全文获取类型
收费全文 | 22693篇 |
免费 | 3802篇 |
国内免费 | 3263篇 |
专业分类
化学 | 16916篇 |
晶体学 | 303篇 |
力学 | 1388篇 |
综合类 | 221篇 |
数学 | 2923篇 |
物理学 | 8007篇 |
出版年
2024年 | 68篇 |
2023年 | 340篇 |
2022年 | 693篇 |
2021年 | 773篇 |
2020年 | 798篇 |
2019年 | 863篇 |
2018年 | 756篇 |
2017年 | 695篇 |
2016年 | 1079篇 |
2015年 | 1168篇 |
2014年 | 1344篇 |
2013年 | 1672篇 |
2012年 | 1948篇 |
2011年 | 2086篇 |
2010年 | 1562篇 |
2009年 | 1535篇 |
2008年 | 1697篇 |
2007年 | 1432篇 |
2006年 | 1298篇 |
2005年 | 1078篇 |
2004年 | 887篇 |
2003年 | 764篇 |
2002年 | 910篇 |
2001年 | 754篇 |
2000年 | 576篇 |
1999年 | 485篇 |
1998年 | 379篇 |
1997年 | 302篇 |
1996年 | 320篇 |
1995年 | 279篇 |
1994年 | 189篇 |
1993年 | 172篇 |
1992年 | 142篇 |
1991年 | 143篇 |
1990年 | 103篇 |
1989年 | 93篇 |
1988年 | 58篇 |
1987年 | 55篇 |
1986年 | 46篇 |
1985年 | 33篇 |
1984年 | 32篇 |
1983年 | 33篇 |
1982年 | 18篇 |
1981年 | 23篇 |
1980年 | 11篇 |
1979年 | 11篇 |
1978年 | 6篇 |
1974年 | 9篇 |
1971年 | 5篇 |
1957年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
101.
New spirocyclic heterocycles 8, 16, 19/20, 25, 27 , and 30 derived from pyrimido[4,5‐b][1,4]diazepin]‐8′(9′H)‐one were synthesised by a tandem nitroso‐ene/Diels–Alder reaction of 4‐(alkenoylamino)‐5‐nitrosopyrimides. The crystal structure of 16 was established by X‐ray analysis. It is characterised by four pairs of intermolecular H‐bonds linking every two molecules in the unit cell. Sequential imine reduction and intramolecular condensation of the C(4′)‐(acylamino)‐pyrimido[4,5‐b][1,4]diazepines 27 and 30 led to the [1,4]diazepino[1,2,3‐gh]purines 28 / 29 and 31 , respectively. 相似文献
102.
Lei Qiao Chao Zhang Xiang‐Wen Zhang Zi‐Chuan Wang Haolin Yin Zhong‐Ming Sun 《中国化学》2020,38(3):295-304
The polypnictide complexes of rare earth cations have drawn the attention of the scientific community for their uncommon bonding modes and potential applications. Herein, we present a systematic and comprehensive summary on recent advances in the field of rare earth polypnictides, focusing on their synthesis, structures, and reactivities. The structural stabilizing effects imposed by the electropositive rare earth cations as well as the reducing capability of rare earth precursors in the synthesis of these polypnictide complexes are described in this review. We also disscuss in detail the bonding interactions and coordination modes between rare earth cations and polypnictide clusters as well as the similarities and the peculiarity of some structures. 相似文献
103.
104.
