Tuning the cross-gap transition energy of a quantum dot by uniaxial stress

We show that a piezoelectric actuator can be used to apply uniaxial stress to a layer of self-assembled quantum dots. The applied stress leads to a change of the quantum dot's ground state exciton energy by up to a few hundred μeV. This approach allows the possibility of an in situ and continuous tuning of the stress at temperatures down to 4 K and offers an alternative to tuning by temperature and Stark effect. We measure the relative change in the charging energy to the n-doped back contact by capacitance and the change in the exciton energy by photoluminescence. By tuning the uniaxial stress we are able to perform reflection spectroscopy on a single dot.     

Bestimmung der Hexabromidzahl, insbesondere des Lein?ls

Ohne Zusammenfassung     

A high‐order triangular discontinuous Galerkin oceanic shallow water model

A high‐order triangular discontinuous Galerkin (DG) method is applied to the two‐dimensional oceanic shallow water equations. The DG method can be characterized as the fusion of finite elements with finite volumes. This DG formulation uses high‐order Lagrange polynomials on the triangle using nodal sets up to 15th order. Both the area and boundary integrals are evaluated using order 2N Gauss cubature rules. The use of exact integration for the area integrals leads naturally to a full mass matrix; however, by using straight‐edged triangles we eliminate the mass matrix completely from the discrete equations. Besides obviating the need for a mass matrix, triangular elements offer other obvious advantages in the construction of oceanic shallow water models, specifically the ability to use unstructured grids in order to better represent the continental coastlines for use in tsunami modeling. In this paper, we focus primarily on testing the discrete spatial operators by using six test cases—three of which have analytic solutions. The three tests having analytic solutions show that the high‐order triangular DG method exhibits exponential convergence. Furthermore, comparisons with a spectral element model show that the DG model is superior for all polynomial orders and test cases considered. Copyright © 2007 John Wiley & Sons, Ltd.     

The application of homotopy analysis method to solve nonlinear differential equation governing Jeffery–Hamel flow

In this paper Jeffery–Hamel flow has been studied and its nonlinear ordinary differential equation has been solved through homotopy analysis method (HAM). The obtained solution in comparison with the numerical ones represents a remarkable accuracy. The results also indicate that HAM can provide us with a convenient way to control and adjust the convergence region.     

Possible extensions of XIA's digital spectrometer technology to portable and remote monitoring instrumentation

The XIA DXP-4C, a 4 channel, CAMAC based X-ray spectrometer, is based on digitally processing directly digitized preamplifier signals. Designed for instrumenting multi-detector arrays for synchrotron radiation applications, the DXP-4C was optimized for very high count rates at a low cost per detector channel. These design constraints coincidentally lead to an instrument which is very compact and relatively low power (3.4 W/channel), considering its count rate and MCA capabilities, and which therefore offers interesting possibilities for effective extension to portable applications. Further, because all functions (gain, filter parameters, pileup inspection criteria and internal calibrations) are digitally controlled, the design can be readily adapted to a large variety of user interfaces, including remote access interfaces. Here we present the basics of the design and examine approaches to lowering the power to less than 300 mW/channel while retaining count rate capabilities in excess of 50,000 cps. We then consider the engineering issues associated with portable and remote spectrometry applications, examining in detail the three cases of a lead paint detector, a remote contamination monitor, and a space mission spectrometer.     

Fine structure of highly charged excitons in semiconductor quantum dots

An exciton in a symmetric semiconductor quantum dot has two possible states, one dark and one bright, split in energy by the electron-hole exchange interaction. We demonstrate that for a doubly charged exciton, there are also two states split by the electron-hole exchange, but both states are now bright. We also uncover a fine structure in the emission from the triply charged exciton. By measuring these splittings, and also those from the singly charged and doubly charged biexcitons, all on the same quantum dot, we show how the various electron-hole exchange energies can be measured without having to break the symmetry of the dot.     

Voltage control of the spin dynamics of an exciton in a semiconductor quantum dot

We report the observation of a spin-flip process in a quantum dot whereby a dark exciton with total angular momentum L = 2 becomes a bright exciton with L = 1. The spin-flip process is revealed in the decay dynamics following nongeminate excitation. We are able to control the spin-flip rate by more than an order of magnitude simply with a dc voltage. The spin-flip mechanism involves a spin exchange with the Fermi sea in the back contact of our device and corresponds to the high temperature Kondo regime. We use the Anderson Hamiltonian to calculate a spin-flip rate, and we find excellent agreement with the experimental results.     

Characterisation of derivatised monomeric and prepolymeric isocyanates by matrix-assisted laser desorption/ionisation time-of-flight mass spectrometry and structural elucidation by tandem mass spectrometry

Isocyanates are an important class of compounds in occupational hygiene monitoring due mainly to their behaviour as respiratory sensitisers. Here, we demonstrate the application of matrix-assisted laser desorption/ionisation mass spectrometry (MALDI-MS) and MALDI tandem mass spectrometry (MS-MS) to the analysis of derivatised isocyanate monomers and prepolymers. The aim of the work has been to gauge the selectivity obtainable from the direct analysis of isocyanate mixtures without prior separation. Monomeric and prepolymeric isocyanate mixtures were analysed as their 1-(2-methoxyphenyl) piperazine derivatives and the potential of MALDI time-of-flight (ToF)-MS for an NCO monitoring program was assessed. The results obtained demonstrated the possibility of direct mixture analysis by this method. MALDI-MS-MS was used for the elucidation of fragment structures in the prepolymer samples. The developed methodology was then applied to the analysis of swabs from an occupational hygiene monitoring scheme and enabled the identification of the isocyanate species detected.     

Rayleigh's contributions to modern vibration analysis

Although Rayleigh performed his work on vibrations approximately one hundred years ago, his contributions with their emphasis on energy principles, approximate methods of solution and use of physical insight to assess problems lead directly to some of the most powerful methods of vibration analysis, which are in use today. His contributions and their relationship to modern analytical methods are outlined and illustrated by simple examples.