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31.
Adrian E. Ion Eike T. Spielberg Lorenzo Sorace Axel Buchholz Winfried Plass 《Solid State Sciences》2009,11(4):766-771
Reaction of the copper precursor [Cu(MeOsaltn)(H2O)] (H2MeOsaltn = N,N′-bis(3-methoxysalicylidene)-1,3-diaminopropane) with Ln(NO3)3·6H2O (Ln = Sm and Tb) and pyrazine-2,3-dicarboxylic acid (H2pyrdic) results in the formation of 1D zigzag chains with the general formula of [Cu(MeOsaltn)Ln(NO3)(pyrdic)]n·nDMF. X-ray crystal structures reveal that the samarium and terbium compounds are isostructural and crystalize in the orthorhombic space group Pbcn. The chains are composed of heterodinuclear copper–lanthanide building blocks which are linked by the pyrazine-2,3-dicarboxylate bridging units. Temperature-dependent susceptibility measurements indicate antiferromagnetic exchange interactions for the samarium–copper chain whereas for the terbium–copper compound ferromagnetic interactions are observed. 相似文献
32.
Chanjuan Zhang Dr. Philipp Gotico Dr. Regis Guillot Dr. Diana Dragoe Dr. Winfried Leibl Dr. Zakaria Halime Prof. Ally Aukauloo 《Angewandte Chemie (International ed. in English)》2023,62(8):e202300926
At the core of carbon monoxide dehydrogenase (CODH) active site two metal ions together with hydrogen bonding scheme from amino acids orchestrate the interconversion between CO2 and CO. We have designed a molecular catalyst implementing a bimetallic iron complex with an embarked second coordination sphere with multi-point hydrogen-bonding interactions. We found that, when immobilized on carbon paper electrode, the dinuclear catalyst enhances up to four fold the heterogeneous CO2 reduction to CO in water with an improved selectivity and stability compared to the mononuclear analogue. Interestingly, quasi-identical catalytic performances are obtained when one of the two iron centers was replaced by a redox inactive Zn metal, questioning the cooperative action of the two metals. Snapshots of X-ray structures indicate that the two metalloporphyrin units tethered by a urea group is a good compromise between rigidity and flexibility to accommodate CO2 capture, activation, and reduction. 相似文献
33.
Alexander Goller Dr. Johannes Obenauf Dr. Winfried P. Kretschmer Prof. Dr. Rhett Kempe 《Angewandte Chemie (International ed. in English)》2023,62(8):e202216464
The highly controlled and efficient polymerization of ethylene is a very attractive but challenging target. Herein we report on a Coordinative Chain Transfer Polymerization catalyst, which combines a high degree of control and very high activity in ethylene oligo- or polymerization with extremely high chain transfer agent (triethylaluminum) to catalyst ratios (catalyst economy). Our Zr catalyst is long living and temperature stable. The chain length of the polyethylene products increases over time under constant ethylene feed or until a certain volume of ethylene is completely consumed to reach the expected molecular weight. Very high activities are observed if the catalyst elongates 60 000 or more alkyl chains and the polydispersity of the strictly linear polyethylene materials obtained are very low. The key for the combination of high control and efficiency seems to be a catalyst stabilized by only one strongly bound monoanionic N-ligand. 相似文献
34.
The sugar-modified Schiff base ligand benzyl 2-deoxy-2-salicylideneamino-alpha-D-glucopyranoside H 2L, prepared by condensation of salicylaldehyde and the monomeric chitosan analogue benzyl 2-deoxy-2-amino-alpha-D-glucopyranoside, reacts with copper(II) acetate to form a self-assembled, alkoxo-bridged tetranuclear homoleptic copper(II) complex [{Cu(L)}4] (4) with Cu4O4 heterocubane core. The chiral complex 4 crystallizes in the space group P2 12 12 1. The tetranuclear complex 4 is composed of two dinuclear {Cu(L)}2 entities linked by the four mu 3-bridging C-3 alkoxide oxygen atoms of the sugar backbone. The preorganization of the dimeric {Cu(L)}2 entities is enforced by strong hydrogen bonds between the phenolate oxygen atom and the C-4 hydroxy group of the two constituting chiral monomeric building blocks. Therefore the Cu4O4 core can be classified as a type I or 2 + 4 cubane. The chirality of the structure is confirmed by circular dichroism (CD) spectra, which reveal a significant dichroism associated with the copper centered transitions at around 600 nm. Temperature dependent magnetic susceptibility measurements indicate ferromagnetic exchange interactions in complex 4. Fitting of the experimental data with a two J model based on the 2 + 4 topology ( H = - J1(S1S3 + S2S4) - J2(S1 + S3)(S2 + S4)) leads to exchange coupling constants of J1 = 64 and J2 = 4 cm(-1). The observed ferromagnetic coupling can be attributed to the very small Cu-O-Cu bridging angles within the Cu2O2 core of the constituting dimeric entities, which are a result of the conformational requirements introduced by the sugar backbone. 4 is not only the first example of an alkoxo-bridged tetranuclear copper(II) complex with Cu4O4 core representing the 2 + 4 cubane class with ferromagnetic ground state but also a rare example for the class of molecules combining a ferromagnetic ground state with optical activity. The ferromagnetic S = 2 ground state of 4 is confirmed by magnetization measurements and ESR spectroscopy. 相似文献
35.
