全文获取类型
收费全文 | 27411篇 |
免费 | 1940篇 |
国内免费 | 1462篇 |
专业分类
化学 | 13851篇 |
晶体学 | 484篇 |
力学 | 1833篇 |
综合类 | 98篇 |
数学 | 2854篇 |
物理学 | 11693篇 |
出版年
2023年 | 229篇 |
2022年 | 477篇 |
2021年 | 450篇 |
2020年 | 474篇 |
2019年 | 445篇 |
2018年 | 502篇 |
2017年 | 462篇 |
2016年 | 731篇 |
2015年 | 625篇 |
2014年 | 898篇 |
2013年 | 1486篇 |
2012年 | 1728篇 |
2011年 | 2080篇 |
2010年 | 1461篇 |
2009年 | 1496篇 |
2008年 | 1642篇 |
2007年 | 1602篇 |
2006年 | 1590篇 |
2005年 | 1339篇 |
2004年 | 1133篇 |
2003年 | 893篇 |
2002年 | 820篇 |
2001年 | 1206篇 |
2000年 | 882篇 |
1999年 | 798篇 |
1998年 | 648篇 |
1997年 | 602篇 |
1996年 | 522篇 |
1995年 | 436篇 |
1994年 | 450篇 |
1993年 | 319篇 |
1992年 | 318篇 |
1991年 | 283篇 |
1990年 | 278篇 |
1989年 | 202篇 |
1988年 | 177篇 |
1987年 | 173篇 |
1986年 | 152篇 |
1985年 | 145篇 |
1984年 | 105篇 |
1983年 | 70篇 |
1982年 | 63篇 |
1981年 | 55篇 |
1980年 | 37篇 |
1979年 | 31篇 |
1978年 | 31篇 |
1977年 | 26篇 |
1976年 | 34篇 |
1975年 | 34篇 |
1973年 | 29篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
171.
Polycrystalline Sn1−xMnxO2 (0≤x≤0.05) diluted magnetic semiconductors were prepared by solid-state reaction method and their structural and magnetic properties had been investigated systematically. The three Mn-doped samples (x=0.01, 0.03, 0.05) undergo paramagnetic to ferromagnetic phase transitions upon cooling, but their Curie temperatures are far lower than room temperature. The magnetization cannot be attributed to any identified impurity phase. It is also found that the magnetization increases with increasing Mn doping, while the ratio of the Mn ions contributing to ferromagnetic ordering to the total Mn ions decreases. 相似文献
172.
提出一种实现简并光学参量振荡器混沌反控制的方法,用正弦信号调制简并光学参量振荡器的基模衰减率,使简并光学参量振荡器从定态输出转化为混沌态.数值模拟结果表明,选择不同的调制幅度和调制角频率,只要满足系统的最大李雅谱诺夫指数大于零,即可实现不同的混沌轨道重构.通过比较最大李雅谱诺夫指数λmax随调制幅度和调制角频率变化曲线, 指出系统从周期态调制到混沌态比从无亚谐波输出的定态调制到混沌态更容易,有更宽的调制幅度和调制角频率选择范围.
关键词:
简并光学参量振荡器
混沌反控制
调制 相似文献
173.
SiC films doped with aluminum (Al) were prepared by the rf-magnetron sputtering technique on p-Si substrates with a composite target of a single crystalline SiC containing several Al pieces on the surface. The as-deposited films were annealed in the temperature range of 400-800 °C under nitrogen ambient. The thin films have been characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The results show that the introduction of Al into films hinders crystalline formation process. And with the increase of annealing temperature, more Si particles are formed in the films, which strongly affect the optical absorption properties. The photoluminescence (PL) spectra of the samples show two peaks at 370 nm and 412 nm. The intensities of the PL peaks are evidently improved after Al doped. We attribute the origin of the two PL peaks to a kind of Si-related defect centres. The obtained results are expected to have important applications in modern optoelectronic devices. 相似文献
174.
