Bipyridinophane‐containing conjugated polymers modulated with an intramolecular aromatic C?H/π interaction

Bipyridinophane–fluorene conjugated copolymers have been synthesized via Suzuki and Heck coupling reactions from 5,8‐dibromo‐2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane and suitable fluorene precursors. Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P7 ) exhibits large absorption and emission redshifts of 20 and 34 nm, respectively, with respect to its planar reference polymer Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐1,4‐(2,5‐dimethylbenzene)] ( P11 ), which bears the same polymer backbone as P7 . These spectral shifts originate from intramolecular aromatic C? H/π interactions, which are evidenced by ultraviolet–visible and ¹H NMR spectra as well as X‐ray single‐crystal structural analysis. However, the effect of the intramolecular aromatic C? H/π interactions on the spectral shift in poly[9,9‐dihexylfluorene‐2,7‐yleneethynylene‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P10 ) is much weaker. Most interestingly, the quenching behaviors of these two conjugated polymers are largely dependent on the polymer backbone. For example, the fluorescence of P7 is efficiently quenched by Cu²⁺, Co²⁺, Ni²⁺, Zn²⁺, Mn²⁺, and Ag⁺ ions. In contrast, only Cu²⁺, Co²⁺, and Ni²⁺ ions can partially quench the fluorescence of P10 , but much less efficiently than the fluorescence of P7 . The static Stern–Volmer quenching constants of Cu²⁺, Co²⁺, and Ni²⁺ ions toward P7 are of the order of 10⁶ M^?1, being 1300, 2500, and 37,300 times larger than those of P10 , respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4154–4164, 2006     

油价波动对国民经济影响模型构建与应用

为了科学构建原油价格波动与国民经济发展的关系,在借鉴国内外专家学者相关模型基础上,考虑不同国民经济指标对油价波动的时滞反馈等因素,构建油价波动对国民经济影响模型.利用原油价格波动对国民经济发展的动态模型,对模型的各部分关系系数进行确定,最后根据所得到的模型对国民经济影响进行实际分析与预测,并得出规避油价波动影响风险的措施.     

“阳”加速器钼丝X-pinch初步实验研究

 在“阳”加速器上进行了直径分别为10, 15, 20 μm, 交叉角为32°,45°,60°的钼（Mo）丝X-pinch实验。“阳”加速器产生的电流峰值约520 kA，上升时间80 ns。实验中通过X射线功率谱仪和纳秒分幅相机等仪器对Mo丝X-pinch辐射特性进行了诊断。实验表明：Mo丝X-pinch过程中会出现多次X射线爆发，箍缩过程中产生的热点辐射出能量超过3 keV的X射线，探测到的最小热点直径小于30 μm。     

傅里叶变换红外光谱与拉曼光谱分析碳青霉烯药物亚胺培南的结构特征

本文采用傅里叶变换红外光谱和激光拉曼光谱对碳青霉烯药物亚胺培南进行光谱检测,并对其的分子振动光谱与结构特征进行分析和探讨,分析了亚胺培南在固相状态下的结构形式,从而为药物合成及质量控制提供了重要的参考价值。     

Widely tunable long-period fiber grating with nm-thick higher refractive index film overlay

By introducing a four-layer step-index waveguide modeling, the characteristics of long-period fiber grating (LPFG) with an nm-thick film overlay, which has higher refractive index than that of fiber cladding are investigated in detail. The influence of both the overlay thickness and refractive index on the tuning ability of LPFG is analyzed. The numerical results demonstrate that spectral response of LPFG is divided into three distinct regions as the overlay deposition increases and the shift of resonant wavelength is drastic in some special thickness range. In conjunction with higher-order cladding mode coupling and fiber cladding etching, the sensitivity of LPFG to the overlay refractive index is enhanced significantly and over 120 nm resonant wavelength tunable range is achieved.     

基于半像素错位的多幅图像重建高分辨率图像技术研究

介绍了一种基于半像素错位的多幅图像重建高分辨率图像技术。分析了半像素错位的多幅图像与高分辨率图像各像素灰度值的对应关系 ,并从CCD数字化采样的角度进行了论证。同时 ,结合实际摄像机CCD结构 ,求出了高分辨率图像重建的计算公式 ,并通过实验进行了验证和完善。重建的本质是以原高分辨率图像的 4邻域平均图像为基础 ,增加一定比例的边缘细节信息 ,去接近原高分辨率图像。CCD的动态范围越大 ,图像的灰度级越多 ,那么计算误差就越小 ,图像的边缘细节信息就可以利用更多 ,重建的图像就越接近原高分辨率图像。通过实验和分析表明 ,利用半像素错位的多幅低分辨率图像重建高分辨率图像的原理是正确的 ,方案是可行的     

A Strongly and Superlinearly Convergent SQP Algorithm for Optimization Problems with Linear Complementarity Constraints

This paper discusses a kind of optimization problem with linear complementarity constraints, and presents a sequential quadratic programming (SQP) algorithm for solving a stationary point of the problem. The algorithm is a modification of the SQP algorithm proposed by Fukushima et al. [Computational Optimization and Applications, 10 (1998), 5-34], and is based on a reformulation of complementarity condition as a system of linear equations. At each iteration, one quadratic programming and one system of equations needs to be solved, and a curve search is used to yield the step size. Under some appropriate assumptions, including the lower-level strict complementarity, but without the upper-level strict complementarity for the inequality constraints, the algorithm is proved to possess strong convergence and superlinear convergence. Some preliminary numerical results are reported.     

标的资产服从几何分数布朗运动的期权定价

本文在M ogens B ladt和T ina H av iid R ydberg无市场假设,仅利用价格过程的实际概率的期权保险精算定价模型的基础上,得出了标的资产服从几何分数布朗运动的欧式期权定价公式,并说明了几何布朗运动是本文的一种特殊情况.     

中心—焦点区分问题的I l'yashenko算法

对二维平面系统的二维系统的中心焦点区分问题 ,I l'yashenko曾建议一个算法 ,本文给出此法的详细证明 .据此 ,我们讨论了区分问题在 Arnold意义下的代数可解性与不可解性     

一种新的奇偶非线性相干态及其量子统计性质

定义了一种新的奇偶非线性相干态即算符B2[B=af(N)]的两个正交归一本征态,利用数值计算方法研究了它们的量子统计性质.结果表明,与通常的奇偶相干态不同,在参数|β|变化的某些范围内,只有偶非线性相干态可以存在压缩效应,而振幅平方压缩和反聚束效应在这两个态中均可以呈现 关键词： 新的奇偶非线性相干态 压缩 振幅平方压缩 反聚束效应