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排序方式: 共有248条查询结果,搜索用时 62 毫秒
161.
In this paper we study the problem of minimizing the Sobolev trace Rayleigh quotient among functions that vanish in a set contained on the boundary ∂Ω of given boundary measure.We prove existence of extremals for this problem, and analyze some particular cases where information about the location of the optimal boundary set can be given. Moreover, we further study the shape derivative of the Sobolev trace constant under regular perturbations of the boundary set. 相似文献
162.
Paulo Amorim Wladimir Neves 《Nonlinear Analysis: Theory, Methods & Applications》2011,74(15):4898-4917
We consider a hyperbolic conservation law posed on an (N+1)-dimensional spacetime, whose flux is a field of differential forms of degree N. Generalizing the classical Kuznetsov’s method, we derive an L1 error estimate which applies to a large class of approximate solutions. In particular, we apply our main theorem and deal with two entropy solutions associated with distinct flux fields, as well as with an entropy solution and an approximate solution. Our framework encompasses, for instance, equations posed on a globally hyperbolic Lorentzian manifold. 相似文献
163.
Small Iminocoumarin Derivatives as Red Emitters: From Biological Imaging to Highly Photoluminescent Non‐doped Micro‐ and Nanofibres
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Kacem Khemakhem Marine Soulié Dr. Rémy Brousses Dr. Houcine Ammar Prof. Souhir Abid Dr. Suzanne Fery‐Forgues 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(21):7927-7937
The fluorescence properties of four derivatives of 3‐thienyl‐2‐(N‐dicyanovinyl)iminocoumarin, bearing a diethylamino group in the 7‐position or a methoxy group in the 6, 7 and 8 positions, were compared in solution and in the solid state. The 7‐diethylamino derivative was strongly fluorescent in various solvents, with marked solvatochromism. Its fluorescence was quenched by aggregation. In contrast, the methoxy derivatives were only moderately or weakly fluorescent in solution, but two of them were strongly photoluminescent in the crystalline state, owing to favourable molecular packing. The 6‐methoxy derivative even exhibited spectacular crystallization‐enhanced emission, examples of which are particularly rare for this type of dyes. Dyes were tested for biological use. The 7‐diethylamino derivative led to particularly strong fluorescence staining of the cytoplasm of HCT‐116 colon cancer cells. No fading was observed over prolonged illumination by the microscope light beam, but a phototoxic effect was detected. The use of the dyes as red‐emitting materials was also investigated. Using easy‐to‐implement preparation methods, the compounds self‐ assembled to give one‐dimensional nano‐ and microsized particles, including millimeter‐long microfibres that exhibited clear wave‐guiding properties. This study shows the value of these low molecular‐weight molecules for the preparation of new orange and red‐emitting fluorescent materials based on totally pure dye. 相似文献
164.
Laurens M. De Coen Bart I. Roman Marine Movsisyan Brecht Dhont Nils De Vos Kristof Van Hecke Christian V. Stevens 《Tetrahedron letters》2017,58(37):3612-3615
A new class of dicationic ionic salts has been developed based on two 7-azoniabicyclo[2.2.1]heptane moieties and a variable spacer. The construction of the 7-azabicyclo[2.2.1]heptane skeleton and introduction of the two- to ten-atom spacer occurred concurrently in a one-pot reaction. Quaternization and subsequent metathesis afforded the dicationic salts consisting of two linked quaternized bicyclic moieties and bis(trifluoromethylsulfonyl)imide or dicyanamide as counterions. These salts are liquids at room temperature if the spacer length was larger than seven atoms. X-ray diffraction analysis revealed a linear conformation of the spacer and RS/SR stereochemistry of the quaternized nitrogens. 相似文献
165.
Haïat G Berti R Galaz B Taulier N Amman JJ Urbach W 《The Journal of the Acoustical Society of America》2011,129(3):1642-1652
A generation of tissue-specific stable ultrasound contrast agent (UCA) composed of a polymeric capsule with a perfluorocarbone liquid core has become available. Despite promising uses in clinical practice, the acoustical behavior of such UCA suspensions remains unclear. A simulation code (2-D finite-difference time domain, FDTD) already validated for homogeneous particles [Galaz Haiat, Berti, Taulier, Amman and Urbach, (2010). J. Acoust. Soc. Am. 127, 148-154] is used to model the ultrasound propagation in such UCA suspensions at 50 MHz to investigate the sensitivity of the ultrasonic parameters to physical parameters of UCA. The FDTD simulation code is validated by comparison with results obtained using a shell scatterer model. The attenuation coefficient (respectively, the sound velocity) increases (respectively, decreases) from 4.1 to 58.4 dB/cm (respectively, 1495 to 1428 m/s) when the concentration varies between 1.37 and 79.4 mg/ml, while the backscattered intensity increases non-linearly, showing that a concentration of around 30 mg/ml is sufficient to obtain optimal backscattering intensity. The acoustical parameters vary significantly as a function of the membrane thickness, longitudinal and transverse velocity, indicating that mode conversions in the membrane play an important role in the ultrasonic propagation. The results may be used to help manufacturers to conceive optimal liquid-filled UCA suspensions. 相似文献
166.
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168.
Polymeric polyimide capillary tubing, both uncoated and coated with stationary phases of two polarities, is explored for use as capillary columns for gas chromatography (GC). These glass-free polyimide columns are flexible and their small winding diameter of less than a cm around a solid support makes them compatible for potential use in portable GC instruments. Polyimide columns with dimensions of 0.32 mm i.d. × 3 m are cleaned, annealed at 300°C, and coated using the static method with phenylmethylsilicone (PMS). Separations of volatile organics are investigated isothermally on duplicate sets of polyimide columns by GC with a flame ionization detector using split injection. Unlike the uncoated ones, the coated polyimide columns successfully separate Grob test mix classes of alkanes, amines, and fatty acid methyl esters. The relative standard deviations for retention time and peak area are 0.5 and 2.5 , respectively. With the 3 m PMS-coated column connected to a retention gap to permit operation at its optimum flow rate of 30 cm/s, a plate count of 3200 or plate height of 1 mm is possible. Lack of retention and tailing peaks are evident for the polyimide polymer capillary columns as compared to that of a 3 m commercial cross-linked PMS fused silica capillary. However, headspace analyses of an aromatic hydrocarbon mix and a Clearcoat automotive paint sample are viable applications on the PMS polyimide polymer column. 相似文献
169.
Damien Hédou Emmanuel Deau Marine Harari Morgane Sanselme Corinne Fruit Thierry Besson 《Tetrahedron》2014
Reliable synthetic routes were studied for an access to a novel polyfunctionalized 6-amino-2-cyanobenzo[d]thiazole-5-carboxylate ester (1) and its analogue 5-amino-2-cyanothiazolo[5,4-b]pyridine-6-carboxylate ester (2). Both compounds 1 and 2 are functionalized as molecular bricks for the synthesis of innovative molecular systems. Part of the chemistry performed in this study was achieved under microwave irradiation. 相似文献
170.