Effects of oxygen-containing defect complex on the electronic structures and transport properties of single-walled carbon nanotubes

The electronic structures and transport properties of (10,0)$(10,0)$ single-walled carbon nanotube ((10,0)$(10,0)$ (SWNT)) with oxygen-containing defect complex are investigated using density functional theory in combination with nonequilibrium Green?s function method. The complex delocalizes the local states of (10,0)$(10,0)$ SWNT induced by mono- and di-vacancy but strengthens the localization of the states induced by the Stone–Wales defect. As a result, the complex partially restores the transport properties of (10,0)$(10,0)$ SWNT with vacancies, but reduces the transmission of (10,0)$(10,0)$ SWNT with Stone–Wales defect. However, the oxygen-containing defect complex only slightly influences the transmission gap and threshold voltage of the system.     

Dielectric relaxations in Tb0.91Yb1.38Bi0.71Fe5O12 ceramics

Dielectric relaxations of Tb_0.91Yb_1.38Bi_0.71Fe₅O₁₂ ceramics were investigated. A Debye-type relaxation was observed in the temperature range of 125-620 K with an activation energy of 0.29 eV. This activation energy agreed well with that of carriers hopping between Fe²⁺ and Fe³⁺, indicating that this relaxation might be a dipolar-type relaxation associated with the hopping carries. A high relaxorlike dielectric peak with a very strong frequency dispersion in the high temperature range of 400-620 K might be originate from the oxygen vacancies related dielectric relaxation.     

Total reaction and fusion cross sections at sub- and near-barrier energies for the system 7Li + 28Si

Fusion cross sections are extracted for the ⁷Li$ + $²⁸Si system, via reaction cross section and transfer measurements at sub- and near-barrier energies ( E _lab = 5.7 to 14MeV). The energy evolution of transfer to reaction cross section ratios is determined with the aid of CDCC calculations, which subsequently allows the deduction of fusion cross sections at sub- and near-barrier energies. It is shown that fusion can be well represented in a BPM context. Fusion cross sections are compared for the systems ⁷Li$ + $²⁸Si and ⁶Li$ + $²⁸Si, the latter studied previously, and are found to exhibit different strengths. Last, the direct channels determined at 13MeV, are found to be dominated by a 2n -transfer mechanism.     

New search for processes violating the Pauli exclusion principle in sodium and in iodine

In this paper a new search for non-Paulian nuclear processes, i.e. processes normally forbidden by the Pauli Exclusion Principle (PEP), is presented. It has been carried out at the Gran Sasso National Laboratory of the INFN by means of the highly radiopure DAMA/LIBRA set-up (sensitive mass of about 250 kg highly radiopure NaI(Tl)). In particular, a new improved upper limit for the spontaneous non-Paulian emission rate of protons with energy E _p ≥ 10 MeV in ²³Na and ¹²⁷I has been obtained: 1.63 × 10⁻³³ s⁻¹ (90% C.L.). The corresponding limit on the relative strength (δ ²) for the searched non-Paulian transition is δ ²≲(3–4)×10⁻⁵⁵ (90% C.L.). Moreover, PEP-violating electron transitions in iodine atoms have also been investigated. Lifetimes shorter than 4.7×10³⁰ s are excluded at 90% C.L.; this allows us to derive the limit δ _e ²<1.28×10⁻⁴⁷ (90% C.L.). This latter limit can also be related to a possible finite size of the electron in composite models of quarks and leptons providing superficial violation of the PEP; the obtained upper limit on the electron size is r ₀<5.7×10⁻¹⁸ cm (energy scale of E≳3.5 TeV).     

Growth, Characterization and Theoretical Study of a Novel Organometallic Nonlinear Optical Crystal: CdHg(SCN)4(C2H5NO)2

A novel potentially useful second harmonic generation (SHG) organometallic nonlinear optical (NLO) crystal: cadmium mercury thiocyanate bis(N-methylformamide), CdHg(SCN)₄(C₂H₅NO)₂ (CMTN), has been prepared, and large high-optical-quality single crystals with dimensions up to 30 ×27×9 mm³ have been grown by the temperature-lowering method. Its structural, physicochemical and optical properties are characterized by elemental analyses, X-ray powder diffraction, Fourier transform infrared and Raman spectroscopy, thermal analysis, powder SHG measurements and UV/Vis/NIR transmission. The specific heat has been determined to be 515.5 J?mol^?1?K^?1 at 300 K. CMTN possesses good physicochemical stability up to 128.5^°C, exhibits powder SHG efficiencies 0.8 times that of urea and its UV transparency cutoff is 358 nm. By the use of the DFT/B3LYP/6-31G(d) method, the microscopic second order NLO behavior of CMTN has been investigated by computing the first-order hyperpolarizability together with that of CdHg(SCN)₄ (CMTC) and CdHg(SCN)₄(C₃H₈O₂) (CMTG) crystals. The results have been explained based on their crystal structures.     

Diode pumped active-mirror Yb:YAG ceramic lasers

Lasers from Yb:YAG ceramic at different temperature were reported in this paper. The Yb:YAG ceramic laser with active-mirror structure was end-pumped by a laser diode whose central wavelength was 940 nm. At 80 K, with doping concentration of 5 at % Yb:YAG ceramic slab, output energy of 0.68 J at 10 Hz repetition rate was obtained under the pump energy of 2.49 J, corresponding to a slope efficiency of 40% and a conversion efficiency of 27.3%, respectively.     

On the nuclear curvature energy

The curvature energy coefficient of the nuclear mass formulaa _c is first calculated for the model case of a Fermi gas bounded by an external Woods-Saxon potential. The semiclassical theory of Wigner and Kirkwood is used anda _c is found to be close to zero. It is, however, shown that this low value is due to the lack of selfconsistency of the potential. When available, the results of the model compare very well with quantal values and the extrapolation to the spherical cavity (billiard) checks with the value fora _c known from the Balian-Bloch theory. Second, the selfconsistent case is generalised to finite range forces. No indication is found that this modifies the fact that all theoretical values for a _c are larger than about 7 MeV which is an order of magnitude above the empirical value.     

Completeness in Supergravity Constructions

We prove that the supergravity r- and c-maps preserve completeness. As a consequence, any component \({\mathcal{H}}\) of a hypersurface {h = 1} defined by a homogeneous cubic polynomial h such that \({-\partial^2h}\) is a complete Riemannian metric on \({\mathcal{H}}\) defines a complete projective special Kähler manifold and any complete projective special Kähler manifold defines a complete quaternionic Kähler manifold of negative scalar curvature. We classify all complete quaternionic Kähler manifolds of dimension less or equal to 12 which are obtained in this way and describe some complete examples in 16 dimensions.     

Uncertainty-based experimental validation of nonlinear reduced order models

This paper presents the first results of a combined experimental–computational investigation focused on the validation of reduced order models of geometrically nonlinear structures in the presence of uncertainty. The validation approach considered here is based on the premise that the model is valid if the experimental results can be considered as random sample responses of the stochastic system of which the reduced order model is the mean. For the situation considered here, the power spectra of the experiments should lie within the 2nd and 98th percentiles of the response (forming the uncertainty band) of the stochastic model. Nominally clamped–clamped beams are considered to demonstrate the entire process. The construction of two mean reduced order models and their stochastic counterparts are first performed. Then, the validation effort is carried out by comparing experimentally obtained power spectra and their corresponding computational uncertainty bands. This process leads, for both reduced order models, to a very good representation of the important upper envelope (98th percentile) of the experimental data but a less good fit of the lower envelope (2nd percentile).