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991.
Polypropylene/poly(butyl methacrylate)(PP/PBMA) blends were prepared by diffusion and subsequent polymerization of butyl methacrylate(BMA) in commercial isotactic polypropylene(iPP) pellets.The diffusion kinetics,diametrical distribution of PBMA in a pellet and phase morphology of a typical PP/PBMA blend were investigated. 相似文献
992.
Chang‐xi Wang Jia‐li Li Xue‐ding Wang Long‐shan Liu Xiao Chen Min Huang 《Biomedical chromatography : BMC》2010,24(4):399-405
A liquid chromatography/tandem mass spectrometry (LC‐MS/MS) method was developed and validated for determining tacrolimus (FK506) in rat tissues to study the effect of Schisandra sphenanthera extract on FK506 tissue distribution. After a liquid–liquid extraction with ethyl acetate, FK506 and ascomycin (IS) were subjected to LC‐MS/MS analysis using positive electrospray ionization under multiple reactions monitoring mode. Chromatographic separation of FK506 and ascomycin was achieved on a Hypersil BDS C18 column with a mobile phase consisting of methanol‐water (containing 2 mM ammonium acetate, 95 : 5, v/v). The intra‐ and inter‐batch precision of the method were less than 8.8 and 9.8%, respectively. The intra‐ and inter‐batch accuracies ranged from 97.5 to 104.0%. The lowest limit of quantification for FK506 was 0.5 ng/mL. The method was applied to a FK506 tissue distribution study with or without a dose of Wuzhi (WZ) tablet. Most of the FK506 tissue concentrations were slightly increased after a concomitant WZ tablet dose, but the whole blood concentration of FK506 was dramatically increased 3‐fold after a concomitant WZ tablet dose. These results indicated that the LC‐MS/MS method was rapid and sensitive enough to quantify FK506 in different rat tissues, and strict drug monitoring is recommended when co‐administering WZ tablet in clinical use. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
993.
994.
丙烯酰胺与丙烯酸十四酯共聚物的合成及性能研究 总被引:6,自引:0,他引:6
利用过氧化苯甲酰为引发剂探讨了丙烯酰胺(AM)和丙烯酸十四酯(TA)的自由基共聚合。重点讨论了合成条件如引发剂用量,单体配比、溶剂、温度等对共聚反应及共聚物对苯丙乳胶增稠性能的影响。并用IR和凯达定氮法表征了共聚物的组成,实验结果表明,AMt TA进行沉淀聚合所得到的共物分子量足够大,可以作为疏水缔合型稠剂使用。 相似文献
995.
996.
SlflsltlC!fi10,dn8VOflOI!gflsfl.W3SISOhtCdnOffiSlhQltICtiffiIC3VCSsfldhdIflhibltOYy卜388cellactlvltyl.巨histypeofnaturalproductshaveshownvariousbloactlvltyandreceivedconsiderableattentionfromsyntheticchemlstsy.Wewishtoreportastereoselectlvetotalsynthesisofslnaltlclnfromreadilyavailablestartingmaterials(land4).OursyntheticdesignIsbaseduponconstructionofthesubstitutedbenzouioxanering,to!lowedbyformationof*theX**flavanonolmoietyFromSchemel,wecansee!natInnilssynthesisofs… 相似文献
997.
998.
Heat-transfer characteristics of climbing film evaporation were experimentally investigated on a vertical climbing film evaporator heated by tube-outside hot water. The experimental setup was designed for determining the effect of the height of feed water inside a vertical tube and the range of temperature difference on local heat transfer coefficient inside a vertical tube (hi). In this setup, the height of feed water was successfully controlled and the polypropylene shell effectively impedes the heat loss to the ground. The results indicated that a reduction in the height of feed water contributed to a significant increase in hi if no dry patches around the wall of the heated tube appeared inside the tube. The height ratio of feed water Rh = 0.3 was proposed as the optimal one as dry patches destroyed the continuous climbing film when Rh is under 0.3. It was found that the minimum temperature difference driving climbing film evaporation is suggested as 5 °C due to a sharp reduction in hi for temperature difference below 5 °C. The experiment also showed that hi increased with an increase in temperature difference, which proved the superiority of climbing film evaporation in utilizing low-grade surplus heating source due to its wide range of driving temperature difference. The experimental results were compared with the previous literature and demonstrated a satisfactory agreement. 相似文献
999.
A New Capillary Electrophoresis Apparatus with Piezoelectric Ceramics High Voltage Source and Amperometric Detector 总被引:13,自引:0,他引:13
Zuan Guang CHENI Jin Yuan MO Xiao Yun YANG Li Shi WANG Xue Ting MEIZ Min Sheng ZHANGI 《中国化学快报》1999,(3)
IntroductionHighperformancecapiliar}'electrophoresis(HPCE)isanewanalyticaltechnology'rapidly'developedinrecentyears.Withtheadvantagesofsmallsample.highsensitivity,highresolution.rapidanalysisandverycheaprunning,ithasbeenappliedinchemistry'.lifescienc... 相似文献
1000.
ZHANG Feng zhang ** XU Liang shu HUANG He qing LONG Min nan QIU Xue hui CHEN Zhong 《高等学校化学研究》1999,(3)
IntroductionNitrogenasefromavarietyofN2-fixingorganismsiscomposedoftwo-componentprotein,MoFe-proteinandFe-protein.Fe-proteincontainsasingleFe4S4-cluster,whichhasthefunctionoftransferingelectronsfromdonortoMoFe-protein.MoFe-proteincontainsP-clusterpai… 相似文献