全文获取类型
收费全文 | 5912篇 |
免费 | 337篇 |
国内免费 | 173篇 |
专业分类
化学 | 4138篇 |
晶体学 | 78篇 |
力学 | 192篇 |
综合类 | 15篇 |
数学 | 526篇 |
物理学 | 1473篇 |
出版年
2024年 | 13篇 |
2023年 | 47篇 |
2022年 | 119篇 |
2021年 | 153篇 |
2020年 | 130篇 |
2019年 | 121篇 |
2018年 | 107篇 |
2017年 | 80篇 |
2016年 | 180篇 |
2015年 | 190篇 |
2014年 | 226篇 |
2013年 | 361篇 |
2012年 | 458篇 |
2011年 | 500篇 |
2010年 | 261篇 |
2009年 | 246篇 |
2008年 | 383篇 |
2007年 | 344篇 |
2006年 | 309篇 |
2005年 | 307篇 |
2004年 | 250篇 |
2003年 | 205篇 |
2002年 | 194篇 |
2001年 | 138篇 |
2000年 | 148篇 |
1999年 | 114篇 |
1998年 | 83篇 |
1997年 | 63篇 |
1996年 | 82篇 |
1995年 | 72篇 |
1994年 | 73篇 |
1993年 | 72篇 |
1992年 | 61篇 |
1991年 | 44篇 |
1990年 | 51篇 |
1989年 | 32篇 |
1988年 | 14篇 |
1987年 | 19篇 |
1986年 | 19篇 |
1985年 | 21篇 |
1984年 | 18篇 |
1983年 | 13篇 |
1982年 | 14篇 |
1981年 | 9篇 |
1980年 | 10篇 |
1978年 | 7篇 |
1977年 | 9篇 |
1976年 | 11篇 |
1975年 | 8篇 |
1974年 | 13篇 |
排序方式: 共有6422条查询结果,搜索用时 15 毫秒
11.
12.
13.
A kinetic model is presented to describe the high temperature (1800 K < T < 3000 K) surface oxidation of particulate boron in a hydrocarbon combustion environment. The model includes a homogeneous gas-phase B/O/H/C oxidation mechanism consisting of 19 chemical species and 58 forward and reverse elementary reactions, multi-component gas-phase diffusion, and a heterogeneous surface oxidation mechanism consisting of ‘elementary’ adsorption and desorption reaction steps. Thermochemical and kinetic parameters for the surface reactions are estimated from available experimental data and/or elementary transition state arguments. The kinetic processes are treated using a generalized kinetics code, with embedded sensitivity analysis, for the combustion of a one-dimensional (particle radius), spherical particle. Model results are presented for the oxidation of a 200 μm boron particle in a JP-4/air mixture at ambient temperatures of 1400 K and 2000 K. These results include temperature and gas-phase species profiles as a function of radial distance and particle burning rates. © 1994 John Wiley & Sons, Inc. 相似文献
14.
This paper presents a simulated annealing algorithm for resource constrained project scheduling problems with the objective of minimising makespan. In the search algorithm, a solution is represented with a priority list, a vector of numbers each of which denotes the priority of each activity. In the algorithm, a priority scheduling method is used for making a complete schedule from a given priority list (and hence a project schedule is defined by a priority list). The search algorithm is applied to find a priority list which corresponds to a good project schedule. Unlike most of priority scheduling methods, in the suggested algorithm some activities are delayed on purpose so as to extend search space. Solutions can be further improved by delaying certain activities, since non-delay schedules are not dominant in the problem (the set of non-delay schedules does not always include an optimal solution). The suggested algorithm is flexible in that it can be easily applied to problems with an objective function of a general form and/or complex constraints. The performance of the simulated annealing algorithm is compared with existing heuristics on problems prepared by Patterson and randomly generated test problems. Computational results showed that the suggested algorithm outperformed existing ones. 相似文献
15.
O. Maksimov P. Fisher M. Skowronski P.A. Salvador M. Snyder J. Xu X. Weng 《Journal of Crystal Growth》2008,310(11):2760-2766
MgO films were grown on (0 0 1) yttria-stabilized zirconia (YSZ) substrates by molecular beam epitaxy (MBE). The crystalline structures of these films were investigated using X-ray diffraction and transmission electron microscopy. Growth temperature was varied from 350 to 550 °C, with crystalline quality being improved at higher temperatures. The MgO films had a domain structure: (1 1 1)[1 1 2¯]MgO(0 0 1)[1 0 0]YSZ with four twin variants related by a 90° in-plane rotation about the [1 1 1]MgO axis. The observed epitaxial orientation was compared to previous reports of films grown by pulsed laser deposition and sputtering and explained as resulting in the lowest interface energy. 相似文献
16.
