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91.
Yu Lin Song Chih Hsiao Cheng Luh-Maan Chang Chia-Fone Lee Yuan Fang Chou 《Applied Acoustics》2011,(12):949-952
Mono-disperse polycarbonate (PC) nanoparticles 20 nm in diameter was spray coated on silicon substrate using a novel high-frequency ultrasonic nozzle. Specifically, Bisphenol-A polycarbonate with a molecular weight (Mw) of approximately 6.4 × 104 g/mol was first dissolved in pyridine. The resulting solution was sprayed into surfactant-containing de-ionized (DI) water using a 300 kHz silicon-based multiple-Fourier horn nozzle (MFHN). As pyridine was extracted into the water, PC nanoparticles formed but remained dispersed. This suspension of PC nanoparticles was then sprayed onto a silicon substrate using a 500 kHz 3-Fourier horn nozzle. Scanning electron microscopy (SEM) of the dried substrate revealed that PC nanoparticles were spread uniformly with no aggregation. 相似文献
92.
Reagen Ying‐Tai Su Li‐Ko Chiu Shan‐Wei Weng Ying‐Shiun Chou Raymond Chien‐Chao Tsiang 《Journal of Polymer Science.Polymer Physics》2012,50(4):280-288
White polymeric light‐emitting diode (WPLED) based on a single polymer, poly(3‐hexylthiophene‐alt‐9,9‐dioctylfluorene) (PTAF), has been successfully demonstrated. This conjugated alternating copolymer, PTAF, comprises 50 mol % of 3‐hexylthiophene which is an orange‐red color chromophore and 50 mol % 9,9‐dioctylfluorene which is a bluish‐green color chromophore. It was synthesized by Suzuki cross‐coupling reaction and has a molecular weight of 15,021 and polydispersity of 1.36. Nanocomposite consisting PTAF and graphene nanosheets enhances the optoelectronic properties and the device fabricated with a configuration of ITO/PEDOT:PSS/(PTAF + 1% graphene)/Ca/Al shows two‐color white electroluminescence with CIE 1931 coordinates of (0.28, 0.34). The white luminescence from a single polymer affords the WPLED device a simple structure and low fabrication cost. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011 相似文献
93.
94.
Shih-Feng Tseng Wen-Tse HsiaoDonyau Chiang Kuo-Cheng HuangChang-Pin Chou 《Applied Surface Science》2011,257(16):7204-7209
The fluorine-doped tin oxide (FTO) thin film deposited on a soda-lime glass substrate was annealed by a defocus ultraviolet (UV) laser irradiation at ambient temperature. The mechanical and optoelectric properties of FTO films annealed by using the various laser processing parameters were reported. After the FTO films were subjected to laser post-annealing, the microhardness were slightly less but the reduced modulus values were larger than that of unannealed FTO films, respectively. The average optical transmittance in the visible waveband slightly increased with increasing the laser annealing energy and scan speed. Moreover, all the sheet resistance of laser annealed films was less than that of the unannealed ones. We found that the sheet resistance decrease was obviously influenced by annealing. The suitable annealing conditions could maintain the film thickness and relief the internal stress generated in the film preparation process to improve the electrical conductivity via decreasing laser energy or increasing scan speed. 相似文献
95.
Liao JH Chen CT Chou HC Cheng CC Chou PT Fang JM Slanina Z Chow TJ 《Organic letters》2002,4(18):3107-3110
[structure: see text] A push-pull conjugated molecule, 2,7-bis(1H-pyrrol-2-yl)ethynyl-1,8-naphthyridine (BPN), has been designed to bind selectively with octyl glucopyranoside (OGU). The BPN/OGU quadruple hydrogen-bonding complex adopts a rigid BPN conformation in which the proton donor (d) and acceptor (a) relays (daad) are resonantly conjugated through the ethynyl bridge, inducing pi-electron delocalization, i.e., a charge transfer effect. The excellent photophysical properties make BPN a highly sensitive probe for monitoring glucopyranoside to a detection limit of approximately 100 pM. 相似文献
96.
