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Stable isotopes of water have been previously used in catchment studies to separate rain‐event water from pre‐event groundwater. However, there are a lack of studies at the smaller scale looking at the separation of event water from pre‐event water. This is particularly relevant for heavy clay soil systems through which the movement of water is uncertain but is thought to be rainwater‐dominated. The data presented here were collected at a rural site in the south‐west of England. The historic rainfall at the site was isotopically varied but similar to the global meteoric water line, with annual weighted means of ?37‰ for δ2H and ?5.7‰ for δ18O and with no seasonal variation. Drainage was sampled from the inter‐flow (surface runoff + lateral through‐flow) and drain‐flow (55 cm deep mole drains) pathways of two 1 ha lysimeters during two rainfall events, which had δ2H values of ?68‰ and ?92‰, respectively. The δ2H values of the lysimeter drainage water suggest that there was no contribution of event water during the first, small discharge (Q) event; however, the second larger event did show isotopic variation in δ2H values negatively related to Q indicating that rainwater was contributing to Q. A hydrograph separation indicated that only 49–58% of the inter‐flow and 18–25% of the drain‐flow consisted of event water. This was surprising given that these soil types are considered retentive of soil water. More work is needed on heavy clay soils to understand better the nature of water movement from these systems. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
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Recently, transition metal borides attracted increased attention as electrocatalysts for the oxygen evolution reaction. Here, we show how the incorporation of nickel into nanoscale dicobalt boride results in an improvement of the activity and stability of the catalyst in alkaline electrolytes. The borides are obtained by a one-step solution synthesis, calcined, and characterized by X-ray diffraction and scanning electron microscopy. For (Co1-xNix)2B (x=0, 0.1, 0.2, 0.3, 0.4, and 0.5), (Co0.9Ni0.1)2B shows the best performance with an overpotential of η=371 mV at 10 mA cm−2 in 1 M KOH. Normalization to the electrochemical surface area shows a clear dependence on the activity with rising nickel content. X-ray photoelectron spectroscopy reveals that the catalyst is modified under reaction conditions and indicates that CoOOH and Ni(OH)2 are formed as active surface species. Flame atomic absorption spectroscopy (F-AAS) measurements show that no cobalt is dissolved during the electrochemical investigations, but the nickel concentration is increased on the surface of the catalyst as follows from XPS measurements after the electrochemical investigation.  相似文献   
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Mesoporous NiFe2O4 for electrocatalytic water splitting was prepared via soft-templating using citric-acid-complexed metal nitrates as precursors. The mesopore evolution during thermal treatment was examined systematically giving insights into the formation process of mesoporous NiFe2O4. Detailed nitrogen physisorption analysis including desorption scanning experiments reveal the presence of highly accessible mesopores generating surface areas of up to 200 m2/g. The ability of the NiFe2O4 powders to perform electrocatalytic oxygen evolution reaction under alkaline conditions was investigated, highlighting the advantages of mesopore insertion. The most active samples reach a current density of 10 mA cm−2 at an overpotential of 410 mV with a small Tafel slope of 50 mV dec−1, indicating an enhanced activity that originated from the increased catalyst surface.  相似文献   
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Colloid and Polymer Science - In Fortsetzung früherer Untersuchungen wird mit der Abreißwinkelmethode die Haftfähigkeit des Wassers und wässeriger Elektrolytlösungen an...  相似文献   
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