We report on photoluminescence studies of Tb3+ in a polycrystalline cryolite type K3YF6 host. The location of the Tb3+ in the center of inversion forbids the electric-dipole transitions of terbium ions in this material. As a consequence almost the entire luminescence intensity is related to the 5D4-(7)F5 magnetic-dipole transition, and it is contained in the extremely narrow spectral bandwidth amounting to 1.7 nm at 8K and to 18 nm at room temperature. The phosphor under study can be efficiently excited making use of intense f-d transitions of Tb3+ in the UV-vacuum-UV region and may be of interest for applications requiring high spectral purity of the emission. 相似文献
To overcome the “curse of dimensionality” (which plagues most predictors (predictive models) when carrying out long-term forecasts) and cope with uncertainty present in many time series, in this study, we introduce a concept of granular time series which are used to long-term forecasting and trend forecasting. A technique of fuzzy clustering is used to construct information granules on a basis of available numeric data present in the original time series. In the sequel, we develop a forecasting model which captures the essential relationships between such information granules and in this manner constructs a fundamental forecasting mechanism. It is demonstrated that the proposed model comes with a number of advantages which manifest when processing a large number of data. Experimental evidence is provided through a series of examples using which we quantify the performance of the forecasting model and provide with some comparative analysis. 相似文献
A simple and convenient thin-layer chromatography (TLC) method combined with image analysis technique was developed to determine thiophanate methyl. The detection of pesticide was based on iodine–azide reaction. Digital images of TLC plate chromatograms were analysed using TLSee software, and quantitative analysis was conducted. The linearity (0.3–3.0 µg per spot), sensitivity, accuracy and precision of the system were investigated. 相似文献
Ion-molecule reactions of Me2S2 with a wide range of aliphatic carbanions differing by structure and proton affinity values have been studied in the gas phase using mass spectrometry techniques and DFT calculations. The analysis of the spectra shows a variety of product ions formed via different reaction mechanisms, depending on the structure and proton affinity of the carbanion. Product ions of thiophilic reaction (m/z 47), SN2 (m/z 79), and E2 elimination – addition sequence of reactions (m/z 93) can be observed. Primary products of thiophilic reaction can undergo subsequent SN2 and proton transfer reactions. Gibbs free energy profiles calculated for experimentally observed reactions using PBE0/6-311+G(2d,p) method show good agreement with experimental results.
An internal characterization of metric spaces which are absolute Borel sets of multiplicative classes is given. This characterization uses complete sequences of covers, a notion introduced by Frolík for characterizing Cech-complete spaces. We also show that the absolute Borel class of is determined by the uniform structure of the space of continuous functions ; however the case of absolute metric spaces is still open. More precisely, we prove that, for metrizable spaces and , if is a uniformly continuous surjection and is an absolute Borel set of multiplicative (resp., additive) class , , then is also an absolute Borel set of the same class. This result is new even if is a linear homeomorphism, and extends a result of Baars, de Groot, and Pelant which shows that the \v{C}ech-completeness of a metric space is determined by the linear structure of .
A novel algorithmic scheme for numerical solution of the 3D Poisson-Nernst-Planck model is proposed. The algorithmic improvements are universal and independent of the detailed physical model. They include three major steps: an adjustable gradient-based step value, an adjustable relaxation coefficient, and an optimized segmentation of the modeled space. The enhanced algorithm significantly accelerates the speed of computation and reduces the computational demands. The theoretical model was tested on a regular artificial channel and validated on a real protein channel-alpha-hemolysin, proving its efficiency. 相似文献
JPC – Journal of Planar Chromatography – Modern TLC - A simple and convenient thin-layer chromatography (TLC) method combined with image analysis technique was developed to determine... 相似文献
Gliomas are aggressive brain tumors that are resistant to conventional chemotherapy and radiotherapy. Much of this resistance is attributed to endogenous nitric oxide (NO). Recent studies revealed that 5‐aminolevulinic acid (ALA)‐based photodynamic therapy (PDT) has advantages over conventional treatments for glioblastoma. In this study, we used an in vitro model to assess whether NO from glioblastoma cells can interfere with ALA‐PDT. Human U87 and U251 cells expressed significant basal levels of neuronal NO synthase (nNOS) and its inducible counterpart (iNOS). After an ALA/light challenge, iNOS level increased three‐ to fourfold over 24 h, whereas nNOS remained unchanged. Elevated iNOS resulted in a large increase in intracellular NO. Extent of ALA/light‐induced apoptosis increased substantially when an iNOS inhibitor or NO scavenger was present, implying that iNOS/NO was acting cytoprotectively. Moreover, cells surviving a photochallenge exhibited a striking increase in proliferation, migration and invasion rates, iNOS/NO again playing a dominant role. Also observed was a large iNOS/NO‐dependent increase in matrix metalloproteinase‐9 activity, decrease in tissue inhibitor of metalloproteinase‐1 expression and increase in survivin and S100A4 expression, each effect being consistent with accelerated migration/invasion as a prelude to metastasis. Our findings suggest introduction of iNOS inhibitors as pharmacologic adjuvants for glioblastoma PDT. 相似文献