Angle-resolved photoemission is employed to measure the band structure of TiSe2 in order to clarify the nature of the ( 2 x 2 x 2) charge density wave transition. The results show a very small indirect gap in the normal phase transforming into a larger indirect gap at a different location in the Brillouin zone. Fermi surface topology is irrelevant in this case. Instead, electron-hole coupling together with a novel indirect Jahn-Teller effect drives the transition. 相似文献
97.
The current-voltage curves of a composite bipolar membrane (CBM) were experimentally measured by varying the interface component between cation- and anion-exchange membranes for water and methanol solutions. In each solution system, 0.05 mol/l LiCl was used as the electrolyte. The interface component was varied by pasting the polymers or installing the thin membranes in the intermediate region of the CBM. The measured results show that the functional groups of the polymers and thin membranes enhanced the water and methanol splitting effect. This phenomenon can be explained by the protonation-deprotonation reactions occurring between these functional groups and the water or methanol molecules in the intermediate region of the CBM. The effect of transition metal compounds existing in the intermediate region of the CBM was also experimentally examined in this study. It was found that the effect of transition metal compounds on water or methanol splitting was not obvious. Copyright 1999 Academic Press. 相似文献
98.
We report difference frequency generation-based wavelength converters with multiple phase-matching wavelengths that use engineered quasi-phase-matching structures in LiNbO(3) waveguides. Multiple-channel wavelength conversion is demonstrated within the 1.5-mum band and between the 1.3- and 1.5-mum bands. With simultaneous use of M pump wavelengths, these devices can also be used to perform wavelength broadcasting, in which each of N input signals is converted into M output wavelengths. 相似文献
99.
M. W. Richman C. S. Chou 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1988,39(6):885-901
Summary We obtain boundary conditions for two-dimensional flows of identical, nearly elastic, circular disks that interact with a flat wall to which identical, evenly spaced half-disks have been attached. Expressions for the transfer of momentum and energy from the boundary to the flow are obtained by statistical averaging over all possible wall-flow disk collisions. We improve upon the expressions derived by Jenkins and Richman [1986] by employing in the averaging process a more elaborate velocity distribution function obtained through the method of moments. In addition we expand the distribution function about a point near the flat wall that guarantees positive slip velocities. With these boundary conditions, we analyze a two-dimensional shear flow driven by parallel bumpy boundaries. The constitutive theory employed includes both the effects of particle collisions and particle transport on the transfer of momentum and energy throughout the flow. We demonstrate how the resulting profiles of velocity, granular temperature, and solid fraction are affected by changes in the geometry of the boundary. We also predict how the induced stresses vary with the geometry of the boundary and the average solid fraction within the flow.
Zusammenfassung Wir erhalten die Randbedingungen für die zweidimensionale Strömung identischer, beinahe elastischer, runder Scheiben, die sich in Wechselwirkung mit einer geraden Wand befinden, an der in gleichmäßigen Abständen Halbscheiben angebracht sind. Es werden Ausdrücke für die Übertragung von Impuls und Energie vom Rand auf den Strom aufgestellt, die durch den statisch errechneten Durchschnitt aller möglichen Scheibenkollisionen Wand-Strom erhalten werden. Wir verbessern die von Jenkins und Richman (1986) entwickelten Ausdrücke dadurch, daß bei der Berechnung der Mittelwerte eine erweiterte Geschwindigkeitsverteilung, die auf der Momentmethode beruht, einbezogen wurde. Außerdem entwickeln wir die Verteilungsfunktion an einem Punkt so nahe an der Wand, daß positive Gleitgeschwindigkeiten garantiert sind. Wir untersuchen eine zweidimensionale Scherströmung mit diesen Randbedingungen, die durch die parallelen unebenen Ränder getrieben wird. Die konstitutive Theorie, die wir anwenden, beinhaltet sowohl den Einfluß der Teilchenkollisionen als auch den des Teilchentransports auf die Übertragung von Impuls und Energie innerhalb der Strömung. Wir zeigen, wie die Profile der Geschwindigkeit, der Granu-lartemperatur und des Festkörperanteils, die sich ergeben, durch Veränderungen der Randgeometrie beeinflußt werden. Weiterhin können wir voraussagen, wie die erzeugten Spannungen sich mit der Randgeometrie und dem im Strom enthaltenen Festkörperanteil verändern.相似文献
100.