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71.
In this study, we report a novel and simple solution-phase route for one-dimensional metal nanocrystals. BiIn nanocrystals were prepared by directly dispersing melting BiIn alloy at an appropriate solvent. The as-obtained BiIn nanocrystals with a dendritic shape possess a good crystalline phase. The morphology of the nanocrystals can be greatly modified by changing the reaction parameters. This strong UV emission might arise from the quantum-confined In2O3 particles. 相似文献
72.
73.
1. PreliminaryIt is well known that{1] a 8ymPlectic form is invariant along the trajectory of a Hamilto-nian system. Based on this fundamental property, certain techniques have been developed.The purpose of this paper is to extend such an approach to a wider class of dynamic systeIns,namely, genera1ized Hamiltonian systems. Our purpose is to investigate a class of dynaInicsystems, which possess a certain "geometric structure".Deflnition 1.1[1'2]. Let M be a tIlallifo1d. w E fl'(M) is call… 相似文献
74.
A new system of multi-channel single-output joint fractional Fourier transform correlator (JFRTC) for color pattern recognition is proposed based on the conventional system of multi-channel single-output joint transform correlator (JTC). The theoretical analysis and optical experiments are performed. With this method, one can obtain three correlation peaks at the output plane which show a pair of desired cross-correlation peaks and one auto-correlation peak. In comparison, the conventional system leads to more correlation peaks playing a noise role in color pattern recognition. 相似文献
75.
76.
<正>An optical fiber evanescent wave methane gas sensor based on core diameter mismatch is reported.The sensor consists of a multimode fiber in which a short section of standard single-mode fiber,coated with the inclusion of cryptophane molecules E in a transparent polysiloxane film,is inserted.The sensing principle is analyzed by optical waveguide theory.For different sensing film thicknesses and interaction lengths,the sensor signal is investigated within the methane concentration range of 0-14.5%(v/v).It is shown that the sensor signal with the thickness of 5μm and the interaction length of 3 mm strengthens linearly with the increasing concentration of methane,with a slope of 0.0186.The best detection limit of the sensor for methane is 2.2%(v/v) with a response time of 90 s.This sensor is suitable for the detection of methane concentration below the critical value of 5%. 相似文献
77.
Over the last couple of years molecular imaging has been rapidly developed to study physiological and pathological processes in vivo at the cellular and molecular levels. Among molecular imaging modalities, optical imaging stands out for its unique advantages, especially performance and cost-effectiveness. Bioluminescence tomography (BLT) is an emerging optical imaging mode with promising biomedical advantages. In this survey paper, we explain the biomedical significance of BLT, summarize theoretical results on the analysis and numerical solution of a diffusion based BLT model, and comment on a few extensions for the study of BLT. 相似文献
78.
Qi-Rui Li Weimin Sheng 《Calculus of Variations and Partial Differential Equations》2013,48(1-2):41-66
In this paper we consider the problem of finding closed hypersurfaces with prescribed Weingarten curvature in a large class of Riemannian manifolds. Under some sufficient conditions, we obtain an existence result by establishing a priori estimates and standard degree theory for the admissible solutions to the prescribed curvature equation. We mainly show that the primary technique developed in Urbas, Wang and the second author’s work in 2004 is flexible enough to be used in more general ambient geometry. 相似文献
79.
Shan She Weimin Xuan Nicola L. Bell Robert Pow Eduard Garrido Ribo Zoe Sinclair De-Liang Long Leroy Cronin 《Chemical science》2021,12(7):2427
The precise control over the formation of complex nanostructures, e.g. polyoxometalates (POMs), at the sub-nanoscale is challenging but critical if non-covalent architectures are to be designed. Combining biologically-evolved systems with inorganic nanostructures could lead to sequence-mediated assembly. Herein, we exploit oligopeptides as multidentate structure-directing ligands via metal-coordination and hydrogen bonded interactions to modulate the self-assembly of POM superstructures. Six oligopeptides (GH, AH, SH, G2H, G4H and G5H) are incorporated into the cavities of Molybdenum Blue (MB) POM nanowheels. It is found that the helicity of the nanowheel can be readily switched (Δ to Λ) by simply altering the N-terminal amino acid on the peptide chain rather than their overall stereochemistry. We also reveal a delicate balance between the Mo-coordination and the hydrogen bonds found within the internal cavity of the inorganic nanowheels which results in the sequence mediated formation of two unprecedented asymmetrical nanowheel frameworks: {Mo122Ce5} and {Mo126Ce4}.Peptide sequence can be used to control the self-assembly and structures of nanoscale molybdenum blue polyoxometalate (POM) wheel-shaped clusters. 相似文献
80.
Yuanlin Ren Bowen Cheng Jinshu Zhang Weimin Kang Zhenhuan Li Xupin Zhuang 《Frontiers of Chemistry in China》2009,4(2):136-141
The thermal decomposition kinetics of the N,N′-bis(5,5-dimethyl-2-phospha-2-thio-1,3-dioxan-2-yl) ethylenediamine (DPTDEDA) in air were studied by TGDTG techniques. The
kinetic parameters of the decomposition process for the title compound in the two main thermal decomposition steps were calculated
through the Friedman and Flynn-Wall-Ozawsa (FWO) methods and the thermal decomposition mechanism of DPTDEDA was also studied
with the Coats-Redfern and Achar methods. The results show that the activation energies for the two main thermal decomposition
steps are 128.03 and 92.59 kJ·mol−1 with the Friedman method, and 138.75 and 106.78 kJ·mol−1 with the FWO method, respectively. Although there are two main thermal decomposition steps for DPTDEDA in air, the thermal
decomposition mechanism of DPTDEDA in the two steps are the same, i.e. f(α) = 3/2(1 − α)4/3[(1 − α)−1/3 − 1]−1.
__________
Translated from Acta Chimica Sinica, 2008, 66(9) (in Chinese) 相似文献