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81.
Arkady I. Gusev William R. Wilkinson Andrew Proctor D. M. Hercules 《Fresenius' Journal of Analytical Chemistry》1996,354(4):455-463
The protocol and various matrices were examined for quantification of biomolecules in both the low ca. 1200 amu and mid mass 6000–12000 amu ranges using an internal standard. Comparative studies of different matrices of MALDI quantitative analysis showed that the best accuracy and standard curve linearity were obtained for two matrices: (a) 2,5-dihydroxybenzoic acid (DHB) combined with a comatrix of fucose and 5-methoxysalicylic acid (MSA) and (b) ferulic acid/fucose. In the low mass range, the quantitative limit was in the 30 fmol range and in the mid mass range the quantitative limit was in the 250 fmol range. Linear response was observed over 2–3 decades of analyte concentration. The relative error of the standard curve slope was 1.3–1.8% with correlation coefficients of 0.996–0.998.The main problem for quantitative measurement was suppression of the signal of the less concentrated component (analyte or internal standard) by the more concentrated component. The effect was identified with saturation of the matrix by the analyte. The threshold of matrix saturation was found to be in the range of 1/(3000–5000) analyte/matrix molar ratio. To avoid matrix saturation the (analyte+internal standard) to matrix molar ratio should be below this threshold. Thus the internal standard concentration should be as low as possible.DHB/MSA/fucose and ferulic acid/fucose matrices demonstrated good accuracy and linearity for standard curves even when the internal standard had chemical properties different from the analyte. However, use of an internal standard with different chemical properties requires highly stable instrumental parameters as well as constant (analyte+internal standard)/matrix molar ratio for all samples. 相似文献
82.
R.J. Grant C.G. Johnson D.H. Wilkinson 《International Journal of Heat and Fluid Flow》1983,4(4):239-245
A single stage model turbine has been provided with a set of three special inlet sections which include backward facing steps to produce casing separations of varying size upstream of the stator blades. In addition each inlet section is equipped so as tc be able to emit a swirling jet which simulates the tip leakage jet from a preceeding stage. It is demonstrated that there is a substantial efficiency penalty associated with the stepped casing and its attendant separation and that a small mitigation is brought about by the tip leakage jet, by re-energising the fluid in the separation zone 相似文献
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R.T. Wilkinson 《Journal of sound and vibration》1984,95(1):55-63
The literature on the effects of noise on sleep is searched for evidence on individual differences along the dimensions of age, sex, occupation, personality, neuroticism, and mental health. With the exception of age, little firm evidence is found. Thus there remains a need to establish at better than the anecdotal level whether or not real individual differences exist. 相似文献
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本文利用中心流面法的概念,指出叶轮机械的设计白变数在内、外环壁面上应有附加的限制条件,并导得其具体简明方程。同时,还定性地分析了S1流面的翘曲情况。 相似文献
89.
Lee Galyer Konstantinos Mertis Geoffrey Wilkinson 《Journal of organometallic chemistry》1975,85(3):C37-C38
A new synthesis of hexamethyltungsten involves the reaction of WCl6 and AlMe3, while interaction of AlMe3 and ReOMe4 gives ReMe6; a dioxorhenium(VII) methyl, ReO2 Me3, is reported. 相似文献
90.