Winfried Wendelin Hans-Wolfgang Schramm Ilse Zmölnig 《Monatshefte für Chemie / Chemical Monthly》1981,112(6-7):853-866
Action of guanidine or urea on cyclohexanone-, cyclopentanone-, cycloheptanone-and acetonecyanohydrine3 a?3 d generates very different products: 3 a reacts with guanidine inDMF to yield 1,3-diazaspiro[4.5]decane-2,4-diimine (5 a). Heating the components without solvent affords 7,14-diazadispiro[5.1.5.2]pentadecan-15-one(7)15–17, the guanidine not participating in the reaction; similarly3 b is transformed by guanidine to a pentacyclic dispirocompound (possible formulae19 and20), whereas3 d reacts to give 3,3,5,5-tetramethylpiperazine-2,6-dione(21)19. In 3-pentanone guanidine-cyanide condensates itself to give 2,4-diamino-triazine (22)21, 22. Action of urea on3 a?3 d yields the 4-imino-1,3-diazaspiroalkan-2-ones6 a?6 c and the 4-imino-5,5-dimethylimidazolidin-2-one6 d 6–8 resp. If the reaction of urea and3 d is carried out inDMF, however, 5,5-dimethyl-4-ureido-3-imidazolin-2-one (28) (or the tautomeric carbamoyliminoimidazolidinone27) is produced. The structures of the compounds prepared are proved by NMR-, IR- and mass spectra. 相似文献
36.
Siethoff C Orth M Ortling A Brendel E Wagner-Redeker W 《Journal of mass spectrometry : JMS》2004,39(8):884-889
A liquid chromatographic/tandem mass spectrometric method was developed and validated for the quantitation of capecitabine and its metabolite 5-fluorouracil in human plasma. The simultaneous determination of both analytes was achieved by a column switching method using a trapping column and two analytical columns with different stationary phases. Isocratic elution was used for the separation of capecitabine on a C18 column whereas 5-fluorouracil was separated using gradient elution on an non-polar carbon phase. The calibration curves were linear for both compounds with a correlation factor (R2) > 0.9993 for 5-fluorouracil and >0.9942 for capecitabine. The assay was validated in the concentration range 5.00-1000 ng ml(-1) for both compounds. The intra-day precision was better than 10% for 5-fluorouracil and better than 11% for capecitabine whereas the inter-day precision was better than 8% for 5-fluorouracil and better than 14% for capecitabine. 相似文献
37.
CHANGES IN TRANSMISSION CHARACTERISTICS OF POLYMETHYLMETHACRYLATE AND CELLULOSE (III) ACETATE DURING EXPOSURE TO ULTRAVIOLET LIGHT 总被引:2,自引:0,他引:2
Steef F. Steeneken Anita G. J. Buma Winfried W. C. Gieskes 《Photochemistry and photobiology》1995,61(3):276-280
Abstract— Ultraviolet-transparent polymethylmethacrylate (PMMA) and cellulose (III) acetate (CA) (often used as a cut-off filter in UVB [280–320 nm] biological effect studies) were exposed to a 20 W Philips TL 12 lamp to examine changes in transmission characteristics due to UVB exposure. Transmission of UVB and biologically weighted UVB (UVBE(DNA) ) through PMMA were similar, 88.3 and 83.5%, respectively. The absorption characteristics of PMMA did not change with time at any of the UV irradiance levels applied. However, transmission of UVB and UVBBE(DNA) ) through new CA differed considerably: 59% versus only 11%, respectively. Also, spectral absorption characteristics changed with time due to degradation of CA, at a rate that was dependent on the incident UVB irradiance. The decrease in transmission through CA of both UVB and UVBE(DNA) can be described by exponential functions. The CA that was wrapped around the UV lamp showed dramatic changes in UV absorption over the first few hours of use. However, when CA was placed at a longer distance from the light source initial degradation was less. It is concluded that PMMA can be applied in UV effect studies as a reasonable alternative for quartz. The CA should, however, be used with care, because the large transmission decreases that were observed strongly hamper an accurate calculation of (biologically weighted) UVB dose rates. 相似文献
38.
39.
4- and 4-methoxy-, 4-hydroxy- and 2-hydroxychalcone4 e,k,f andg, respectively, are transformed by action of guanidine in benzene to yield 4-(4-methoxyphenyl)-6-phenyl-2-pyrimidinamine (6 e=6 k) and hydroxyphenylpyrimidinamines6 f andg, respectively. In contrast, 4- and 4-chlor-, 4-brom- and 4-phenylchalcone4 h,l–n resp. react with guanidine under analogous conditions to give 4,6-diaryl-1,4-dihydro-2-pyrimidinamines5 h,l–n. The bases5 h,l–n also tend to aromatize, but they can be stabilized by transformation into salts5 h,l–n · HCl with hydrochloric acid. Heating of5 n inDMF under atmospheric oxygen yields 4-(4-biphenyl)-6-phenyl-2-pyrimidinamine (6 n). Action of guanidine on 4-nitrochalcone4 o in chloroform affords 2-amino-4-nitrophenyl-6-phenyl-tetrahydro-4-pyrimidinol8 o, which is transformed by hydrochloric acid into 6-nitrophenyl-dihydropyrimidinamine-hydrochloride5 o · HCl. Treating of the latter with sodiummethylat in methanol yields the very stable dihydropyrimidinamine5 o. Action of guanidine on 4-chlor- and 4-bromchalcone4 h andm respectively (in addition to5 h andm) yields 2,4,6,8-tetraaryl-1,4-dihydro-2H-pyrimido[1,2-a]pyrimidines7 h andm, respectively.
Herrn Prof. Dr.Erwin Schauenstein mit den besten Wünschen zum 65. Geburtstag gewidmet. 相似文献
40.