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Sulfur doped ZnO/TiO2 nanocomposite photocatalysts were synthesized by a facile sol‐gel method. The structure and properties of catalysts were characterized by X‐ray diffraction (XRD), X‐ray photoelectron spectroscopy (XPS), UV‐vis diffusive reflectance spectroscopy (DRS) and N2 desorption‐adsorption isotherm. The XRD study showed that TiO2 was anatase phase and there was no obvious difference in crystal composition of various S‐ZnO/TiO2. The XPS study showed that the Zn element exists as ZnO and S atoms form SO2?4. The prepared samples had mesoporosity revealed by N2 desorption‐adsorption isotherm result. The degradation of Rhodamine B dye under visible light irradiation was chosen as probe reaction to evaluate the photocatalytic activity of the ZnO/TiO2 nanocomposite. The commercial TiO2 photocatalyst (Degussa P25) was taken as standard photocatalyst to contrast the prepared different photocatalyst in current work. The improvement of the photocatalytic activity of S‐ZnO/TiO2 composite photocatalyst can be attributed to the suitable energetic positions between ZnO and TiO2, the acidity site caused by sulfur doping and the enlargement of the specific area. S‐3.0ZnO/TiO2 exhibited the highest photocatalytic activity under visible light irradiation after Zn amount was optimized, which was 2.6 times higher than P25. 相似文献
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Jie Xu Hui Zhang Lei Wang Guijie Liang Luoxin Wang Xiaolin Shen Weilin Xu 《Monatshefte für Chemie / Chemical Monthly》2010,17(1):549-555
Abstract
The ground-state geometries, electronic structures, and electronic absorption spectra of symmetrical squaraine dyes SQ1–SQ4 were investigated using density functional theory and time-dependent DFT at the B3LYP level. The calculated geometries indicate that strong conjugation effects occur in the dyes. The highest occupied molecular orbital energy levels were calculated to be −4.95, −5.22, −5.09, and −5.06 eV, and the lowest unoccupied molecular orbital energies were −2.72, −3.05, −2.80, and −2.80 eV for SQ1–SQ4, respectively. Taking the conduction band energy of TiO2 into account, these data reveal the sensitized mechanism: the interfacial electron transfer between the semiconductor TiO2 electrode and the dye sensitizers SQ1–SQ4 are electron-injection processes from excited dyes to the semiconductor conduction band. The intense calculated absorption bands are assigned to π → π* transitions, which exhibit appreciable blue-shift compared with the experimental absorption maxima due to the inherent approximations in the TD-DFT. 相似文献24.
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Synthesis and magnetic properties of organic multilayer films based on the layer‐by‐layer assembly 下载免费PDF全文
Two polymers containing pyridine rings were prepared by free‐radical polymerization and confirmed by Fourier transform infrared and 1H NMR spectra. The preparation of four multilayer films that were obtained by self‐assembly of the polymer and the transition metal neutralized polyelectrolyte on PE substrate was described. UV–vis spectra and atomic force microscopy images were applied to characterize these films and indicate the uniform assembling process. The driving force for building up the multilayer films was identified by infrared spectroscopy to be the coordination interaction. The magnetic behavior was examined as a function of magnetic field strength at 30 kOe and as a function of temperature (5–300 K). All films display strong soft ferromagnetic properties and higher than those of the bulk materials. The magnetic results show that the layer‐by‐layer self‐assembling approach is beneficial to the ordered alignment of adjacent paramagnetic spins and induces better magnetic phenomena. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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Symmetrical diynes were synthesized by ligand‐free copper‐catalyzed homocoupling reaction of 1,1‐dibromo‐1‐alkenes using a DBU/DMSO system at room temperature in good to excellent yields dot.?1. 相似文献
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This paper deals with the problems of consistency and strong consistency of the maximum likelihood estimators of the mean and variance of the drift fractional Brownian motions observed at discrete time instants. Both the central limit theorem and the Berry-Ess′een bounds for these estimators are obtained by using the Stein’s method via Malliavin calculus. 相似文献
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I.IntroductionTheResonanceScattcringThcory(RST)asanimportantmethodtoana1yzeacousticscat-teringofsubmergede1asticbodieswascxtcnsivelyuscdforcy1indrica1andspherica1geometries,inc1udingsolidstructuresandho11owoncs.RSTismain1yappliedtostudytheresonancescat-teringspcctra(oracousticspcctra)ofanc1astictargctcxcitedby'theinciderttacousticwavesoastOidentifythetargct.Tocxtracttheresonancescattcringspcctra,anappropriatebackgroundsuchasrigidbackgroundorsoftonemust-besubtractcd.Expcrimenta1ly,theReson… 相似文献