炸药爆温的光纤测温法测量

本文阐述了光纤测温技术依据的原理,给出了多通道瞬时光纤测温装置的构成。利用该装置对液体炸药硝基甲烷的实际爆轰温度及其光谱发射率进行了实验测量,结果分别为3700±100（K）和0.71±0.15。     

gem-Difunctionalization of α-diazoarylketones with diaryldiselenides and N-halosuccinimides: facile synthesis of α-halo-α-arylseleno ketones

Molecular Diversity - An efficient synthesis of α-halo-α-arylseleno ketones has been developed via gem-difunctionalization of α-diazoarylketones with diaryldiselenides and...     

Ruthenium(II)/Chiral Brønsted Acid Co‐Catalyzed Enantioselective Four‐Component Reaction/Cascade Aza‐Michael Addition for Efficient Construction of 1,3,4‐Tetrasubstituted Tetrahydroisoquinolines

An elegant synergistic catalytic system comprising a ruthenium complex with a chiral Brønsted acid was developed for a four‐component Mannich/cascade aza‐Michael reaction. The ruthenium‐associated ammonium ylides successfully trapped with in situ generated imines indicates a stepwise process of proton transfer in the ruthenium‐catalyzed carbenoid N?H insertion reaction. The different decomposition abilities of various ruthenium complexes towards diazo compounds were well explained by the calculated thermodynamic data. The transformation features a mild, rapid, and efficient method for the synthesis of enantiomerically pure 1,3,4‐tetrasubstituted tetrahydroquinolines bearing a quaternary stereogenic carbon center from simple starting precursors in moderate yields with high diastereo‐ and enantioselectivity.     

A Facile Access to Polyfunctional Oxygen‐containing Heterocycles via Intramolecularly Formed Protic Oxonium Ylide Trapping Processes

Based on the assumption that intramolecularly formed protic oxonium ylides could be trapped by electrophiles, transition‐metal‐catalyzed reactions of diazoesters bearing a primary hydroxy group with electron‐deficient aldehydes and isatins were examined. Good to high chemo‐ and diastereoselectivities were achieved with reactions catalyzed by Cu(hfacac)₂. The reactions were assumed to occur via tandem intramolecular protic oxonium ylide formation and subsequent aldol‐type addition. They not only provided an efficient entry to 3‐substituted 1,4‐dioxan‐2‐one heterocycles with at least one quaternary carbon center but also provided experimental evidence for a stepwise pathway for the transition‐metal‐catalyzed intramolecular O? H insertion of diazo compounds.     

Recent advances in metal carbenoid mediated nitrogen-containing zwitterionic intermediate trapping process

Zwitterionic intermediates generated from metal carbenoids and compounds containing enamine units belong to a class of highly active synthetic intermediates that undergo different types of transformations. They can undergo rapid proton transfer to afford C–H functionalization products, or undergo intramolecular trapping process to give [3+2] annulation products. Recently, by taking advantage of its unique electronic feature, novel transformations have been developed by applying suitable electrophiles to trap such type of zwitterionic intermediates. The successful trapping process offers a powerful strategy for the effective construction of diversified nitrogen-containing molecules.     

Estimation of radiative properties and temperature distributions in coal-fired boiler furnaces by a portable image processing system

This paper presented an experimental investigation on the estimation of radiative properties and temperature distributions in a 670 t/h coal-fired boiler furnace by a portable imaging processing system. The portable system has been calibrated by a blackbody furnace. Flame temperatures and emissivities were measured by the portable system and equivalent blackbody temperatures were deduced. Comparing the equivalent blackbody temperatures measured by the portable system and the infrared pyrometer, the relative difference is less than 4%. The reconstructed pseudo-instantaneous 2-D temperature distributions in two cross-sections can disclose the combustion status inside the furnace. The measured radiative properties of particles in the furnace proved there is significant scattering in coal-fired boiler furnaces and it can provide useful information for the calculation of radiative heat transfer and numerical simulation of combustion in coal-fired boiler furnaces. The preliminary experimental results show this technology will be helpful for the combustion diagnosis in coal-fired boiler furnaces.     

折射率失配对双光子三维光存储中像差的影响

双光子吸收三维光信息存储是实现高密度光存储的重要方法。三维数据写入过程中光束需经过两层不同的介质(如空气和存储材料),对像差和存储效果产生很大的影响,因此在理论和实验上分析系统各项光学参量对折射率失配引起的像差和存储效果的影响具有很大的意义。首先建立光学存储系统模型,在平行平板条件下,利用波像差函数推导展开,获得五项初级(赛德耳)像差,即球差、彗差、像散、场曲、畸变,然后对于存储材料在水平和倾斜两种情况下对初级像差进行模拟计算与分析,理论模拟与实验表明:物镜的数值孔径越大,像差随着存储深度增加而增大的速度就越快。     

Efficient synthesis of α-aryl serine derivatives via three-component reactions of aryldiazoacetates,anilines and formaldehyde

A three-component reaction based on trapping of ammonium ylides with formaldehyde was first reported. This reaction offers a new strategy for the synthesis of α-aryl serine derivatives and can be extended to the preparation of α-aryl threonine derivatives. Synthetic application of the three component reaction for the preparation of hydroquinoxaline derivative was also demonstrated.     

基于DVD光头的双光子光致漂白三维光存储

基于现有的DVD光头物镜与音圈电机，根据光致漂白的双光子吸收气维光信息存储原理，以钛蓝宝石飞秒脉冲激光进行双光子光信息写入和读出，利用音圈电机进行选层，在新型光致漂白材料二苯乙烯衍生物中进行光致漂白二进制编码信息的存储和读出实验研究；实现了三层光信息存储，信息点间距和信息层间距分别为4μm和15μm；用Matlab软件读出信息的信号强度并对其进行了识别，识别结果与写入的二进制编码信息完全一致。实验证明了用DVD光头进行双光子三维光数据存储的可行性，表明双光子吸收光致漂白技术可以与现有CD／DVD兼容，为实现多层高密度和超高密度光信息存储打下基础。