Allyl-Palladium-Catalyzed Ketone Dehydrogenation Enables Telescoping with Enone α,β-Vicinal Difunctionalization

The telescoping of allyl-palladium catalyzed ketone dehydrogenation with organocuprate conjugate addition chemistry allows for the introduction of aryl, heteroaryl, vinyl, acyl, methyl, and other functionalized alkyl groups chemoselectively to a wide variety of unactivated ketone compounds via their enone counterparts. The compatibility of the dehydrogenation conditions additionally allows for efficient trapping of the intermediate enolate with various electrophiles. The utility of this approach is demonstrated by comparison to several previously reported multistep sequences.     

Visible-Light-Mediated [4+2] Cycloaddition of Styrenes: Synthesis of Tetralin Derivatives

We report a formal [4+2] cycloaddition reaction of styrenes under visible-light catalysis. Two styrene molecules with different electronic or steric properties were found to react with each other in good yield and excellent chemo- and regioselectivity. This reaction provides direct access to polysubstituted tetralin scaffolds from readily available styrenes. Sophisticated tricyclic and tetracyclic tetralin analogues were prepared in high yield and up to 20/1 diasteroselectivity from cyclic substrates.     

Double-Layered Plasmonic–Magnetic Vesicles by Self-Assembly of Janus Amphiphilic Gold–Iron(II,III) Oxide Nanoparticles

Janus nanoparticles (JNPs) offer unique features, including the precisely controlled distribution of compositions, surface charges, dipole moments, modular and combined functionalities, which enable excellent applications that are unavailable to their symmetrical counterparts. Assemblies of NPs exhibit coupled optical, electronic and magnetic properties that are different from single NPs. Herein, we report a new class of double-layered plasmonic–magnetic vesicle assembled from Janus amphiphilic Au-Fe₃O₄ NPs grafted with polymer brushes of different hydrophilicity on Au and Fe₃O₄ surfaces separately. Like liposomes, the vesicle shell is composed of two layers of Au-Fe₃O₄ NPs in opposite direction, and the orientation of Au or Fe₃O₄ in the shell can be well controlled by exploiting the amphiphilic property of the two types of polymers.     

Recent Progress of Synthesis and Application in Au@MOFs Hybrid Materials

The combination of gold nanoparticles and metal–organic frameworks is one of the new directions of current research. It has applications in many aspects, especially as a catalyst for a variety of reactions. Therefore, this paper describes recent progress of synthesis and application in Au@MOFs hybrid materials.     

Self-catalytic synthesis of hydrophilic polypyrrole/tellurium nanocomposite and its capacitance performance

Journal of Solid State Electrochemistry - A hydrophilic polypyrrole/tellurium (PPy/Te) nanocomposite was synthesized by a facile approach in which H2TeO3 was used as the oxidizing agent of pyrrole...     

A sustainable synthesis of biomass carbon sheets as excellent performance sodium ion batteries anode

Biomass-derived carbon (BMC) materials have attracted much attention due to their high performance and properties of abundant source. Herein, biomass carbon sheets (BMCS) from wheat straws had been successfully synthesized via a facile high temperature carbonization and expansion processes. The morphology of BMCS keeps the natural honeycomb-like shape of the cross section and the hollow tubular array structure of the vertical section with rich pores, which provides low-resistant ion channels to support fast diffusion. The (002) crystal plane reveals that the intercalation distance of carbon sheets is 0.383 nm larger than that graphite (0.335 nm), which benefits the larger sodium ion de/intercalation. By comparing different carbonization temperatures, wheat straws carbonized at 1200 °C (BMCS-1200) with well graphite microcrystallites show more excellent sodium ion storage performance than that of 900 °C (BMC-900). BMCS-1200 shows a stable reversible capacity of 221 mAh g^?1 after 200 cycles at 0.05 A g^?1, while BMC-900 is 162 mAh g^?1 after 100 cycles. And it also exhibits better rate capability (220, 109 mAh g^?1) than that of BMC-900 (125, 77 mAh g^?1) at 0.2 and 1 A g^?1, respectively. Finally, it delivers 89 mAh g^?1 stable capacity after 1400 cycles at 1 A g^?1 to prove its excellent long-term cycling stability.

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Graphical abstract High temperature carbon sheets with well graphite microcrystallites synthesized from wheat straw forexcellent sodium ion storage performance

     

Synthesis,characterization of new bisphenol-based benzoxazines and the thermal properties of their polymers

Journal of Thermal Analysis and Calorimetry - New bisphenol-based benzoxazines (BBA-a and BBA-bra) were synthesized from bisphenol containing trityl group, paraformaldehyde, aniline and...     

Hamiltonicity of edge chromatic critical graphs

Vizing conjectured that every edge chromatic critical graph contains a 2-factor. Believing that stronger properties hold for this class of graphs, Luo and Zhao (2013) showed that every edge chromatic critical graph of order $n$ with maximum degree at least $\frac{6n}{7}$ is Hamiltonian. Furthermore, Luo et al. (2016) proved that every edge chromatic critical graph of order $n$ with maximum degree at least $\frac{4n}{5}$ is Hamiltonian. In this paper, we prove that every edge chromatic critical graph of order $n$ with maximum degree at least $\frac{3n}{4}$ is Hamiltonian. Our approach is inspired by the recent development of Kierstead path and Tashkinov tree techniques for multigraphs.     

Gröbner–Shirshov bases for some Lie algebras

Siberian Mathematical Journal - We give Gröbner–Shirshov bases for the Drinfeld–Kohno Lie algebra L n in [1] and the Kukin Lie algebra A P in [2], where P is a semigroup. By way of...     

New model and heuristic solution approach for one-dimensional cutting stock problem with usable leftovers

In the one-dimensional cutting stock problem with usable leftovers (1DCSPUL), items of the current order are cut from stock bars to minimize material cost. Here, stock bars include both standard ones bought commercially and old leftovers generated in processing previous orders, and cutting patterns often include new leftovers that are usable in processing subsequent orders. Leftovers of the same length are considered to be of the same type. The number of types of leftovers should be limited to simplify the cutting process and reduce the storage area. This paper presents an integer programming model for the 1DCSPUL with limited leftover types and describes a heuristic algorithm based on a column-generation procedure to solve it. Computational results show that the proposed approach is more effective than several published algorithms in reducing trim loss, especially when the number of types of leftovers is limited.