Perforation of steel and polycarbonate plates by tumbling projectiles

An experimental investigation to assess the effect of tumbling by hard-steel, blunt-faced cylindrical projectiles on the impact response of thin 4130 steel and polycarbonate target plates was performed. Deformation and failure phenomena were observed and discussed; comparisons of the results with analytical models and numerical stimulation, described in a previous paper, were also performed for the steel targets. The final velocity of the projectile and the crater length in the target were correlated with the striker impact angle (or yaw angle with a zero oblique angle); reasonable agreement was attained among the experimental, analytical and numerical results. It was found that an increase of the impact angle can increase the velocity drop and the crater length markedly. The increase tends to be stabilized after the impact angle exceeds 50° and the consequences in such a case are almost the same as in side-on impact.     

Stereoselectivity in Reactions of Metal Complexes. Part XI. 2,6-Bis(pyrrolidin-2-yl)pyridine: Synthesis and resolution of the meso and the optically active isomers. Complex formation with copper(II) ion in aqueous solution

The new linear triamine 2,6-bis(pyrrolidin-2-yl)pyridine ( II ) has been synthesized, and the (R, S)-, (R, R)-, and (S, S)-isomers have been separated. Compared to other triamines showing a similar structure, these new ligands form very stable Cu²⁺ complexes. No significant difference is observed between the meso and the racemic forms for their binary or ternary mixed-ligand complexes with the amino acids alanine and proline.     

New disc-shaped mesogens based on pentakis(phenylethynyl)benzene derivatives

First examples of amphiphilic alkyl pentakis(phenylethynyl)benzene ethers containing functional groups at the terminal position of their alkoxy chains were synthesized by etherification of pentabromophenol with 11-bromoundecan-1-ol and 11-bromoundecanoic acid ethyl ester, respectively, and subsequent palladium catalyzed, fivefold coupling reactions with the substituted phenylacetylene. Two undecanoic acid derivatives with different pentakis(phenylethynyl)phenoxy substituents in the ω-position were prepared by ester cleavage from the corresponding ethyl esters. The thermal behaviours of five penta-alkynes in their pure states, as well as of their charge transfer complexes formed from mixtures with 2,4,7-tri-nitrofluorenone, were examined.