含异亚丙基聚亚胺醚酮的合成与性能

首先通过Friedel-Crafts酰基化反应得到1,4-双-(4′-溴苯酰基)苯,经两步合成芳香二胺2,2-双-[4-(4-氨基苯氧基)苯基]丙烷,以1,4-双-(4′-溴苯酰基)苯和2,2-双-[4-(4-氨基苯氧基)苯基]丙烷为单体,以三(二亚苄基丙酮)二钯为催化剂,1.1′-联萘-2.2′-二苯膦(BINAP)为配体,由钯催化的胺基化反应缩聚合成了高分子量含异亚丙基聚亚胺醚酮(pr-PIEK),Mn=5.15×104、Mw=1.26×105.其结构由红外、核磁氢谱和元素分析表征,表征结果与目标结构吻合良好.通过XRD、DSC和TG等对pr-PIEK的主要性能进行分析,结果表明pr-PIEK为无定形态,表现出良好的热稳定性(高的热分解温度TD>450℃)、力学性能(拉伸强度为72.76 MPa、拉伸模量为1013.63 MPa、断裂伸长率为10.32%)和较好的溶解性能,pr-PIEK在室温条件下可溶解在普通有机溶剂氯仿中,50℃溶于丙酮.     

超高效液相色谱-串联质谱法测定药材牛大力中刺桐碱、芒柄花素和高丽槐素

采用超高效液相色谱-串联质谱联用技术,建立了同时测定中药材牛大力中刺桐碱、芒柄花素和高丽槐素的分析方法.采用Waters ACQUITY UPLC BEH C18色谱柱(100 mm×2.1 mm,1.7 μm),以甲醇-0.1％甲酸水溶液为流动相,梯度洗脱;质谱采用电喷雾电离,负离子源,以多反应监测模式检测,外标法定...     

Component Analysis and Anti-Colorectal Cancer Mechanism via AKT/mTOR Signalling Pathway of Sanghuangporus vaninii Extracts

Sanghuangporus vaninii (Ljub.) L.W. Zhou & Y.C. Dai (SV) is a major cultivar of Sanghuang, which is well known as an excellent anti-tumour drug and reaches the mainstream market in China. Water, 60% ethanol and 95% ethanol were used to extract the drug, and three kinds of polar extracts were obtained separately. Compared with water extracts and 95% ethanol extracts, the 60% ethanol extract had the highest flavonoid content, and its polysaccharide content was greater than that in the 95% ethanol extract and lower than that in the water extract. Its essential components were phenolics whose majority were phenolic acids, flavonoids and phenylpropanoids. This extract has better inhibition effects on the proliferation of SW480 human colon cancer cells, inducing cell apoptosis and blocking G2/M period cells. It can significantly inhibit gene expression and reduce the activation of the AKT/mTOR signalling pathway. The anti-cancer activity of the 60% ethanol extract is satisfactory and may be a result of the combined effects of polysaccharides and flavonoids. The data suggest that the 60% ethanol extract can be used as an adjuvant for chemotherapy and as a potential anti-cancer agent with broad development prospects.     

柔性液晶微透镜阵列的制备与性能研究

针对集成成像视场角狭小的问题,设计并制备了一种柔性圆孔驱动电极控制液晶分子偏转的可弯曲和焦距可调的柔性液晶微透镜阵列.利用光刻技术在柔性ITO基板表面刻蚀并形成规则的圆孔阵列电极,旋涂工艺制备柔性聚酰亚胺(PI)膜层,PI膜层经60℃加热5 min后,再利用等离子体在功率630 W条件下处理5 min固化成PI取向层....     

Comparative Analysis of the Phenolic Profile of Lycium barbarum L. Fruits from Different Regions in China

Lycium barbarum L. (LB) fruits have high nutritive values and therapeutic effects. The aim of this study was to comprehensively evaluate the differences in phenolic composition of LB fruits from different geographical regions. Different methods of characterization and statistical analysis of data showed that different geographic sources of China could be significantly separated from each other. The highest total phenolic compound (TPC) content was observed in LB fruits from Ningxia (LBN), followed by those from Gansu (LBG) and Qinghai (LBQ). The Fourier transform infrared (FTIR) spectra of LB fruits revealed that LBQ had a peak at 2972 cm⁻¹ whereas there was no similar peak in LBG and LBQ. A new HPLC method was established for the simultaneous determination of 8 phenolic compounds by quantitative analysis of multiple components by a single marker (QAMS), including 4 phenolic acids (chlorogenic acid, caffeic acid, 4-hydroxycinnamic acid, and ferulic acid), 1 coumarin (scopoletin), and 3 flavonoids (kaempferol-3-O-rutinoside, rutin, and narcissoside). It was showed that rutin was the most dominant phenolic compound in LBQ, although the average content of 4 phenolic acids was also high in LBQ, and scopoletin was the richest in LBG. UHPLC-Q-TOF-MS was used to qualitatively analyze the phenolics, which showed LBN was abundant in phenolic acids, LBQ was rich in flavonoids, and coumarins were the most plentiful in LBG. In conclusion, this study can provide references for the quality control and evaluation of phenolics in LB fruits and their by-products.     