用密度泛函B3LYP/6-311++G(d,p)方法和相对论有效实势(Lanl2dz基组)对VOn±(n=0,1,2)分子离子的势能函数及光谱常数进行了分析. 结果表明它们都能稳定存在, 其基态电子状态分别是:4Σ(VO2-), 3Σ(VO-), 4Σ(VO), 3Σ(VO+)和2Σ(VO2+). 其中VO2-和VO2+的势能函数曲线呈“火山口”型, 属于亚稳态分子离子. 用七参数Murell-Sorbie势拟合VO2-和VO2+分子亚稳态双原子分子离子势能函数, 发现其拟合曲线与势能函数曲线符合得很好. 同时,讨论了电荷对势能函数和能级的影响.
关键词:
分子离子
密度泛函理论
势能函数
能级 相似文献
175.
176.
177.
X.F. Hu 《Applied Surface Science》2006,252(13):4625-4627
The synthetic antiferromagnets (SAF) have been used in spin-valve sensor in data storage industry [1]. We report a new hard/Ru/soft sandwich structure (SHBL) fabricated by pulsed lased deposition to replace current single layer structure for information recording application. SHBL consists of two magnetic layers separated by thin nonmagnetic layers, typically with Ru layers of 0.7-1.2 nm, through which antiferromagnetic coupling is induced. Varying the relative thickness of the magnetic layers, the spacer layers, and the type of magnetic materials can alter magnetic properties of CoCrPt/Ru/CoFe superlattice. The coercivity Hc and grain size of magnetic layer is also dependent on the laser fluence. High laser fluence results in both small grain size and high Hc. The observed phenomena are related to high quenching and deposition rates during PLD at high fluence, resulting in more pronounced phase segregation. 相似文献
178.
L. Pillier C. Moreau X. Mercier J.F. Pauwels P. Desgroux 《Applied physics. B, Lasers and optics》2002,74(4-5):427-434
Cavity ring-down spectroscopy (CRDS) is used to measure the NO mole fraction formed in the burnt gases of low-pressure premixed
flames. It is shown that the line-of-sight absorption is greatly increased by the contribution of the NO molecules surrounding
the burner. This contribution has been quantified by developing a mathematical procedure taking into account the spatial and
spectral features of the CRDS measurement. Calculations have been undertaken in the general case of a stable species not consumed
in the flame. The most sensitive parameter is the temperature both in the flame and outside the flame. Simulations allow the
selection of the best spectroscopic transitions for a given flame (i.e. a given temperature profile), ensuring the weakest
influence of the inaccuracy affecting the temperature determination. High quantum states belonging to the A–X (0–1) band of
NO have been found to be the most valuable and have led to a NO mole fraction determination with an accuracy of ±13%. NO absorption
in the flame was completely masked using the A–X (0–0) band. Finally, the prompt-NO mole fraction formed in a methane/air
flame stabilized at 33 Torr is obtained by combining CRDS and laser induced fluorescence techniques.
Received: 12 October / Revised version: 1 February 2002 / Published online: 14 March 2002 相似文献
179.
X. Luo F. Y. Shi J. X. Lin 《International Journal of Infrared and Millimeter Waves》1991,12(2):141-147
Detection of COCl2, a highly toxic gas in chemical industry, using laser photoacoustic spectroscopy is presented. The spectrophone system used has a broad band LN2 cooled CW CO laser as a source of radiation, which operates from 4.8–8.4 um in the mid-infrared. Using an extracavity open longitudinal resonant cell, absorption signals to about 30 CO laser lines in the 5.45 um region could be observed. detection sensitivity has been estimated to be ppb order.This work has been supported by the NSFC 相似文献
180.
I. Ortalli G. Pedrazzi K. Jiang X. Zhang C. Carlo-Stella V. Rizzoli 《Il Nuovo Cimento D》1992,14(4):351-358
Summary A new approach to cancer treatment using low-energy gamma-rays is discussed. Cultures of bone marrow mononuclear cells collected
from normal donors and patients with chronic myelogenous leukaemia have been studied after the addition of hematin, at different
concentrations, and irradiation by a M?ssbauer gamma-ray source. Growth stimulation has been observed when hematin is added
to normal bone marrow cultures, while growth inhibition is observed when hematin is added to leukaemic cultures. The effect
becomes then more pronounced when hematin is used in combination with M?ssbauer gamma-rays. 相似文献