点、线接触真实粗糙表面的弹流润滑研究

本文给出了点、线接触的真实粗糙表面的微弹流数值解。在给定随机粗糙表面样本后,求解大小不同的载荷和粗糙的弹流问题。从计算结果可以看出,由于Reynolds方程中速度项的作用,在表面对应粗糙的位置处引起了压力变化,从而因其产生的弹性变形使粗糙变得平滑。对此光滑表面解可以看出,因粗糙引起的压力和膜厚的变化在光滑解附近波动。载荷较大时,压力分节接近固体接触情况。     

结合部切向接触刚度分形模型研究

根据球体与平面接触的切向接触刚度和粗糙表面的接触分形理论，从理论上首次建立了结合部切向接触刚度分形模型，该模型具有尺度独立性。通过对所建模型的数字仿真，直观地给出了结合部切向接触刚度与其影响因素之间的非线性关系，并与实验研究结果具有较好的一致性，从而说明了该模型是合理的。     

铸铁材料在边界润滑条件下形成薄片状磨屑的塑性流动机制

本文在铸铁材料油润滑线接触滑动磨损状态研究的基础上,对边界润滑区典型的薄片状磨屑之形成过程进行了考察。通过对磨损表面的几何形貌、磨屑的形态和内部显微组织变化的分析,提出了薄片状磨屑的塑性流动形成机制。作者认为,薄片状磨屑的形成是磨损表面材料在局部应力和摩擦热的作用下以3种方式发生塑性流动的结果:当摩擦方向垂直于磨削加工条纹时为单侧塑性流动;当摩擦方向平行于磨削加工条纹时为双侧塑性流动;而在峰顶平台(磨削加工粗糙条纹磨合后形成的微平台)较大且载荷较高时,则为平台上的材料沿着摩擦方向向前挤压流动。     

Two new eudesmane derivatives from Verbesina virginica

<正>Two new eudesmane derivatives were isolated from the leaves and flowers of Verbesina virginica,along with the known 6-O-β-E -p-coumaroyl-4α-hydroxyeudesmane(1).Their structures were determined as 6-O-β-Z-p-coumaroyl-4α-hydroxyeudesmane(2) and 6-O-α-E-p-coumaroyl-1β-4α-dihydroxyeudesmane(3) by spectroscopic methods.     

Kinetic comparison between ferric ion and decamethyferrocene at the liquid/liquid interface as studied by scanning electrochemical microscopy

<正>Comparison in electron transfer(ET) processes from decamethyferrocene(DMFe) in nitrobenzene(NB) to ferric ion in aqueous phase was investigated for the first time by the scanning electrochemical microscopy(SECM).As compared with the system of Fe(CN)_6~(3-)-DMFe,the ET rate obtained from Fe~(3+)-DMFe was lower in spite of larger driving force,which may arise from the effect of reorganization energy.Otherwise,the effect of common ion on rate constants was also probed and results suggested additional complexity of the ET mechanism between Fe(CN)_6~(3-) and DMFe.     

Synthesis, spectroscopic and electrochemical property of an unsymmetrical porphyrin and its Zn compound

<正>In this article,a new 5-(p-maleicaminophenyl)-10,15,20-triphenylporphyrin(H_2P) and relative zinc compound(ZnP) were synthesized and characterized by means of elemental analyses,UV-vis,IR,MS and ~1H NMR spectroscopies.Furthermore,we have investigated the fluorescence spectroscopy of these compounds.The oxidation and reduction properties of the compounds were studied by the cyclic voltarnmetry,the oxidation-reduction potentials were obtained.     

Fluorescence quenching method for the determination of catechol with gold nanoparticles and tyrosinase hybrid system

<正>The determination method of catechol by fluorescence quenching was developed.The assay was based on the combination of the unique property of gold nanoparticles with tyrosinase enzymatic reaction.In the presence of tyrosinase,the fluorescence of gold nanoparticles was quenched by catechol which can be employed to detect catechol.Under the optimal conditions,a linear range 5.0×10~(-7)-1.0×10~(-3) mol L~(-1) and a detection limit 1.0×10~(-7) mol L~(-1) of catechol were obtained.o-Quinone intermediate produced from the enzymatic catalyzed oxidation of catechol was considered to play the main role in the fluorescence quenching.     

Separation of gibberellin A4 from A4 and A7 mixture by selective complex

<正>Gibberellin A4 is effectively separated from mixture of gibberellin A4 and its analogue gibberellin A7,in the form of its crystalline complex with N,N,N',N'-tetramethylethylenediamine.After removing the tetramethylethylenediamine from the crystal by dilute HCl,gibberellin A4 is obtained a purity of 98.1%and a yield of 72.7%.     

Synthesis of diblock copolymers containing poly(N‐vinylcarbazole) by reversible addition‐fragmentation chain transfer polymerization

The reversible addition‐fragmentation chain transfer (RAFT) polymerization of N‐vinylcarbazole (NVK) mediated by macromolecular xanthates was used to prepare three types of block copolymers containing poly(N‐vinylcarbazole) (PVK). Using a poly(ethylene glycol) monomethyl ether based xanthate ( PEG‐X ), the RAFT polymerization of NVK proceeded in a controlled way to afford a series of PEG‐b‐PVK with different PVK chain lengths. Successive RAFT polymerization of NVK and vinyl acetate (VAc) with a small molecule xanthate ( X1 ) as the chain transfer agent was tested to prepare PVK‐b‐PVAc. Though both monomers can be homopolymerized in a controlled manner with this xanthate, only by polymerizing NVK first could give well‐defined block copolymers. The xanthate groups in the end of PVK could be removed by radical‐induced reduction using tributylstannane, and PVK‐b‐PVA was obtained by further hydrolysis of PVK‐b‐PVAc under basic conditions. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010     

Electrophoretic sol–gel synthesis of SrBi<Subscript>2</Subscript>Ta<Subscript>2</Subscript>O<Subscript>9</Subscript> nanowires

We report the independent invention of perovskite ferroelectric nanowires strontium bismuth tantalate (SrBi₂Ta₂O₉, SBT). Electrophoretic sol–gel techniques have been used successfully. The morphology and structures are analyzed via SEM, TEM and XRD. SBT nanowires and nanoparticles filled template revealed 30 and 40 μm long, respectively. SBT are proved to be a single phase of orthorhombic perovskite structure. As it indicated, SBT nanowires has been crystallized at 700 °C. To minimize surface polarity, SBT nanowires oriented preferentially along the growing axis (c axis) by translation and rotation of atomic clusters of SBT.