全文获取类型
收费全文 | 252篇 |
免费 | 23篇 |
国内免费 | 45篇 |
专业分类
化学 | 219篇 |
晶体学 | 1篇 |
力学 | 10篇 |
综合类 | 2篇 |
数学 | 13篇 |
物理学 | 75篇 |
出版年
2024年 | 2篇 |
2023年 | 16篇 |
2022年 | 19篇 |
2021年 | 25篇 |
2020年 | 29篇 |
2019年 | 13篇 |
2018年 | 17篇 |
2017年 | 11篇 |
2016年 | 10篇 |
2015年 | 11篇 |
2014年 | 16篇 |
2013年 | 20篇 |
2012年 | 14篇 |
2011年 | 15篇 |
2010年 | 9篇 |
2009年 | 15篇 |
2008年 | 8篇 |
2007年 | 11篇 |
2006年 | 5篇 |
2005年 | 4篇 |
2004年 | 7篇 |
2003年 | 8篇 |
2002年 | 5篇 |
2001年 | 2篇 |
1999年 | 6篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1995年 | 6篇 |
1994年 | 6篇 |
1993年 | 2篇 |
1990年 | 1篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1971年 | 1篇 |
排序方式: 共有320条查询结果,搜索用时 15 毫秒
1.
Enantioselective catalytic trimethylsilylcyanations of aldehydes with 48% to 92% e.e. have been studied using the novel Ti-chiral Schiff base complexes. We have found that the catalyst led to high enantoselectivity when the molar ratio of the Schiff base 1 to Ti(O-i-Pr)4 was 2:1. 相似文献
2.
后处理温度对ZrO2气凝胶超细粉织构和结构的影响 总被引:5,自引:0,他引:5
运用神效儿宝治疗小儿厌食症210例,总有效率为95.2%,显效率为62.4%。该药使用、携带方便、见效快,疗效短,无毒副作用。实验证明,该药能显著提高胃蛋白酶含量,减慢肠管推进性运动,提高动物耐疲劳、耐缺氧能力,提高巨噬细胞吞噬率及血清补C3含量,且无毒副。作用 相似文献
3.
A novel hyperbranched polyester acrylate (HPEA) was synthesized based upon ethylenediamine tetraacetic acid as a “core” molecule, 5‐hydroxyisophthalic acid as an AB2 monomer, and 2‐hydroxyethyl acrylate as an endcapping reagent. The obtained oligomer has an unsaturation concentration of 4.10 mmolC?C g?1 measured by nuclear magnetic resonance and a wide molecular weight distribution of 1.64 measured by gel permeation chromatography. The two‐photon absorption (TPA) photopolymerization of HPEA under the exposure of a Ti : sapphire femtosecond laser with a wavelength of 800 nm was investigated through laser exposure dose‐dependant spatial resolutions of its resins. The TPA photopolymerization thresholds at the range 1.6–4.3 × 107 mJ cm?2, and exposure dose windows at the range 3.4–4.3 for three formulations were determined. A spatial resolution of 0.85 μm was obtained through the TPA photopolymerization of the formulation containing 1 wt% photoinitiator and 0.3 wt% photoinhibitor. A diffraction grating and real three‐dimensional coupled gear wheel created by TPA photopolymerization were described to demonstrate the unique capability of HPEA in microfabrications. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
4.
5.
6.
Shipeng Wu Yinghao Wang Prof. Qiue Cao Prof. Qihua Zhao Dr. Wenhao Fang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(9):3019-3028
High-surface-area mesoporous CeO2 (hsmCeO2) was prepared by a facile organic-template-induced homogeneous precipitation process and showed excellent catalytic activity in imine synthesis in the absence of base from primary alcohols and amines in air atmosphere at low temperature. For comparison, ordinary CeO2 and hsmCeO2 after different thermal treatments were also investigated. XRD, N2 physisorption, UV-Raman, H2 temperature-programmed reduction, O2 temperature-programmed desorption, EPR spectroscopy, and X-ray photoelectron spectroscopy were used to unravel the structural and redox properties. The hsmCeO2 calcined at 400 °C shows the highest specific surface area (158 m2 g−1), the highest fraction of surface coordinatively unsaturated Ce3+ ions (18.2 %), and the highest concentration of reactive oxygen vacancies (2.4×1015 spins g−1). In the model reaction of oxidative coupling of benzyl alcohol and aniline, such an exceptional redox property of the hsmCeO2 catalyst can boost benzylideneaniline formation (2.75 and 5.55 mmol h−1 based on >99 % yield at 60 and 80 °C, respectively) in air with no base additives. It can also work effectively at a temperature of 30 °C and in gram-scale synthesis. These are among the best results for all benchmark ceria catalysts in the literature. Moreover, the hsmCeO2 catalyst shows a wide scope towards primary alcohols and amines with good to excellent yield of imines. The influence of reaction parameters, the reusability of the catalyst, and the reaction mechanism were investigated. 相似文献
7.
A new family of univariate exponential slash distribution is introduced, which is based on elliptical distributions and defined by means of a stochastic representation as the scale mixture of an elliptically distributed random variable with respect to the power of an exponential random variable. The same idea is extended to the multivariate case. General properties of the resulting families, including their moments and kurtosis coefficient, are studied. And inferences based on methods of moment and maximum likelihood are discussed. A real data is presented to show this family is flexible and fits much better than other related families. 相似文献
8.
9.
10.
Optically active 1, 2-Diphenylethylendiamine(9) is obtained by asymmetric oxidative coupling reaction of d-camphor ketimine anion (4). Among various oxidating agents, TiCl(Oipr)3 is better than l2, Br2, CuCl2, FeCl3 and BrCH2CH2Br. 相似文献