流通池介质交换差示脉冲阳极溶出伏安法用于多元素重叠峰的分离及其同时测定

本文用流通池介质交换差示脉冲阳极溶出伏安法在盐酸介质中富集,而以碳酸钠-碳酸氢钠缓冲溶液为溶出介质,有效地分离了酸性介质中Cu(Ⅱ)、Sb(Ⅲ)、Pb(Ⅱ)、Tl(Ⅰ)、Cd(Ⅱ)、In(Ⅲ)的重叠溶出峰,实现了多离子的同时测定。     

核磁共振法测定高聚物的结构—核磁共振二维谱

介绍了核磁共振(NMR)波谱,尤其是核磁共振二维谱(2D NMR)在最近几年内的进展。内容包括怎样用NMR测定高聚物的序列分布、共聚物结构、聚合物的混溶性、聚合物液晶的取向度、分子量、短链度和长链支化度、凝聚态高聚物的多相结构等。     

LaNi4Fe催化合成氨反应性能的研究

用冶金法、还原扩散法、共沉淀法制得了LaNiFe,并对其催化合成氨反应性能进行了研究。实验结果表明:还原扩散法,共沉淀法制得的LaNi_4Fe催化活性均比冶金法好。X—射线分析指出LaNi_4Fe在合成氨反应过程中变为Ni_4Fe和LaN。     

毛细管离子交换电色谱的分离行为

在离子交换毛细管色谱柱上实施电色谱，并对其分离行为进行了研究，采用７５μｍ（ｉ．ｄ．）２０ｃｍ的毛细管强阳离子交换柱（３μｍ）以ＮａＨ２ＰＯ４－Ｈ３ＰＯ４缓冲液为淋洗剂，紫外柱上检测（２１４ｎｍ）考察了流动相的ｐＨ值，有机改性剂及分离电压等因素对分离的影响，研究表明，不同的ｐＨ溶质的流出次序发生改变，随着有机改性剂含量增加，溶质的保留时间减小，而电渗流却增大，同时，对分离的柱效和方法的重现性进行了     

血清硒浓度与口腔鳞癌相关性研究

分析了１９９４￣１９９５年在浙江医科大学附属第一医院门诊的口腔鳞癌患者的血清的硒浓度，结果表明口腔鳞癌患者血清硒浓度极显著低于正常人群，而手术后患者血清硒浓度又极显著高于手术前患者。     

因子分析—伏安法同时测定波峰重叠的混合物组份

本文将目标因子分析用于伏安分析法同时测定波峰重叠的混合物组份。用此法对Ｐｂ（Ⅱ）、Ｔｌ（Ｉ）混合体系的导数脉冲伏安重叠峰数据进行解析，获得了较理想的结果。     

双波长分光光度法同时测定岩石矿物中的微量金和钯

本文提出以硫代米蚩酮为显色剂，用双波长分光光度法同时测定岩石矿物中的微量金和钯的方法，消除了测定金钯的相互干扰，该方法简便，快速，选择性好，用于矿石样品中金和钯的测定，结果满意。     

立方介孔相含钇氧化硅的合成与表征

以低浓度的十六烷基三甲基溴化铵为结构导向剂,在碱性条件下通过水热法合成了具有立方结构的含钇Y MCM 48介孔分子筛材料。XRD测试表明当Y/Si<0.05时可以获得典型的长程有序介孔立方结构相,随Y/Si比的增加,晶胞参数的增大和红外吸收光谱(FTIR)的变化为Y进入介孔分子筛骨架中提供了有力证据。N2吸附-脱附实验给出这种立方介孔材料的BET表面积为1180m2·g-1,BJH平均孔径为3.4nm。紫外 可见漫反射光谱(UV vis)证明钇以一种六配位的形式存在。X射线光电子能谱(XPS)进一步证明钇以三价形式存在于立方介孔分子筛骨架中。     

Effects of electrolytes used in roughening gold substrates by oxidation–reduction cycles on surface-enhanced Raman scattering

In this work, the effects of electrolytes used in roughening gold substrates by electrochemical methods on surface-enhanced Raman scattering (SERS) were first investigated. First, gold substrates were roughened by triangular-wave oxidation–reduction cycles (ORC) in aqueous solutions containing different kinds of 0.1 M electrolytes. Then Rhodamine 6G (R6G) was used as Raman probe to examine this effect of electrolytes used on the SERS observed. The result indicates that the highest intensity of SERS of R6G was obtained on the roughened Au substrate prepared in 0.1 M NaCl, which was less used in the literature. Meanwhile, it was also found that the rougher surface morphology observed, which is contributive to the higher SERS obtained, is corresponding to the smaller cathodic peak area shown in the cyclic voltammograms for roughening the Au substrate.     

Comparison of localization and delocalization indices obtained with Hartree-Fock and conventional correlated methods: effect of Coulomb correlation

Atomic populations and localization [lambda(A)] and delocalization [delta(A,B)] indices (LIs and DIs) are calculated for a large set of molecules at the Hartree-Fock (HF), MP2, MP4(SDQ), CISD, and QCISD levels with the 6-311++G(2d,2p) basis set. The HF method and the conventional correlation methods [MP2, MP4(SDQ), CISD, and QCISD] yield distinct sets of LIs and DIs. Yet, within the four conventional correlation methods the differences in atomic populations and LIs and DIs are small. Relative to HF, the conventional correlation methods [MP2, MP4(SDQ), CISD, QCISD] yield virtually the same LIs and DIs for molecules with large charge separations while LIs and DIs that differ significantly from the HF values--the LIs are increased and DIs decreased--are obtained for bonds with no or small charge separations. Such is the case in the archetypal homopolar molecules HC(triple bond)CH, H2C=CH2, CH3-CH3, and "protonated cyclopropane" C(3)H(7) (+), in which case the bonding may be atypical. Relative to HF, the typical effect of the conventional correlation methods is to decrease the DI between atoms.