全文获取类型
收费全文 | 9297篇 |
免费 | 1533篇 |
国内免费 | 1253篇 |
专业分类
化学 | 6854篇 |
晶体学 | 146篇 |
力学 | 408篇 |
综合类 | 107篇 |
数学 | 1069篇 |
物理学 | 3499篇 |
出版年
2024年 | 37篇 |
2023年 | 153篇 |
2022年 | 322篇 |
2021年 | 331篇 |
2020年 | 356篇 |
2019年 | 428篇 |
2018年 | 305篇 |
2017年 | 302篇 |
2016年 | 420篇 |
2015年 | 494篇 |
2014年 | 594篇 |
2013年 | 716篇 |
2012年 | 881篇 |
2011年 | 860篇 |
2010年 | 671篇 |
2009年 | 663篇 |
2008年 | 718篇 |
2007年 | 633篇 |
2006年 | 549篇 |
2005年 | 422篇 |
2004年 | 374篇 |
2003年 | 274篇 |
2002年 | 252篇 |
2001年 | 200篇 |
2000年 | 141篇 |
1999年 | 147篇 |
1998年 | 109篇 |
1997年 | 91篇 |
1996年 | 107篇 |
1995年 | 97篇 |
1994年 | 76篇 |
1993年 | 67篇 |
1992年 | 59篇 |
1991年 | 43篇 |
1990年 | 39篇 |
1989年 | 25篇 |
1988年 | 32篇 |
1987年 | 19篇 |
1986年 | 19篇 |
1985年 | 24篇 |
1984年 | 9篇 |
1983年 | 9篇 |
1982年 | 3篇 |
1981年 | 5篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1959年 | 1篇 |
1957年 | 1篇 |
1936年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
911.
Youjun He Yi Zhou Guangjin Zhao Jie Min Xia Guo Bo Zhang Maojie Zhang Jing Zhang Yongfang Li Fengling Zhang Olle Inganäs 《Journal of polymer science. Part A, Polymer chemistry》2010,48(8):1822-1829
A new benzodithiophene (BDT)‐based polymer, poly(4,8‐bis(2‐ethylhexyloxy)benzo[1,2‐b:4,5‐b′]dithiophene vinylene) (PBDTV), was synthesized by Pd‐catalyzed Stille‐coupling method. The polymer is soluble in common organic solvents and possesses high thermal stability. PBDTV film shows a broad absorption band covering from 350 nm to 618 nm, strong photoluminescence peaked at 545 nm and high hole mobility of 4.84 × 10?3 cm2/Vs. Photovoltaic properties of PBDTV were studied by fabricating the polymer solar cells based on PBDTV as donor and PC70BM as acceptor. With the weight ratio of PBDTV: PC70BM of 1:4 and the active layer thickness of 65 nm, the power conversion efficiency of the device reached 2.63% with Voc = 0.71 V, Isc = 6.46 mA/cm2, and FF = 0.57 under the illumination of AM1.5, 100 mW/cm2. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1822–1829, 2010 相似文献
912.
Pheophorbide a (Pa) from Chinese herbal medicine Scutellaria Barbata and Silkworm excreta has been proved to be potential photosensitizer. The present study investigated the cytotoxicity of ovarian cancer cells
induced by LED-activated Pa using light microscopy with the SRB staining. We further investigated the apoptosis of the cells
6 h after LED-activated Pa using of the flow cytometer with PI staining and nuclear staining. The results showed that LED-activated
Pa remarkably caused cell death of ovarian cancer cells. The condensation of chromatin, nuclear fragmentations, and 12.3%
of cells containing subdiploid levels of DNA were found in the ovarian cancer cells after the treatment of LED-activated Pa.
These data demonstrated that LED-activated Pa could cause significant cytotoxicity and apoptosis of ovarian cancer cells. 相似文献
913.
914.
Pure aluminum films were deposited on B270 glass by electron beam evaporation technique. The aluminum films, which were used as anode, were placed in phosphoric acid to prepare porous alumina films using a two-step anodization method. They were subsequently annealed in high temperature to improve transmission. The microstructure, transmitted spectrum and laser damage characteristics of the alumina films were then tested. Their microstructure formed in phosphoric acid was retiform. The transmissivity can be increased efficiently if the annealing temperature is adequately high. The laser-damaged spots of the porous films were formed by innumerable small damaged pits with no mutual effect. In contrast, the laser-damaged spots of the compact films were formed by several larger damaged pits which acted together toward expansion. The damage process of the porous films comprised heat ablation and stress fracture. 相似文献
915.
