Properties of Graphene/Waterborne Polyurethane Nanocomposites Cast from Colloidal Dispersion Mixtures

Nanocomposites of waterborne polyurethane (WPU) reinforced with functionalized graphene sheets (FGSs) were effectively prepared by casting from a colloidal dispersion of FGS and WPU, and the morphology and physical properties were examined. The finer aqueous FGS dispersions or WPU with smaller particles yielded nanocomposites with enhanced electrical conductivity and thermal resistance due to finely dispersed FGS. The FGS nucleated the crystallization of the polycaprolactone (PCL) segments in WPU and improved its modulus. However, FGS inhibited crystal growth and deteriorated the tensile properties at high deformation, i.e., tensile strength and elongation at break, because the interaction between FGS and WPU hindered the chain rearrangement of WPU in the nanocomposite.     

Application of HPLC-Thermospray Flame AAS: Interaction Between Heavy Metals and Duckweed Chlorophyll

Thermospray nebulizer interfaced HPLC-Flame AAS was used to study the effect of heavy metals (Al, Cd, Cu, Hg and Zn) on the chlorophylls of duckweed. Flame AAS was used as a metal specific detector of HPLC. Study indicated that heavy metals promote the degradation of chlorophylls. No evidence of direct replacement of central magnesium with heavy metals was found.     

Sonochemical synthesis and characterization of nano-sized lead(II) 3D coordination polymer: Precursor for the synthesis of lead(II) oxybromide nanoparticles

Nanoparticles of a three-dimensional coordination polymer, [Pb(L)(μ₂-Br)(H₂O)]_n (1), (L^? = 1H-1,2,4-triazole-3-carboxylate), have been synthesized by an ultrasonic method and characterized by scanning electron microscopy, X-ray powder diffraction, IR spectroscopy and elemental analyses. The thermal stability of compound 1 both its bulk and nano-size has been studied by thermal gravimetric (TG) and differential thermal (DTA) analyses and compared each other. Concentration of initial reagents effects and the role of power ultrasound irradiation on size and morphology of nano-structured compound 1, have been studied. Calcination of the compound 1 at 500 °C under air atmosphere yields Pb₃O₂Br₂ nanoparticles.     

Significant decrease in interfacial energy of grain boundary through serrated grain boundary transition

The mechanism of serrated grain boundary formation and its effect on liquation behaviour have been studied in a wrought nickel-based superalloy – Alloy 263. It was newly discovered that grain boundaries are considerably serrated in the absence of γ?′-phase or M₂₃C₆ at the grain boundaries. An electron energy-loss spectroscopy study suggests that serration is triggered by the discontinuous segregation of C and Cr atoms at grain boundaries for the purpose of relieving the excessive elastic strain energy. The grain boundaries serrate to have specific segments approaching one {111} low-index plane at a boundary so that the interfacial free energy of the grain boundary can be decreased, which may be responsible for the driving force of the serration. The serrated grain boundaries effectively suppress grain coarsening and are highly resistant to liquation due to their lower wettability resulting from a lower interfacial energy of the grain boundary.     

Manipulation of light at the nanoscale for high-performance spectroscopic and optical applications

In this paper, we explore the use of nanostructures for a number of fascinating applications. These applications based on nanostructures include (1) optical sensors, (2) nanopixel printing, (3) improving the resolution of imaging techniques, and (4) lithography. In the sensing field, nanostructures are exploited for advanced sensor performance, namely, the label-free and enhanced sensitivity of (1) the surface plasmon resonance sensor and (2) the extraordinary optical transmission sensor and (3) the high sensitivity and selectivity of surface-enhanced Raman spectroscopy. In addition, research using nanostructures for visual applications was introduced for (1) harnessing nanostructures for full-color pixel printing and (2) exploiting metallic nanostructures to enhance the imaging resolution under diffraction limits based on the plasmonic effect. Finally, we introduce low cost, high accuracy, and fast lithographic methods based on the plasmonic effect by exploiting metallic nanostructures.     

A study of design velocity field computation for shape optimal design

Design velocity field computation is an important step in computing shape design sensitivity coefficients and updating a finite element mesh in the shape design optimization process. Applying an inappropriate design velocity field for shape design sensitivity analysis and optimization will yield inaccurate sensitivity results or a distorted finite element mesh, and thus fail in achieving an optimal solution. In this paper, theoretical regularity and practical requirements of the design velocity field are discussed. The crucial step of using the design velocity field to update the finite element mesh in the design optimization process is emphasized. Available design velocity field computation methods in the literature are summarized and their applicability for shape design sensitivity analysis and optimization is discussed. Five examples are employed to discuss applicability of these methods. It was found that a combination of isoparametric mapping and boundary displacement methods is ideal for the design velocity field computation.     

Construction of inclusions with vanishing generalized polarization tensors by imperfect interfaces

We investigate the problem of planar conductivity inclusion with imperfect interface conditions. We assume that the inclusion is simply connected. The presence of the inclusion causes a perturbation in the incident background field. This perturbation admits a multipole expansion of which coefficients we call as the generalized polarization tensors (GPTs), extending the previous terminology for inclusions with perfect interfaces. We derive explicit matrix expressions for the GPTs in terms of the incident field, material parameters, and geometry of the inclusion. As an application, we construct GPT-vanishing structures of general shape that result in negligible perturbations for all uniform incident fields. The structure consists of a simply connected core with an imperfect interface. We provide numerical examples of GPT-vanishing structures obtained by our proposed scheme.     

The effect of inflation pressure and vehicle loading on the sidewall of a radial tire

The sidewall is one of the regions where service failures occur in a pneumatic tire. Knowledge of the stresses or strains developed in the sidewall under varying service conditions is required if such pneumatic-tire failures are to be avoided. This paper describes an experimental investigation into the effect of inflation pressure, vehicle load and camber angle on the sidewall-surface strains in a radial tire. Photoelastic coating and a specially designed strain-gaging technique were used. For pure-inflation pressure, the magnitude of the measured shear strains in the sidewall is directly related to the inflation pressure. The maximum sidewall shear strains in pure inflation are located in the lower sidewall (18 mm from bead), irrespective of the magnitude of the inflation pressure. The mendional sidewall strain is predominant in the inflated but otherwise unloaded tire. The meridional strain is proportional to the square root of the inflation pressure. The maximum mendional strain is located in the mid-sidewall region. For a constant vehicle loading, there is a transition inflation pressure below or above which the circumterential shoulder strain increases sharply. This observation highlights the importance of maintaining satistactory inflation pressure in passenger-car tires as an under-inflated tire will induce severe strain development at the shoulder. In addition to the vehicle load, the introduction of camber angle produces localized change in the meridional and circumterential strains within the contact zone. The increase of camber angle up to 10 deg causes continuous increase in the meridional strain in the lower sidewall but decrease in the upper sidewall. The mid-sidewall meridional strains remain practically unchanged. The circumferential strains along the load line are, in general, lower due to the increase in camber angle.