米兰花化学成分的GC-MS分析

采用超声波提取米兰花.然后对其化学成分进行GC-MS分析.从米兰花中分离确定了27种主要成分,其中萜类物质含量相对较高.     

Complete chaotic synchronization mechanism of polarization mode of VCSEL with anisotropic optical feedback

We numerically investigate the complete chaotic synchronization mechanism of polarization mode of VCSEL with anisotropic optical feedback. Firstly, the synchronization quality of the x-linear polarization (LP) mode and the y-LP mode are both periodically changed with the angle θ between the polarizer and the light axes. Secondly, in a enough large scale region of the feedback coefficient and the injection current, where each LP mode can obtained good synchronization quality when the angle θ exists in the former half period region and the injection current is fixed at a certain value, which is over the threshold current. Under this condition, their synchronization quality is independent of the polarization states. By contrast, in the latter half period region of the angle θ where each LP mode can be obtained very instable and inferior synchronized quality. At last, the robustness of the synchronization scheme is sensitive to the internal and external parameter mismatch between the transmitter-VCSEL and the receiver-VCSEL.     

Planarization machining of sapphire wafers with boron carbide and colloidal silica as abrasives

The as-cutted sapphire wafers are planarized by the grinding and polishing two-step machining processes with micrometer B₄C and nanometer silica as abrasives, respectively. The material removal rates (MRRs) of two processes are measured. During the polishing process, the MRR increases with the down-pressure increased, whereas the rotational speeds have less effect on the MRR. The alkaline colloidal silica is more favorable than the acidic to polish sapphire wafer. The ground and polished surfaces of the substrate are compared by scanning electron microscopy, atomic force microscopy, and X-ray rocking curves. Our results show that B₄C abrasives are effective in elimination of the ununiformity in thickness within a wafer. The colloidal silica can achieve a nanoscale flatness of wafer, but the lasting polishing time seems unfavorable. The polishing process is also analyzed in terms of chemical mechanical polishing mechanism.     

Preparation of microporous activated carbon and its electrochemical performance for electric double layer capacitor

Microporous activated carbons were prepared by microwave heating petroleum coke with potassium hydroxide as activation agent. Microporous activated carbons were characterized by infrared spectroscopy, X-ray diffraction and nitrogen adsorption/desorption isotherms. Electrochemical properties of an electric double layer capacitor using microporous activated carbon as electrode materials were investigated by constant current charge-discharge and electrochemical impedance spectroscopic techniques. The results show that the specific surface area and the pore volume of microporous activated carbon increase with increasing activation time before the activation time reaches 37 min. The microporous volume totals 94.0% in the microporous activated carbons and the average pore diameter of microporous activated carbon is 2.00 nm. Microporous activated carbons prepared in the activation time of 31, 35 and 37 min are named as AC-31, AC-35 and AC-37, respectively. Compared with AC-27 electrode, the internal resistance for ions transferring in AC-31, AC-35 or AC-37 electrode is relatively small. The specific capacitance of AC-31 is the biggest among the microporous activated carbons, and it retains 279.6 F g^?1 maintaining 93.5% capacity after 200 recycling number.     

Enhanced blue emission from ZnS–ZnO composites confined in SBA-15

A new optical material, the ZnO nanoparticles that are modified with ZnS and confined in SBA-15, has been prepared through the controllable sulfuration at relatively low temperature (40 °C) from the ZnO/SBA-15 composites. The precursor composites can be prepared through a novel path in which the zinc is well dispersed by directly grinding zinc nitrate into the as-synthesized SBA-15 occluded with template followed by calcination, and it is possible to control the conversion of ZnO to ZnS by adjusting the reaction time. The resulting samples are characterized by XRD, nitrogen adsorption–desorption and photoluminescence (PL) spectroscopy. ZnO–ZnS composites, mainly confined in the mesopore of SBA-15, exhibit dramatically enhanced blue emission at the expense of the UV emission.     

Quantum entanglement in the mode-mode competition system

Considering a two-level atom interacting with the competing two-mode field, this paper investigates the entanglement between the two-level atom and the two-mode field by using the quantum reduced entropy, and that between the two-mode field by using the quantum relative entropy of entanglement. It shows that the two kinds of entanglement are dependent on the relative coupling strength of atom-field and the atomic distribution, and exhibit the periodical evolution. The maximal atom-field entanglement state can be prepared via the appropriate selection of system parameters and interaction time.     

