The photoacoustic determination of fluorescence yields of dye solutions

A new method for the measurement of the primary fluorescence quantum yield of dye solutions is presented. The method is conceptually and experimentally simple, relying of the S_n → S₁ transition probability as an internal standard for comparison with the S₁ radiationless transition probability, both probabilities being measured by photoacoustic spectroscopy.     

The adsorption of chlorine and chloridation of Ag(111)

The adsorption of chlorine on the Ag(111) surface has been studied using LEED, Auger and temperature programmed desorption. Chlorine adsorbs dissociately with an initial sticking probability of ~ 0.4, and a precursor state is implicated in the chemisorption process. The chlorine appears to form a close-packed monolayer with the same packing density as in AgCl(111), and is epitaxially related to the substrate mesh. Chlorine continues to adsorb above a monolayer in coverage, though the sticking probability drops precipitately, being ~ 0.01 after the adsorption of 5 monolayers at 300 K. There is little increase in the chlorine Auger signal above one monolayer coverage at 300 K, but when adsorption is carried out at 240 K the chlorine signal is more than doubled. This is interpreted as being due to the formation of a layer structure of alternate Cl and Ag layers at the lower temperature, while adsorption at 300 K results in dissolution of subsurface Cl into the bulk of the crystal. Upon heating, the low temperature layer structure is destroyed, the chlorine signal diminishes to a limiting value at 450 K equivalent to the value for one adsorbed monolayer — apparently due to the dissolution of the near surface Cl layers into the bulk. However, the chlorine re-emerges at the surface at ~ 600 K, probably due to an exothermic heat of solution of Cl in the silver lattice. Desorption from the multilayers peaks at 670 K and both AgCl and Ag are desorbed coincidently with kinetics identical to those for the sublimation of bulk AgCl (ΔH = 235 kJ mol^?1, ΔS = 90 JK^?1 mol^?1). After the multilayers have desorbed, the final Cl layer desorbs in a higher temperature peak ( ~ 760 K) as AgCl (no silver desorption) which shows complex desorption kinetics indicative of the strong influence of a precursor state in the desorption process.     

The effect of cobalt doping on vanadyl pyrophosphate catalyst

Co-promoted vanadyl pyrophosphate catalyst (Co/V = 2.23 %) was prepared by classical organic method via VOHPO₄ ^.0.5H₂O precursor and calcined for 100 h in a mixture of n-butane in air. The synthesised catalyst was characterised by N₂ physisorption, ICP, X-ray diffraction, scanning electron microscopy, and temperature-programmed desorption of oxygen. This revised version was published online in June 2006 with corrections to the Cover Date.     

Masses of S and P wave mesons and pseudoscalar decay constants using a confinement scheme

In the framework of relativistic harmonic confinement model for quarks and antiquarks, the masses of S- and P-wave mesons and pseudoscalar decay constants from light flavour to heavy flavour sectors are computed. The residual two-body Coulomb interaction and the spin-dependent interaction of the confined one gluon exchange effects (COGEP) such as spin-spin and spin-orbit interactions are perturbatively incorporated with the confinement energy to get the respective vector-pseudoscalar meson mass differences. Here we employ the same parametrization and model parameters as used in a recent study of low-lying hadron masses and leptonic decay widths. The results are being compared with the values obtained from other theoretical models and the experimental values.     

Long time evolution of collisionless shocks in laser produced counterstreaming plasmas

Long time evolution of collisionless shocks in laser-produced plasmas is discussed. By irradiating a double plane target a high Mach number collisionless shock has been observed in laser produced counterstreaming plasmas [Kuramitsu et al., Phys. Rev. Lett., 106, 175002 (2011)]. While in early time we observe the shock in front of one plane, which is irradiated with the laser, we observe another shock in front of the other plane in much later time than the first shock formation. These two shocks coexist and collide or merge with each other as time passes. This means that the upstream plasmas for the first and second shocks have to be provided from the second and first shock sides, respectively, i.e., both the first and second shock have to be collisionless. There are two major candidates to account for the long time evolution of the collisionless shocks. One is that the secondary plasmas at the planes can be continuously created by the plasmas from the other planes. Another is that the actual shock thickness is much thiner than the detection limit, as indicated by numerical simulations.     

Upper Bounds in Affine Weyl Groups under the Weak Order

Björner and Wachs proved that under the weak order every quotient of a Coxeter group is a meet semi-lattice, and in the finite case is a lattice. In this paper, we examine the case of an affine Weyl group W with corresponding finite Weyl group W ₀. In particular, we show that the quotient of W by W ₀ is a lattice and that up to isomorphism this is the only quotient of W which is a lattice. We also determine that the question of which pairs of elements of W have upper bounds can be reduced to the analogous question within a particular finite subposet.