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991.
992.
Chen H Fan B Petitjean M Panaye A Doucet JP Li F Xia H Yuan S 《European journal of mass spectrometry (Chichester, England)》2003,9(5):445-457
The use of the mass spectral simulation system, MASSIS, is reported and its performance has been evaluated. The search for substructures matching with fragments stored in four pivot databases was realised using the Ullmann algorithm. Special cleavage rules, such as the McLafferty rearrangement, the retro-Diels-Alder reaction, elimination of a neutral small molecule and oxygen migration, are processed through shortest path and depth-first search algorithms. For a search in the database of small fragments, the key step is to determine the tautomeric fragments; then a match can be obtained using a subgraph isomorphism algorithm. A string match is used to determine peak intensity. If the limited environment of an atom is the same as that found in the database of relationships between fragment and intensity, this intensity value is assigned to the query atom. Performance in a set of tests is very important in evaluating the system performance. A comparison of peaks with an intensity greater than 5% (relative) shows that our system has a very high performance figure (> 90% ) for routine organic compounds. 相似文献
993.
Chen H Fan B Xia H Petitjean M Yuan S Panaye A Doucet JP 《European journal of mass spectrometry (Chichester, England)》2003,9(3):175-186
A mass spectrum simulation system was developed. The simulated spectrum for a given target structure is computed based on the cleavage knowledge and statistical rules established and stocked in pivot databases: cleavage rule knowledge, function groups, small fragments and fragment-intensity relationships. These databases were constructed from correlation charts and statistical analysis of large population of organic mass spectra using data mining techniques. Since 1980, several systems were proposed for mass spectrum simulation, but in present there is no any commercial software available. This shows the complexity and difficulties in the development of a such system. The reported mass spectral simulation system in this paper could be the first general software for organic chemistry use 相似文献
994.
We report on the use of NMR micro-imaging to observe flow within a tubeless siphon. The flow is maintained in a visco-elastic liquid of high extensional viscosity, namely 0.5% w/v 8 million Dalton polyethylene oxide in water. The velocity profiles reveal a significant velocity gradient in the vertical direction as well as a transition from near-Poiseuille flow at the pipe entrance to plug flow far from the pipe entrance towards the base of the tubeless siphon. 相似文献
995.
The structure of XLPE and the distribution of space charge 总被引:1,自引:0,他引:1
The formation and accumulation of space charge under charge treatment are investigated using PWP method. The interaction between space charge and the structure of XLPE is measured using infrared spectroscopy (IR) method. The related mechanism about space charge distribution and the structure of XLPE are discussed. 相似文献
996.
Jingbo Xia 《Proceedings of the American Mathematical Society》2003,131(8):2505-2514
For an analytic function which maps the open unit disc to itself, let be the operator of composition with on the Bergman space . It has been a longstanding problem to determine whether or not the membership of in the Schatten class , , is equivalent to the condition that the function has a finite integral with respect to the Möbius-invariant measure on . We show that the answer is negative when .
997.
In this paper, we obtain some rigidity theorems for compact Riemannian manifolds Ω with boundary M and nonnegative Ricci curvature; for instance, we prove that the existence of certain functions on M together with a lower bound c > 0 on the principal curvtures of M imply that Ω is an euclidean ball of radius $ {1\over c} $ . 相似文献
998.
Like the closing lemma, the connecting lemma is of fundamental importance in dynamical systems. Hayashi recently proved the connecting lemma for stable and unstable manifolds of a hyperbolic invariant set. In this paper, we prove several very general connecting lemmas. We simplify Hayashi's proof and extend the results to more general cases.
999.
Tong GL Varner GS Wang F Wang LS Wang LZ Wang M Wang P Wang PL Wang SM Wang TJ Wang YY Wei CL Wu N Wu YG Xi DM Xia XM Xie PP Xie Y Xie YH Xu GF Xue ST Yan J Yan WG Yang CM Yang CY Yang HX 《Physical review letters》2000,84(4):594-597
Using the upgraded Beijing Spectrometer, we have measured the total cross section for e(+)e(-) annihilation into hadronic final states at center-of-mass energies of 2.6, 3.2, 3.4, 3.55, 4.6, and 5.0 GeV. Values of R, sigma(e(+)e(-)-->hadrons)/sigma(e(+)e(-)-->&mgr;(+)&mgr;(-)), are determined. 相似文献
1000.
Xia Y Kong X Smith DK Liu Y Man D Zhu G 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2000,143(2):407-410
Previous theoretical calculations have demonstrated that the multiquantum relaxation rate of (1)H(alpha)-(13)C(alpha)(R(MQ)) is, on average, 1.3 +/- 0.4 or 1.7 +/- 0.6 times slower than the single-quantum relaxation rate of (13)C(alpha)(R(C)) for a sample with or without, respectively, amide protons. By taking advantage of this fact and by using the PEP sensitivity enhancement scheme, an HMQC version of the HCACO experiment has been developed. We demonstrate that this new experiment is 23 and 55% more sensitive than the original HSQC version of the HCACO experiment, at constant times of 7 and 27 ms, respectively, for a sample of the BC domain of the ciliary neurotrophic factor receptor protein dissolved in D(2)O at 20 degrees C. 相似文献