Unconventional Assembly of Bimetallic Au–Ni Janus Nanoparticles on Chemically Modified Silica Spheres

This paper reports that Janus Au?Ni nanoparticles (JANNPs) can self‐assemble onto silica spheres in a novel way, which is different from that of single‐component isotropic nanoparticles. JANNPs modified with octadecylamine (ODA) assemble onto catechol‐modified silica spheres (SiO₂?OH) to form a very special core–loop complex structure and finally the core–loop assemblies link each other to form large assemblies through capillary force and the hydrophobic interaction of the alkyl chains of ODA. The nanocomposites disassemble in the presence of vanillin and oleic acid because of the breakage of the catechol–metal link. Vanillin‐induced disassembly enables the JANNPs to reassemble into a core–loop structure upon ODA addition. The assembly of SiO₂?OH and isotropic Ni or Fe₃O₄ particles generates traditional core–satellite structures. This unconventional self‐assembly can be attributed to the synergistic effect of Janus specificity and capillary force, which is also confirmed by the assembly of thiol‐terminated silica spheres (SH?SiO₂) with anisotropic JANNPs, isotropic Au, and Ni nanoparticles. These results can guide the development of novel composite materials using Janus nanoparticles as the primary building blocks.     

A modified quick,easy, cheap,effective, rugged,and safe method with hydrophobic natural deep eutectic solvent as extractant and analyte protectant for analyzing pyrethroid residues in tomatoes

In this work, a novel quick, easy, cheap, effective, rugged, and safe technique with hydrophobic natural deep eutectic solvent as both extractant and analyte protectant was developed and combined with gas chromatography–tandem mass spectrometry to analyze pyrethroid residues in tomatoes. Eight hydrophobic natural deep eutectic solvents were first evaluated as analyte protectants and those with decanoic acid or lactic acid as hydrogen bond donor were demonstrated to be effective in compensating for the matrix effects of pyrethroids in the gas chromatography system. Hence, they were added to solvent standards for correcting the quantitation errors instead of matrix‐matched calibration standards. Then the abilities of these acid‐based deep eutectic solvents to extract pyrethriods from tomatoes were evaluated. Results showed the recoveries of all pyrethroids reached to over 80% with only 5 mL menthol:decanoic acid (1:1) used, and good phase separation was easily achieved without the addition of inorganic salt in the extraction step, indicating hydrophobic natural deep eutectic solvent could be a green substitute for acetonitrile in the quick, easy, cheap, effective, rugged, and safe extraction. Compared with the conventional method, the proposed protocol improved the recoveries, reduced the matrix effects, and simplified the extraction step, demonstrating to be an effective, fast, and green method.     

一类二阶渐近周期微分方程的正同宿轨道

§ 1　IntroductionIn this note we are concerned with the asymptotically periodic second order equation-u″+α( x) u =β( x) uq +γ( x) up,　 x∈ R,( 1 )where1 相似文献   

光学系统时间畸变和色时间滞后的研究

本文对皮秒和飞秒技术中瞬态现象测量系统所用的特殊光学系统校正时间畸变和压缩色时间滞后的问题进行了讨论。实验证明用该方法设计研制的光学系统校正效果显着。     

Controlling synthesis of BiIn dendritic nanocrystals by solution dispersion

In this study, we report a novel and simple solution-phase route for one-dimensional metal nanocrystals. BiIn nanocrystals were prepared by directly dispersing melting BiIn alloy at an appropriate solvent. The as-obtained BiIn nanocrystals with a dendritic shape possess a good crystalline phase. The morphology of the nanocrystals can be greatly modified by changing the reaction parameters. This strong UV emission might arise from the quantum-confined In2O3 particles.     

On generalized hamiltonian systems

1. PreliminaryIt is well known that{1] a 8ymPlectic form is invariant along the trajectory of a Hamilto-nian system. Based on this fundamental property, certain techniques have been developed.The purpose of this paper is to extend such an approach to a wider class of dynamic systeIns,namely, genera1ized Hamiltonian systems. Our purpose is to investigate a class of dynaInicsystems, which possess a certain "geometric structure".Deflnition 1.1[1'2]. Let M be a tIlallifo1d. w E fl'(M) is call…     

Color pattern recognition based on the joint fractional Fourier transform correlator

A new system of multi-channel single-output joint fractional Fourier transform correlator (JFRTC) for color pattern recognition is proposed based on the conventional system of multi-channel single-output joint transform correlator (JTC). The theoretical analysis and optical experiments are performed. With this method, one can obtain three correlation peaks at the output plane which show a pair of desired cross-correlation peaks and one auto-correlation peak. In comparison, the conventional system leads to more correlation peaks playing a noise role in color pattern recognition.