Relaxation dynamics of a broadband nanosecond acoustic pulse in a bubbly medium

The first experimental observation of the propagation dynamics of a short broadband acoustic pulse in a resonance medium with gas bubbles is carried out. The probing pulse is generated using the optoacoustic effect. It is shown that the theory of short pulse propagation in media with generalized resonance relaxation adequately and accurately describes the dynamics of short pulse dispersion. A possibility to determine the relaxation and resonance parameters of media by the pulsed testing technique is demonstrated.     

Spatial regularities in the effect of locking of photon echo signals and associative optical memory

The efficiency of suppression of the generation of a photon echo response depending on the mutual spatial orientation of gradients of external nonumform electric fields acting on a resonant medium is studied. The possibility of creating an associative memory where the mutual orientation of the gradients of external electric fields is an associative key is discussed.     

Two-stream-like mechanism of zonal-flow generation by Rossby waves in a shallow rotating fluid

It is shown that the small-scale Rossby waves in a shallow rotating fluid placed in a gravitational field can generate large-scale zonal flows by means of a two-stream-like mechanism. This mechanism is revealed under the conditions when the Lighthill instability criterion is not satisfied. The text was submitted by the authors in English.     

Interaction of cationic 5,10,15,20-tetrakis(4-N-methyl pyridyl) porphyrin with mono-and polynucleotides: A study by picosecond fluorescence spectroscopy

The interaction of water-soluble cationic 5,10,15,20-tetrakis(4-N-methyl pyridyl) porphyrin (H₂TMPyP4) with some mono-and polynucleotides is studied by time-resolved and steady-state fluorescence spectroscopy, as well as by steady-state absorption spectroscopy. The fluorescence decay kinetics are analyzed by reconstructing the decay time distributions, which made it possible to describe in more detail than previously the complexes formed due to the interaction. The main effect of binding of H₂TMPyP4 adenosine 5′-monophosphate and to poly(dA-dT)₂ is shown to be an increase in the fluorescence lifetime from 4.6 ns in the solution to 8.3 and 12.3 ns, respectively. This effect is explained by a less polar (in comparison with water) environment of porphyrin in complexes, which leads to a decrease in the quenching action of the intramolecular charge transfer state between the porphyrin macrocycle and methyl pyridyl groups. In the case of complex formation with guanine-containing nucleotides (guanosine 5′-monophosphate and poly(dG-dC)₂), the effect of decrease in the quenching action of the intramolecular charge transfer state caused by a decrease in the medium polarity is superimposed by a stronger effect of decrease in the fluorescence lifetime of porphyrin as a result of intermolecular electron transfer from guanine to excited porphyrin. A high sensitivity of this intermolecular quenching to the mutual arrangement of the electron donor and the electron acceptor makes it possible to reveal four types of complexes between H₂TMPyP4 and guanosine 5′-monophosphate, which differ in the positions of four broad peaks in the porphyrin fluorescence decay time distribution (0.1, 0.7, 2.4, and 6.1 ns). For the complex with poly(dG-dC)₂, a narrow peak at 2.8 ns prevails in the fluorescence decay time distribution, with the contributions from two additional narrow peaks at 1.0 and 6.2 ns being small.     

Exact solution of a quasipotential equation that describes a bound state of spinor particles

Theoretical and Mathematical Physics -     

Neutron interferometry in gravitational field with torsion

We consider the possibility of finding experimental evidence of the fifth force with the measurement of a phase shift of neutron beams via an interferometric apparatus and also a possible rotation of the polarization plane of polarized neutron beams when torsion is introduced in a gravitational field.     

Bipyridinophane‐containing conjugated polymers modulated with an intramolecular aromatic C?H/π interaction

Bipyridinophane–fluorene conjugated copolymers have been synthesized via Suzuki and Heck coupling reactions from 5,8‐dibromo‐2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane and suitable fluorene precursors. Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P7 ) exhibits large absorption and emission redshifts of 20 and 34 nm, respectively, with respect to its planar reference polymer Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐1,4‐(2,5‐dimethylbenzene)] ( P11 ), which bears the same polymer backbone as P7 . These spectral shifts originate from intramolecular aromatic C? H/π interactions, which are evidenced by ultraviolet–visible and ¹H NMR spectra as well as X‐ray single‐crystal structural analysis. However, the effect of the intramolecular aromatic C? H/π interactions on the spectral shift in poly[9,9‐dihexylfluorene‐2,7‐yleneethynylene‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P10 ) is much weaker. Most interestingly, the quenching behaviors of these two conjugated polymers are largely dependent on the polymer backbone. For example, the fluorescence of P7 is efficiently quenched by Cu²⁺, Co²⁺, Ni²⁺, Zn²⁺, Mn²⁺, and Ag⁺ ions. In contrast, only Cu²⁺, Co²⁺, and Ni²⁺ ions can partially quench the fluorescence of P10 , but much less efficiently than the fluorescence of P7 . The static Stern–Volmer quenching constants of Cu²⁺, Co²⁺, and Ni²⁺ ions toward P7 are of the order of 10⁶ M^?1, being 1300, 2500, and 37,300 times larger than those of P10 , respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4154–4164, 2006