Synthesis of single crystalline layered lithium manganese oxide nanorods

Single-crystalline layered lithium manganese oxide nanorods were prepared via a low-temperature molten salt synthesis method. The material was investigated by a variety of techniques, including X-ray powder diffraction (XRD), transmission electron microscopy (TEM), and X-ray photoelectron spectrum (XPS).     

Finite element method in the solution of the Euler and Navier-Stokes equations for internal flow

Finite element solutions of the Euler and Navier-Stokes equations are presented, using a simple dissipation model. The discretization is based on the weak-Galerkin weighted residual method and equal interpolation functions for all the unknowns are permitted. The nonlinearity is iterated upon using a Newton method and at each iteration the linear algebraic system is solved by a direct solver with all unknowns fully coupled. Results are presented for two-dimensional transonic inviscid flows and two- and three-dimensional incompressible viscous flows. Convergence of the algorithm is shown to be quadratic, reaching machine accuracy in very few iterations. The inviscid results demonstrate the existence of nonunique numerical solutions to the steady Euler equations.     

Attractors of the sine-Gordon equation in the field of a quasiperiodic external force

The well-known sine-Gordon equation, supplemented with small damping and small quasiperiodic external force, is studied under the zero Dirichlet boundary conditions at the endpoints of a finite interval. The main assumption is that all frequencies of the external force are in 1:1 resonance with certain eigenfrequencies of the unperturbed equation; i.e., the socalled fundamental multifrequency resonance is observed. It is shown that in this case, by an appropriate choice of the parameters of the external force, one can make it so that the boundary value problem has a stable invariant torus of any finite dimension that bifurcates from zero on any preassigned finite set of spatial modes. It is also shown (by numerical analysis) that in a number of cases the above-mentioned torus coexists with a chaotic attractor.     

Statistical properties of the nonlinear negative binomial state

In this context, we introduce and investigate the properties of the nonlinear negative binomial state (the state which interpolates between the nonlinear coherent and the number states). Mainly we concentrate on the statistical properties for such state where we have discussed two different cases of squeezing phenomenon. The first case is the normal squeezing while the second is the amplitude squared squeezing, further the second order correlation function is also considered. Our discussion have been extended to include the quasi-probability distribution functions (W-Wigner and Q-functions). The quadrature distribution and the phase properties in Pegg-Barnett formalism besides the phase variances are considered. Examination of the resonance fluorescence against the present state is given (single atom and thermodynamic limit). It has been shown that the atomic inversion is sensitive to any variation in the nonlinear negative binomial number m.     

Interpretation of the polyelectrolyte and antipolyelectrolyte effects of poly(N‐vinylimidazole‐co‐sodium styrenesulfonate) hydrogels

Hydrogels of N‐vinylimidazole (VI) and sodium styrenesulfonate (SSS) were synthesized in aqueous solution by radical crosslinking copolymerization with N,N′‐methylene‐bis(acrylamide) as crosslinker. Swelling in several saline solutions was measured for hydrogel samples synthesized with different comonomer concentrations (C_T = 10, 25, or 40%) and with SSS mole fractions covering a broad range (f_SSS = 0–0.7), while the crosslinker ratio was 2 wt % in all cases. The degree of swelling in aqueous solution with a specific ionic strength (μ), plotted versus the SSS composition of the feed, shows a minimum for any set of samples synthesized with a fixed C_T. The dependence of swelling on μ shows both polyelectrolyte (f_SSS beyond the minimum) and antipolyelectrolyte behaviors (in the low f_SSS limit). It was found that the nonGaussian factor of the crosslinking density and the polymer‐solvent interaction parameter increase with f_SSS for any C_T. Moreover, in the low f_SSS limit, the osmotic swelling pressure is governed not only by the ionic contribution, but also by the polymer‐solvent mixing and, the concentration of mobile counterions inside the gel is not proportional to the net fixed charge but to the addition of cationic and anionic side groups, what discards the formation of ionic pairs. The antipolyelectrolyte effect is interpreted as due to the increasing protonation of VI as μ goes up. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1683–1693, 2007     

Crystal structure of bis(ethylenediamine)cuprate ethylenediaminetetraacetate-zinc(II) tetrahydrate

All-Union Research Institute for Chemical Reagents and High-Purity Chemicals. Translated from Zhurnal Strukturnoi Khimii, Vol. 31, No. 5, pp. 140–143, September–October, 1990.     

On the invertibility of the operator <Emphasis Type="Italic">d/dt</Emphasis> + <Emphasis Type="Italic">A</Emphasis> in certain functional spaces

We prove that the operator d/dt + A constructed on the basis of a sectorial operator A with spectrum in the right half-plane of ℂ is continuously invertible in the Sobolev spaces W _p ¹ (ℝ, D _α), α ≥ 0. Here, D _α is the domain of definition of the operator A ^α and the norm in D _α is the norm of the graph of A ^α. __________ Translated from Ukrains’kyi Matematychnyi Zhurnal, Vol. 59, No. 8, pp. 1020–1025, August, 2007.     

Thermographic inspection of TBC coated gas turbine blades: Discrimination between coating over-thicknesses and adhesion defects

When performing in-field tests on thermal barrier coatings (TBCs) deposited on gas turbine blades, the main problem encountered is the difficulty to correctly interpret the experimental data. The coating thickness changes, which are not regarded as anomalies, are one of the most common sources of false alarms. They are very challenging to recognize because, unlike stains, eroded areas and optical property variations, they are not detectable in the visible band. Furthermore, their thermal signal is similar to the one produced by an adhesion defect. In this paper, a procedure to reliably discriminate thickness changes and real defects is proposed. The approach is based on the analysis of the apparent effusivity profile. Preliminary results are presented and discussed.     

Discovery of a new long-lived isomeric state in 125Ce

A new long-lived isomeric state in the near proton dripline nucleus ¹²⁵Ce has been identified with Schottky mass spectrometry at GSI. The excitation energy E ^* = 103(12)keV and the decay time of 193(1)s have been obtained from a single stored fully ionized ^125m Ce⁵⁸⁺ ion. The data implies an E3 transition and a 1/2⁺ assignment for the spin of the isomer.     

Photoacoustic spectroscopy for fast and sensitive ammonia detection

A photoacoustic (PA) spectrometer with H-type first longitudinal resonant cells for ammonia detection is developed. A new PA cell structure is designed to accelerate the drift velocity of the sample gas near the cell surface, so that the short response time at the flow rate of 100 sccm (standard cubic centimeter per minute) is achieved. The response time of 5 min and detection limit of 0.86 ppbv is reached for ammonia concentration measurement with a Teflon polytetrafluoroethylene (PTFE) cell. Further improvement could be expected when using a brass cell with a high quality Teflon fluorinated ethylene propylene (FEP) coating.