Feldspar thermoluminescence fading phenomena were investigated here by using newly-constructed thermoluminescence spectrometer
on the basis of charge-coupled detector, and thereafter the discussion and explanation on feldspar TL fading mechanism were
presented. The experimental results show that the fading rate of feldspar TL depends on both wavelength and stimulated temperature,
and normally the feldspar TL in every region of wavelength and temperature shows different traits, namely the low temperature
TL (170°–190°) fading at the rate of logarithmic function and furthermore the TL of different wavelengths fading at approximately
the same rate on the condition of 160° preheating. While the medium and high temperature TLs (290°–400°) do not show much
thermal fading, their fading rate at room temperature invariably correlates well with their wavelength, namely the longer
TL wavelength, the slower TL fading rate. The thermal instability of traps and the quantum-mechanical tunneling effects can
explain the above fading phenomena respectively. It is recognized that feldspar TL fading depends on its wavelength, and furthermore
new aspects of the solid thermoluminescence process can be displayed by the combination of three-dimensional TL spectral analysis
and thermal fading or anomalous fading of TL for feldspar.
Supported by the National Natural Science Foundation of China (Grant No. 40534019) and the Knowledge Innovation Program of
the Chinese Academy of Sciences (Grant No. GIGCX3-07-10) 相似文献
916.
A new method to protect the copyright of digital museum based on digital holography is proposed. The Fresnel hologram of watermark image is embedded in the object to be protected through discrete wavelet transform (DWT). After the watermark detection, the copyright information appears in the reconstructed hologram. With the higher redundancy feature in the hologram, the proposed technique can actually survive several kinds of image processing. Experimental results prove that the presented method has good robustness in image protection. 相似文献
917.
Liu R Yang J Wu X Sun C 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2002,58(3):457-465
The interaction of berberine with nucleic acid in the presence of cetyltrimethylammonium bromide (CTMAB) in aqueous solution has been studied by spectrophotometry and resonance light scattering (RLS) spectroscopy. At pH 7.30, the RLS signals of berberine were greatly enhanced by nucleic acid in the region of 300-600 nm characterized by four peaks at 324.0, 386.5, 416.5 and 465.0 nm. The binding properties were examined by using a Scatchard plot based on the measurement of enhanced RLS data at 416.5 nm. Under optimum conditions, the increase of RLS intensity of this system at 416.5 nm is proportional to the concentration of nucleic acid. The linear range is 7.5 x 10(-9)-7.5 x 10(-5) g ml(-1) for calf thymus DNA, 7.5 x 10(-9)-2.5 x 10(-5) g ml(-1) for herring sperm DNA, and 5.0 x 10(-9)-2.5 x 10(-5) g ml(-1) for yeast RNA. The detection limits (S/N = 3) are 2.1 ng ml(-1) for calf thymus DNA, 6.5 ng ml(-1) for herring sperm DNA and 3.5 ng ml(-1) for yeast RNA, respectively. Three synthetic samples were analyzed satisfactorily. 相似文献
918.
Mid-infrared pulses generated from the mixing output of an amplified, dual-wavelength Ti:sapphire system 总被引:2,自引:0,他引:2
We demonstrate the generation of femtosecond mid-infrared pulses by direct difference-frequency mixing in a AgGaS(2) crystal of two intense pulses from a dual-wavelength oscillator that have been simultaneously amplified in a single regenerative amplifier. A pulse energy of as much as 1.6 muJ was achieved at wavelengths of 9-11 mum. 相似文献
919.
Robert C. Moore Marian Borkowski Michael G. Bronikowski Jianfeng Chen Oleg S. Pokrovsky Yuanxian Xia Gregory R. Choppin 《Journal of solution chemistry》1999,28(5):521-531
The stability constants of NpO
2
+
, UO
2
2+
Am3+, and Th4+ with acetate and lactate anions has been measured in 0.3–5.0m NaCl media at 25°C by the solvent extraction technique. For the 1:1 complexation, the values of the stability constants increased in the order: NpO
2
+
< Am3+ <
2
2+
< Th4+, in accordance with the actinide charge density and reflecting the strongly ionic bonding of the complexes. The Pitzer ionic interaction parameters were calculated and used to estimate the thermodynamic stability constants at I = 0. Because our data were collected mainly in the high ionic strength region values of (1) were estimated from values reported in the literature. For all stability constants the Pitzer model gives an excellent representation of the data using three interaction parameters (0), (1), and COn leave from Institute of 相似文献
920.
系统地研究了Gd掺杂对Bi2Sr2Ca1-xGdxCu2Oy单晶超导电性及各向异性电阻率的影响.Tc满足Tc/Tc,max=1-82.6(ax+b)2,并随Gd含量的增加而下降,这是由于Gd掺杂引起载流子浓度减小所导致.在x≥0.19时,ρab(T)在Tc附近有类半导体行为,dρab/dT随Gd含量增大而增大.ρc(T)呈半导体行为,并可用唯象公式ρc(T)=(a/T)exp(Δ/T)+bT+c加以描述.电阻率各向异性ρc/ρab随掺杂浓度增大而增大. 相似文献