Sensitive and automated detection of iron-oxide-labeled cells using phase image cross-correlation analysis

Superparamagnetic iron oxide (SPIO) nanoparticles are increasingly being used to noninvasively track cells, target specific molecules and monitor gene expression in vivo. Contrast changes that are subtle relative to intrinsic sources of contrast present a significant detection challenge. Here, we describe a postprocessing algorithm, called Phase map cross-correlation Detection and Quantification (PDQ), with the purpose of automating identification and quantification of localized accumulations of SPIO agents. The method is designed to sacrifice little flexibility - it works on previously acquired data and allows the use of conventional high-SNR pulse sequences with no extra scan time. We first investigated the theoretical detection limits of PDQ using a simulated dipole field. This method was then applied to three-dimensional (3D) MRI data sets of agarose gel containing isolated dipoles and ex vivo transplanted allogenic rat hearts infiltrated by numerous iron-oxide-labeled macrophages as a result of organ rejection. A simulated dipole field showed this method to be robust in very low signal-to-noise ratio images. Analysis of agarose gel and allogenic rat heart shows that this method can automatically identify and count dipoles while visualizing their biodistribution in 3D renderings. In the heart, this information was used to calculate a quantitative index that may indicate its degree of cellular infiltration.     

Vis-NIR光谱快速估测土壤可侵蚀性因子可行性分析

土壤侵蚀降低土地生产力,导致土壤环境恶化,其中水力侵蚀是土壤侵蚀中最主要的一种形式。土壤可侵蚀性K值是评价土壤被降雨侵蚀难易程度的一项重要指标。使用河南、福建和浙江三省研磨干样可见-近红外(Vis-NIR)漫反射光谱数据,将其转换为吸收率后进行Savitzky-Golay(SG)平滑去噪;对土壤有机质(SOM)和机械组成进行精准预测后,分别采用EPIC和RUSLE2模型估算K值,并对预测精度进行比较分析,所得结论如下：(1)建立土壤有机质和机械组成高光谱最佳预测模型,土壤质地(砂粒、粉粒和黏粒)预测采用支持向量机(SVM)模型,SOM预测采用局部加权回归(LWR)模型,模型四分位相对预测误差(RPIQ)为2.27,3.17,2.18和3.44;(2)通过土壤质地估算的土壤渗透性等级分类效果较好,Kappa系数为0.62,同时估测的土壤质地类型与实测土壤质地类型分布特征相近,质地主要类型均是粉黏土、砂黏壤土、壤土、壤砂土和砂壤土;(3)EPIC和RUSLE2两种模型均具有较为精确的估测能力,EPIC模型预测精度更高,均方根误差(RMSEP)为0.006 6 (t·ha·h)/(ha·MJ·mm),RPIQ达1.58,而RUSLE2模型精度相对较低(其中RPIQ为1.43),因此推荐使用EPIC模型结合Vis-NIR光谱技术估测土壤可侵蚀性K值。本研究为今后快速准确预测K值提供思路,并为大面积监测土壤侵蚀提供辅助手段。     

基于光子晶体光纤交叉敏感分离的磁场温度传感研究

提出了一种基于定向耦合效应和表面等离子共振效应的交叉敏感分离的磁场温度传感结构.在光子晶体光纤的一个特定空气孔中填充磁流体,利用磁流体的磁光效应和定向耦合效应形成磁场传感通道;在垂直方向的另一空气孔的内壁镀金纳米薄膜并填充甲苯液体,利用甲苯的温敏效应和表面等离子共振效应形成温度传感通道.对应输出谱出现两个损耗峰,测量损耗峰位置可以间接测出磁场强度和温度变化.通过理论计算()和结构优化,在90—270 Oe1 Oe=10~3/(4π) A/m范围内,磁场强度的灵敏度最高可达1.16 nm/Oe;在25—60?C范围内,温度的灵敏度可达-9.07 nm/?C.虽然填充的两种液体的折射率都受环境温度的影响,但通过建立灵敏度系数矩阵,可以消除磁场强度与温度的交叉敏感,实现磁场温度双参量的高灵敏度检测.     

FeTe合金结构分析及其薄膜制备

利用固态反应法制备了名义成分为FeTe的合金, 采用X射线粉末衍射技术和Rietveld全谱拟合分析方法测定了其相组成和晶体结构. 研究表明,主相为Fe_1.08Te,空间群为P4/nmm,点阵参数 a = 3.8214(3) Å, c = 6.2875(3) Å, Z = 2, Fe原子占据2a和2c晶位, Te原子占据2c晶位. 利用脉冲激光沉积技术制备的FeTe薄膜超导转变起始温度为13.2 K,零电阻温度为9.8 K. 关键词： FeTe Rietveld结构精修 超导薄膜