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101.
The crystal structure, magnetic and magnetotransport properties of the variation of B′-site transition metal in Sr2FeMO6 (M=Mo, W) with double perovskites structure have been investigated systematically. Measurements of magnetization vs. temperature at H=5 T show that Sr2FeMoO6 is a ferromagnet and Sr2FeWO6 is an antiferromagnet with TN∼35 K. Additionally, the large magnetoresistance ratio (MR) of ∼22% (H=3 T) at room temperature (RT) was observed in the Sr2FeWO6 compound. However, the Sr2FeMoO6 compound did not show any significant MR even at high fields and RT (MR∼1%; H=3 T and 300 K). The implications of these findings are supported by band structure calculations to explain the interaction between the 4d(Mo) and 5d(W) orbitals of transition metal ions and oxygen ions. 相似文献
102.
差分吸收光谱法测量大气痕量气体浓度误差分析及改善方法 总被引:8,自引:2,他引:6
差分吸收光谱技术(DOAS)中采用线性最小二乘拟合方法,用痕量气体标准差分吸收截面对测量得到的差分吸收光谱进行拟合,得出大气中痕量气体的浓度.计算结果的准确性不仅取决于光谱的测量精度,而且受标准差分吸收截面以及仪器函数和温度等诸多因素的影响.详细地分析了计算误差的产生原因,提出了用高浓度样品池得到标准吸收截面的方法,针对光谱固有结构,以及温度对标准吸收截面的影响,改进了浓度反演算法.大量的实验表明,综合运用上述方法,即便对低浓度的样气,相对测量误差也能降低到10%以下. 相似文献
103.
Yang Mujie Zhao Jian Li Aibing Shen Zhiquan Zhang Mingjian Lin Senhao 《Journal of polymer science. Part A, Polymer chemistry》1989,27(11):3829-3835
This paper reports that 60Co γ-ray irradiation can convert cis-polyphenylacetylene (cis-PPA) films prepared with rare-earth coordination catalysts to highly photosensitive materials. The dependence of the photosensitivity on irradiation dose, preparation methods, and microstructure of the PPA films has been investigated by means of a potential discharge technique. The photosensitivity was enhanced with increasing irradiation dose. The critical dose to produce a light response was 5 × 103 Gy. The maximum surface potential discharge rate was 618 V/s, and the dark decay was approximately 2 V/s for cis-PPA films irradiated with 60Co γ-ray (dose: 2 × 105 Gy). The cis-transoidal-PPA and an electrophotographic photoreceptor device incorporating cis-PPA showed a higher irradiation effect. The structure and properties of 60Co γ-ray irradiated rare-earth PPA films are similar to the unirradiated films. 相似文献
104.
Inspired by the recent work [HHM03], we prove two stability results for compact Riemannian manifolds with nonzero parallel spinors. Our first result says that Ricci flat metrics which also admit nonzero parallel spinors are stable (in the direction of changes in conformal structures) as the critical points of the total scalar curvature functional. Our second result, which is a local version of the first one, shows that any metric of positive scalar curvature cannot lie too close to a metric with nonzero parallel spinor. We also prove a rigidity result for special holonomy metrics. In the case of SU(m) holonomy, the rigidity result implies that scalar flat deformations of Calabi-Yau metric must be Calabi-Yau. Finally we explore the connection with a positive mass theorem of [D03], which presents another approach to proving these stability and rigidity results. Dedicated to Jeff Cheeger for his sixtieth birthday 相似文献
105.
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107.
We investigate the origin of ultraviolet (UV) emission from Mg0.12 Zn0.88 O alloy thin films with a wurtzite structure fabricated on c-plane Al2O3 substrates by plasma assisted molecular beam epitaxy. At room temperature, the absorption edge and UV emission band of the Mg0.12Zn0.88O film shift to high-energy side compared with ZnO films. Temperature dependence of the photoluminescence spectra shows that the UV emission is composed of free exciton and neutral donor bound exciton emissions. Two-step dissociation processes of the UV emission are observed with the increasing temperature. The thermal quenching mechanism is attributed to the dissociation of the free exciton from the neutral donor bound exciton in the low temperature region and the dissociation of free electron and hole from the free exciton in the high temperature region. 相似文献
108.
Ching‐Yuan Cheng Kuan‐Jiuh Lin 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(8):m363-m365
In the title compound, catena‐poly[lithium‐μ3‐ethylenediphosphonato], [Li(C2H7O6P2)]n, the supramolecular monoclinic (C2/c) structure consists of one‐dimensional lithium chains [Li⋯Li = 2.7036 (8) Å] that are embedded within ethylenediphosphonate anions linked by strong symmetric hydrogen bonds [O⋯O = 2.473 (3) Å]. The Li atoms and the H atom in the symmetric hydrogen bond reside on twofold rotation axes and there is an inversion center at the mid‐point of the C—C bond of the ethylenediphosphonate ligand. 相似文献
109.
家用吊扇的核心部分是单相异步电动机,此绕组如图1,有一主绕组(工作绕组)与一串联电容器C的副绕组(启动绕组)相并联.这样做可使二绕组的电流在相位上相差90°,从而形成旋转磁场.转子的转动过程与三相异步电动机相似. 相似文献
110.