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131.
Fluorescent reagent sodium 1-naphthylamine diacetate (NADA) was assembled onto gold electrodes via its electrostatic interaction with cysteine (Cys) that was directly assembled on the gold electrode surface. Formation of the self-assembled bilayers was confirmed and primarily characterized by cyclic voltammetry and X-ray photoelectron spectra (XPS). The Cys modification of the gold electrode prevented direct adsorption of NADA onto the gold electrode and hence eliminated fluorescence quenching by gold. Strong fluorescence was observed from the NADA self-assembled bilayers at gold surface and was highly efficiently quenched by Cu2+ that allowed for an extremely highly sensitive detection of Cu2+ with a detection limit of 0.2 ppt and quantitative detection range of 0.5–9 ppt. The fluorescence from NADA/Cys/Au can be easily regenerated and therefore the present report showed a reusable method for immobilizing reagent in fabricating fluorescent chemosensors. 相似文献
132.
We compute the curvature of the -metric on the direct image of a family of Hermitian holomorphic vector bundles over a family of compact Kähler manifolds. As an application, we show that the -metric on the direct image of a family of ample line bundles over a family of abelian varieties and equipped with a family of canonical Hermitian metrics is always projectively flat. When the parameter space is a compact Kähler manifold, this leads to the poly-stability of the direct image with respect to any Kähler form on the parameter space.
133.
The study of the sugar-metal ion interactions remains one of the main objectives of carbohydrate coordination chemistry because the interactions between metal ions and carbohydrates are involved in many biochemical processes. This paper presents a comparison of coordination structures of erythritol with alkaline-earth-metal and lanthanide chloride and nitrate in the solid state using FT-IR and X-ray diffraction. Neutral, nondeprotonated erythritol (E) reacts with CaCl(2) to give three CaCl(2)(-)erythritol (CaE(I), CaE(II), CaE(III)) complexes, showing that three of the five general features of calcium-carbohydrate complexes deduced in the reference encounter contrary examples. Different coordination structures have been observed for calcium and lanthanide chloride and nitrates. The coordination of carbohydrates to metal ions is complicated, and erythritol, chloride ions, nitrates, water molecules, and ethanol (crystallization medium and reaction solvents) have the chance to coordinate to metal ions. IR spectral results show that different lanthanide ions, from LaCl(3) to TbCl(3), have similar coordination structures with erythritol. The results show that erythritol can act as two bidentate neutral ligands (CaE(I), CaE(II), CaE(III), CaEN, PrE, NdE) or as a three-hydroxyl donor (NdEN). The IR results are consistent with the crystal structures. 相似文献
134.
具时滞的奇异(n-1,1)共轭边值问题的多重正解 总被引:2,自引:0,他引:2
WengPeixuan TianYanling 《高校应用数学学报(英文版)》2000,15(2):128-136
Abstract. This paper discusses the singular (n-l, 1) conjugate boundary value problem as fol-lows by using a fixed point index theorem in cones 相似文献
135.
针对关键生命线系统,如电网、供水网、供气网、交通网、通信网等的一些共性特征,建立一个普适性的灾害蔓延动力学模型. 这个模型考虑网络结点的自修复功能、灾害蔓延机制和内部随机噪声,并研究自修复因子、延迟时间因子和噪声强度三个重要特征参数对三种网络(随机网络、无标度网络和小世界网络)结点修复率和崩溃结点数的影响. 模拟结果与这些实际生命线系统的特征一致,表明所建立的模型可以有效地模拟生命线系统的灾害演化动力学.
关键词:
复杂网络
生命线系统
灾害蔓延 相似文献
136.
The B-meson decay constant fB has been calculated from unquenched lattice QCD in the unphysical region. For extrapolating the lattice data to the physical
region, we propose a phenomenological functional form based on the effective chiral perturbation theory for heavy mesons,
which respects both the heavy quark symmetry and the chiral symmetry, and the non-relativistic constituent quark model which
is valid at large pion masses. The inclusion of pion loop corrections leads to non-analytic contributions to fB when the pion mass is small. The finite-range regularization technique is employed for the re-summation of higher-order terms
of the chiral expansion. We also take into account the finite volume effects in lattice simulations. The dependence on the
parameters and other uncertainties in our model are discussed.
PACS 12.39.Fe; 12.39.Hg; 12.39.-x; 12.38.Gc 相似文献
137.
138.
139.
140.
In situ variable temperature XRD (VT-XRD) measurements on the transformation of nano-precursors to LaNiO phases are presented. Experimental results showed that LaNiO3 and La2NiO4 phases were formed at ca. 700 °C via the reaction of La2O3 and NiO (from the initial nano-precursors), where a relatively low temperature of 700 °C was found for the synthesis of La2NiO4. The formation of La3Ni2O7 at higher temperature (up to 1150 °C) appeared to proceed through a further reaction of La2NiO4 with unreacted NiO, whilst the formation of La4Ni3O10 (at 1075 °C) proceeded via a further decomposition of LaNiO3. Although phase pure La3Ni2O7 and La4Ni3O10 were not directly obtained under the processing conditions herein, the results of this study allow for a better understanding of formation pathways, particularly for the higher order La-Ni-O phases. 相似文献