiation and sonication of synthesized expandable graphite. The nanocomposites were fabricated via the in situ polymerization of the monomer at the presence of graphite nanosheets. The as-synthesized graphite nanosheets and PANI/graphite nanocomposite materials were characterized with Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, and thermogravimetric analysis (TGA). The conductivity of the PANI/graphite nanocomposites was dramatically increased over that of pure PANI. TGA indicated that the incorporation of graphite greatly improved the thermal stability of PANI. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1972–1978, 2004 相似文献
96.
Xiao Xiaohua Cao Yuguan Liu Xia Jiang Shengxiang 《Journal of inclusion phenomena and macrocyclic chemistry》2004,48(3-4):111-115
A PM3 calculation in vacuum of the inclusion complexation ofo-, m-, p-nitro-phenol with calix[n]arenes is performedsuccessfully. The pathways for inclusion process are describedand the most probable structures of the 1:1 complex are soughtthrough a potential energy scan. The energy differences betweenthe inclusion complexes and the hosts, by calculation, show thatthe most stable complexation is calix[4]-p-nitro phenol andcalix[6]-m-nitro phenol. 相似文献
97.
Xiao‐Dong Pan 《Journal of Polymer Science.Polymer Physics》2004,42(13):2467-2478
For properly chosen elastomer compounds, thermorheological characterization is combined with an examination of the variation of the wet sliding friction with temperature. A conceptual argument leads to the assumption that the wet sliding friction should maximize at the energy dissipation peak associated with the dynamic softening transition at a characteristic frequency determined by the sliding speed and the effective smallest surface asperity scale. The dynamic softening transition is characterized with the peak in tan δ/G′n, where tan δ is the loss tangent, G′ is the elastic modulus, and n is a constant between 0 and 1. The William–Landel–Ferry transform is uncritically applied for extrapolating the position of the peak in tan δ/G′n at high frequencies. Even based on the criterion of tan δ, the results obtained on a concrete surface indicate that the effective smallest asperity scale is of order of 100 μm. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 2467–2478, 2004 相似文献
98.
Chunxia Zhao Guowang Xu Xianzhe Shi Jianmei Ma Yan Zhang Shen Lv Qianfeng Weng Qing Yang 《Analytical sciences》2004,20(7):1001-1005
Fluorescent-based single-strand conformation polymorphism (F-SSCP) analysis with capillary electrophoresis (CE) is the most common method for the detection of mutation because of its high sensitivity and resolution. In this study, we prepared an inexpensive linear polyacrylamide (LPA), and successfully applied it to CE-SSCP analysis and tandem CE-SSCP/heteroduplex analysis (HA) of the P53 gene on an ABI capillary genetic analyzer. A comparison of the sieving capabilities of a homemade LPA and commercial polydimethylacrylamide (PDMA) demonstrates that the homemade LPA has a higher resolution, a shorter analysis time, and is more suitable for tandem SSCP/HA than commercial PDMA. To show the usefulness, mutations of P53 gene exon 7 - 8 in 37 tumor samples were investigated by using homemade LPA. The results indicate that 10 mutations were found in 9 of 37 cases; the majority of P53 mutations were missense mutations, and 70% were located in exon 7, which plays an important role in neoplastic progression in human tumorigenesis. 相似文献
99.
NianYuanTAN XiaoMingXIAO ZeLinLI TakekoMATSUMURA-INOUE 《中国化学快报》2004,15(6):687-690
A new cobalt(Ⅱ) complex with tridentate ligand 2, 6-bis (benzimidazol-2-yl)pyridine has been synthesized by microwave irradiation method and characterized by elemental analysis,electrochemical and spectral methods. The binding of the complex with calf thymus DNA has also been investigated by absorption and fluorescence spectra. 相似文献
100.
Ri Cheng XUAN* Wei Xiao HU Zhong Yu YANG Ya Ping LU College of Pharmaceutical Sciences Zhejiang University of Technology Hangzhou 《中国化学快报》2004,(2)
2-Chloro-5-methylpyridine is an important intermediate for the preparation of biological active compounds, especially insecticides1, e.g. imidacloprid2, and is usually manufac- tured from 3-methylpyridine N-oxide. However, the manufacturing process also forms the by-products: 3-methylpyridine and its isomer 2-chloro-3-methylpyridine3. The pro- perties of the isomers are similar, it is difficult to separate by ordinary methods, such as distillation. Scheme 1 79.4%13.6%5.2%NClCH3NCH3ClNC… 相似文献