Yan B Collins N Wheatley J Irving M Leopold K Chan C Shornikov A Fang L Lee A Stock M Zhao J 《Journal of combinatorial chemistry》2004,6(2):255-261
We have developed a high-throughput purification system to purify combinatorial libraries at a 50-100-mg scale with a throughput of 250 samples/instrument/day. We applied an accelerated retention window method to shorten the purification time and targeted one fraction per injection to simplify data tracking, lower QC workload, and simplify the postpurification processing. First, we determined the accurate retention time and peak height for all compounds using an eight-channel parallel LC/UV/MS system, and calculated the specific preparative HPLC conditions for individual compounds. The preparative HPLC conditions include the compound-specific gradient segment for individual compounds with a fixed gradient slope and the compound-specific UV or ELSD threshold for triggering a fraction collection device. A unique solvent composition or solvent strength was programmed for each compound in the preparative HPLC in order to elute all compounds at the same target time. Considering the possible deviation of the predicted retention time, a 1-min window around the target time was set to collect peaks above a threshold based on UV or ELSD detection. Dual column preparative instruments were used to maximize throughput. We have purified more than 500 000 druglike compounds using this system in the past 3 years. We report various components of this high-throughput purification system and some of our purification results. 相似文献
105.
Thermodynamic and Equilibrium Composition Analysis of Using Iron Oxide as an Oxygen Carrier in Nonflame Combustion Technology 总被引:1,自引:0,他引:1
Jiayu Xin Hua Wang* Fang He Zhimin Zhang Faculty of Materials Metallurgical Engineering Kunming University of Science Technology Kunming China 《天然气化学杂志》2005,14(4)
1. Introduction The utilization of fossil fuels causes serious neg- ative impacts on the environment and human life. There are many pollutants such as SOx, NOx and CO2 emission produced from the combustion of coal, oil and natural gas. It has been known for more than 100 years that CO2 is a greenhouse gas and that the release of CO2 from fossil fuel combustion may affect the climate of the earth. In the last years the concern over the aspects of an increased release of greenhouse gases has… 相似文献
106.
107.
Hae‐Jeong Lee Christopher L. Soles Da‐Wei Liu Barry J. Bauer Wen‐Li Wu 《Journal of Polymer Science.Polymer Physics》2002,40(19):2170-2177
X‐ray reflectivity has been used to determine the mass uptake of probe molecules in porous thin films supported on thick silicon wafers. The adsorption occurs by capillary condensation when the films are exposed to probe vapor at controlled partial vapor pressures. The probe solvent partial pressure was varied by mixing saturated air and dry air at constant temperature or by changing sample temperature at a constant vapor concentration. Pore size distribution in the films can be calculated from the probe uptake with typical porosimetric approaches such as the application of the Kelvin equation to convert partial pressure into pore size. For illustration, the pore size distribution of three different nanoporous thin films, the primary candidate of ultra‐low‐k interlevel dielectrics in the next generation of integrated circuit chips, was determined with this technique. These samples represent different generations of low‐k dielectrics developed by industry. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 40: 2170–2177, 2002 相似文献
108.
109.
Yonghong Wen Zhi Qin Weisheng Liu 《Journal of Radioanalytical and Nuclear Chemistry》2001,250(2):285-289
The extraction of Am3+ and Eu3+ from aqueous picric acid solution by N, N-dinaphthyl-N, N-diphenyl-3,6-dioxaoctanediamide (LI) and 1, 1-(3, 6, 9-trioxaundecanedionyl)diphenothiazine (LII) was investigated by a radioactive tracer technique. Extraction distribution ratios of Am3+ and Eu3+ have been measured as a function of pH, picric acid concentration, extractant concentration, diluent and temperature. The extraction of Am3+ is preferred to that of Eu3+ for both LI and LII, and the latter gives larger separation factor than the former. The equilibrium constants and thermodynamic parameters of extraction reactions were also calculated. 相似文献
110.
镉—溴化物—罗丹明B高灵敏显色反应的研究:离心光度法测定镉 总被引:10,自引:0,他引:10
本研究了一个高灵敏的测定镉的方法,离心光度法,该体系络合物λmax=560nm,表观摩尔吸系数ε560=5.06×10^8L.mol^-1.cm^-1,Cd^2+浓度0.10×10^-2-1.0×10^-2μg/10mL呈线性关系,本法已用于血清和水中痕量镉的测定,探讨了高灵敏的显色反应机理。 相似文献