Practical and efficient catalytic asymmetric allylic transfer reactions of tin reagents promoted by BINOL-Ti[OCH(CF3)2]2 complex by the utilization of t-BuSBEt2 are successful with a variety of functionalized aldehydes containing ketone, aldehyde, ester, amide, or carbamoyl functionality and affords products in high levels of enantioselectivity. 相似文献
17.
The chemometric calibration performance was systematically investigated by two parameters (changing the chemical matrix as well as the signal-to-noise ratio) of the NIR (near-infrared) spectrum. Three different analytes (hexane, cyclohexane, toluene) were selected and heptane was used as a solvent. The degree of spectral difference significantly affected the calibration performance. The largest structural difference between the analyte and the solvent provided the best calibration result for a given signal-to-noise ratio. Additionally, the signal-to-noise ratio of the spectra also directly influenced the calibration performance. Overall, the spectral difference and signal-to-noise ratio were the major factors for governing the chemometric calibration performance, especially in the low-concentration range. 相似文献
18.
C. D. Schaper Y. M. Cho T. Kailath 《Applied Physics A: Materials Science & Processing》1992,54(4):317-326
A low-order model of rapid thermal processing (RTP) of semiconductor wafers is derived. The first-principles nonlinear model describes the static and dynamic thermal behavior of a wafer with approximate spatial temperature uniformity undergoing rapid heating and cooling in a multilamp RTP chamber. The model is verified experimentally for a range of operating temperatures from 400° C to 900° C and pressures of 1 Torr and 1 atmosphere in an inert N2 environment. Theoretical predictions suggest model validity over a still wider range of operating conditions. One advantage of the low-order model over previous high-order and statistical models is that the proposed model contains a small number of fundamental parameters and functions that, if necessary, are easily identifiable. Furthermore, because of reduced computational complexity, the low-order model can be used in real-time predictive applications including signal processing and process control design. In studying and verifying the model, the dynamic behavior of a semiconductor wafer undergoing rapid temperature changes is characterized. Close comparison between theory and experiment in terms of the wafer eigenvalue and dc gain is demonstrated; the strong nonlinear effects of temperature are shown. Convective heat transfer losses are also examined and are shown to increase with radial position on the wafer. 相似文献
19.
Fa‐Yan Meng Xu‐Qing Liu Seik Weng Ng 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(7):m341-m342
The terephthalate dianion and the bis(imidazolyl)benzene ligand of the title compound, {[Zn(C8H4O4)(C20H14N4)]·C2H6O}n, each bridges two adjacent zinc centers, resulting in a layer‐type coordination polymer; the zinc center shows tetrahedral coordination. The disordered ethanol solvent molecules occupy the spaces between the layers and are hydrogen bonded to the layers. The two symmetry‐independent dianions lie on different inversion sites. 相似文献
20.
Yanlin Huang Kiwan Jang Wanxue Zhao Eunjin Cho Ho Sueb Lee Xigang Wang Dake Qin Ying Zhang Chanfang Jiang Hyo Jin Seo 《Journal of solid state chemistry》2007,180(12):3325-3332
Usually, Sm2+ ions could be reduced by heating the materials in reducing atmospheres. Exposure to ionizing radiations is also known to cause Sm3+→Sm2+ conversion. In this work, BaBPO5 doped with the samarium ion was prepared by high temperature solid-state reaction. Sm2+ ions were obtained by two different reduction methods, i.e., heating in H2 reduced atmosphere and X-ray irradiation. The measurements of X-ray diffraction (XRD), and scanning electron microscope (SEM) were investigated. It is found that the conversion of Sm3+→Sm2+ is very efficient in BaBPO5 hosts after X-ray irradiation. Sm2+ ions under these two reduction methods exhibit different characteristics that were studied by measurements of luminescence and decay. The results showed that the luminescence properties of Sm2+ ions in BaBPO5 were highly dependent on the sample preparation conditions. 相似文献