基于红失谐高斯光束的冷原子束流长距离传输

提出了一种利用红失谐高斯光束偶极力实现二维磁光阱长距离传输冷原子束的方案.利用二能级原子所受散射力公式分析并构造了87 Rb原子在光偶极阱二维磁光阱(2D-ODT MOT)中的受力公式,考虑了原子与背景气体碰撞的影响,利用四阶龙格-库塔法求解原子运动方程,获得原子的运动轨迹,统计并求出原子在不同高斯光束失谐以及功率条件作用下进入差分泵浦范围的原子数.实验验证了在红失谐高斯光束与原子束推送光相互组合的4种工作状态下科学实验腔中磁光阱冷原子装载情况.理论与实验结果表明:基于红失谐高斯光束的二维磁光阱长距离传输冷原子束的效果提升显著,科学腔原子装载效率明显提升、原子数目明显增加.     

成桩后黏性土中超孔压和有效应力试验研究

针对预制桩沉桩挤土效应问题,采用现场原位试验和数值模拟方法,分析了桩土界面超孔压和竖向有效应力随时间的变化规律,并应用水力压裂理论、孔穴扩张理论和修正剑桥(modified Cam-clay, MCC) 模型,揭示了成桩后桩周土体固结过程的超孔压沿桩长的分布形式。结果表明：桩周超孔压大小同孔压与传感器入土深度成正比;在外载荷作用下,黏性土中超孔压和竖向有效应力分别随时间呈“增–减–平”和“平–增–平”的三段式变化趋势;成桩后约25天,超孔压基本消散完毕,竖向有效应力趋于稳定最大值;基于修正理论公式的数值模型得出,不同载荷下,桩侧中下部出现负超孔压,距桩的水平距离和距桩端竖向距离越小,超孔压越大。可为同类静压沉桩挤土效应问题提供参考依据。

     

Highly Stable Photo-Assisted Zinc-Ion Batteries via Regulated Photo-Induced Proton Transfer

Photo-assisted ion batteries utilize light to boost capacity but face cycling instability due to complex charge/ion transfer under illumination. This study identified photo-induced proton transfer (photo-induced PT) as a significant process in photo-(dis)charging of widely-used V₂O₅-based zinc-ion batteries, contributing to enhanced capacity under illumination but jeopardizing photo-stability. Photo-induced PT occurs at 100 ps after photo-excitation, inducing rapid proton extraction into V₂O₅ photoelectrode. This process creates a proton-deficient microenvironment on surface, leading to repetitive cathode dissolution and anode corrosion in each cycle. Enabling the intercalated protons from photo-induced PT to be reversibly employed in charge-discharge processes via the anode-alloying strategy achieves high photo-stability for the battery. Consequently, a ~54 % capacity enhancement was achieved in a V₂O₅-based zinc-ion battery under illumination, with ~90 % capacity retention after 4000 cycles. This extends the photo-stability record by 10 times. This study offers promising advancements in energy storage by addressing instability issues in photo-assisted ion batteries.     

Identifying Active Sites of Pt-NiFe LDH Catalysts for CO Oxidation Using In-Situ DRIFTS with Multiple Microscopy and Spectroscopy Techniques

Layered double hydroxide (LDH) nanostructures are commonly used to study the interfacial effects of Pt-based catalysts in CO oxidation. However, the specific role and detailed intermediates involved in CO oxidation remain unclear. Density functional theory (DFT) predicted that NiFe LDH loaded with single Pt atoms would exhibit satisfactory CO oxidation activity. On this basis, we prepared Pt₁NiFe LDH catalysts with various Fe : Ni ratios by using the one-pot method and achieved favorable dispersion of single Pt atoms. Pt₁/FN-1, which had the optimal Fe : Ni ratio (1 : 1), exhibited satisfactory catalytic performance for CO oxidation and a high turnover frequency, as determined through DFT calculations and experimental characterization. In-situ diffuse reflectance infrared Fourier transform spectroscopy confirmed that CO directly reacted with Pt₁/FN-1 to produce CO₂ and that introduced O₂ formed bicarbonate species to produce CO₂ together with the adsorbed CO on Pt₁ sites. Overall, our work provides new insights into the catalytic mechanism of the well-known Pt₁NiFe LDH catalysts in CO oxidation.     

固相萃取-超高效液相色谱-串联质谱法检测环境水体中18种农药残留

建立了固相萃取-超高效液相色谱-串联质谱(SPE-UPLC-MS/MS)同时检测环境水体中不同极性范围的18种农药残留的分析方法。样品经大体积固相萃取装置,以2 mL/min的速率通过Cleanrt■-PEP固相萃取柱进行净化和富集,浓缩50倍后结合UPLC-MS/MS检测,外标法定量。研究表明,目标化合物在0.5～50μg/L范围内线性关系良好,线性相关系数(R²)≥0.995;在10、100和1 000 ng/L 3个添加水下,18种农药在3种不同环境水体中的平均回收率为71.3%～105.9%,相对标准偏差(RSD,n=5)为1.3%～9.9%;定量限(LOQ)均为10 ng/L。该方法应用于泰安市区周围水环境的检测,各采集位点均未检出农药残留。该方法具有净化效果好、通用性强、灵敏度高、准确度高和操作简单等优点,适用于环境水体中18种农药的残留检测。