Self-assembling poly(dioxaborole)s as blue-emissive materials

Conjugated, borole-linked polymers have been self-assembled based on boronate ester formation between a fluorene-2,7-diboronic acid and 1,2,4,5-tetrahydroxybenzene. Readily soluble polymers with molecular weights approaching 60 000 have been generated with materials exhibiting extended conjugation over approximately 3-5 borole linkages. Emission from these polymers reaches into the visible (blue) range, representing a novel class of blue-emitting materials.     

基于模型辨识的BP神经网络在光伏系统MPPT中的应用

光伏电池作为光伏发电系统的重要组成部分,研究其模型的准确性并对其最大功率点进行预测与跟踪,对于光伏发电效率的提高具有重大意义。本文首先根据光伏电池的内部结构和伏安特性建立其数学模型,并对所建立的模型进行参数辨识,进而得到模型输出与测量信息偏差最小的参数值,验证模型的准确和有效性。根据模型所反映的规律,将温度和光照强度作为输入变量,最大功率点对应的电压作为输出变量,构建了用于MPPT的神经网络模型。神经网络经训练后对最大功率点电压进行预测与跟踪,结果表明构建的神经网络具有良好的适应性。     

二异丁胺修饰的天然壳聚糖磁性微球与铼的吸附行为

以生物质废弃物螃蟹壳为原料,通过简单的化学处理制成磁性微球,再经二异丁胺(DIBA)修饰合成了生物质吸附剂FCS-DIBA[FCS:Fe3O4与壳聚糖(CS)复合微球]。 FCS-DIBA对Re(Ⅶ)具有很高的吸附选择性,最大吸附量可达185 mg/g,而且不受环境酸度的影响,在pH=2条件下可实现Re(Ⅶ)与Cu(Ⅱ)、Zn(Ⅱ)、Mn(Ⅶ)和Fe(Ⅲ)等常见共存金属离子的分离,该吸附等温线符合Langmuir方程。 此外,对FCS-DIBA吸附铼的机制和吸附稳定性能等进行了探讨。     

Camina－Gagen定理的一个推广（Ⅱ）

设Ｇ是２－（ｖ，ｋ，１）设计Ｄ上的自同构群的一个子群，且是线－本原．如果（Ｖ，ｋ）＝ｋ／ｋ２，ｋ２≤１０．则Ｇ也是点－本原的。     

叔胺N235萃取柠檬酸的研究

用正辛醇－叔胺Ｎ２３５石油醚溶液萃取柠檬酸有协同效应，协萃系数Ｒ＝２．７萃取为一放热反应，Ｈ＝－１４．６ｋＪ．ｍｏｌ＾－１一次萃取率可达９２．２％，用稀盐酸反萃率为９９．３％。测定了协萃有机相的红外光谱。     

400GeV/c pp碰撞间歇指数的测量

利用CERNNA27合作组提供的LEBC泡室照片对400GeV/c pp碰撞产生的带电粒子赝快度分布进行了测量.计算了标度阶乘矩.得出间歇指数随矩阶数的增加而增加,随平均多重数的增加而变小;反常分形维数dq随q的增加而增加.这表明在强子-强子碰撞中多粒子产生具有自相似级联的性质.     

基于衍射微透镜的光学加速度传感器设计

提出了一种基于菲涅耳衍射微透镜的新型光学加速度传感器,它能够解决导航系统中惯性传感器普遍存在的抗电磁干扰和电磁冲击能力差等缺陷。其传感原理是把一个反光膜平行地置于衍射微透镜的后方,加速度的变化会改变反光膜的位置,根据微透镜前方会聚点处光强的变化,感知加速度的大小。介绍了传感器及其动力学系统的工作原理,并对衍射微透镜和动力学系统的微弹性机械结构进行了设计和加工,最后对传感器的性能和误差进行了分析。原理验证性实验的结果表明这种新型光学加速度传感器的原理正确,并且结构简单,灵敏度高。     

高中生物理学习障碍的原因浅析

据一项高中学科难度的调查显示，物理排在众学科之首．高中物理为何难学？笔者认为除了其学科本身的抽象性和复杂性外，重要的原因在于我们对物理学习的规律认识还不够清楚，把握不够准确，从而导致教学的力度和效果不够．本文拟从高中生学习的角度来探讨物理学习中的障碍成因，以期为改进高中物理教学提供参照．     

New Wine in Old Bottles: Prolonging Room‐Temperature Phosphorescence of Crown Ethers by Supramolecular Interactions

Supramolecular macrocyclic hosts have long been used in smart materials. However, their triplet emission and regulation at crystal level is rarely studied. Herein, ultralong and universal room‐temperature phosphorescence (RTP) is reported for traditional crown ethers. A supramolecular strategy involving chain length adjustment and morphological locking through complexation with K⁺ was explored as a general method to tune the phosphorescence lifetime in the solid state. A maximum 10‐fold increase of lifetime after complex formation accompanied with by invisible to visible phosphorescence was achieved. A deep encryption based on this activated RTP strategy was also facilely fabricated. This work thus opens a new world for supramolecular macrocycles and their intrinsic guest responsiveness offers a new avenue for versatile smart luminescent materials.     

Flash nanoprecipitation with Gd(III)‐based metallosurfactants to fabricate polylactic acid nanoparticles as highly efficient contrast agents for magnetic resonance imaging

Polylactic acid (PLA) nanoparticles coated with Gd(III)‐based metallosurfactants (MS) are prepared using a simple and rapid one‐step method, flash nanoprecipitation (FNP), for magnetic resonance imaging (MRI) applications. By co‐assembling the Gd(III)‐based MS and an amphiphilic polymer, methoxy poly(ethylene glycol)‐b‐poly(?‐caprolactone) (mPEG‐b‐PCL), PLA cores were rapidly encapsulated to form biocompatible T₁ contrast agents with tunable particle size and narrow size distribution. The hydrophobic property of Gd(III)‐based MS were finely tuned to achieve their high loading efficiency. The size of the nanoparticles was easily controlled by tuning the stream velocity, Reynolds number and the amount of the amphiphilic block copolymer during the FNP process. Under the optimized condition, the relaxivity of the nanoparticles was achieved up to 35.39 mM^?1 s^?1 (at 1.5 T), which is over 8 times of clinically used MRI contrast agents, demonstrating the potential application for MR imaging.