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191.
It is found that the fluorescence intensity of Tb3+-oxolinic acid (OA) complex can be greatly quenched by albumins in sodium dodecyl sulphate (SLS). Under optimum conditions, the quenched fluorescence intensity is in proportion to the concentration of proteins in the range of 5.0×10−8-1.0×10−5 g ml−1 for bovine serum albumin (BSA), 1.0×10−7-1.0×10−5 g ml−1 for human serum albumin (HSA) and 4.0×10−7-1.0×10−5 g ml−1 for egg albumin (EA). Their detection limits (S/N=3) are 2.1×10−8, 2.5×10−8 and 5.0×10−8 g ml−1, respectively. In addition, the interaction mechanism is also investigated. 相似文献
192.
Potential PDP phosphors with strong absorption around 172 nm: Rare earth doped NaLaP2O7 and NaGdP2O7
Jun Lin Yuan Jiao Wang Ding Bang Xiong Jing Tai Zhao Yi Bing Fu Chao Shu Shi 《Journal of luminescence》2007,126(2):717-722
NaLaP2O7 and NaGdP2O7 powder samples are prepared by solid-state reactions at 750 and 600 °C, respectively, and the VUV-excited luminescence properties of Ln3+ (Ln=Ce, Pr, Tb, Tm, Eu) in both diphosphates are studied. Ln3+ ions in both hosts show analogous luminescence. For Ce3+-doped samples, the five Ce3+ 5d levels can be clearly identified. As for Pr3+ and Tb3+-doped samples, strong 4f-5d absorption band around 172 nm is observed, which matches well with Xe-He excimer in plasma display panel (PDP) devices. As a result, Pr3+ can be utilized as sensitizer to absorb 172 nm VUV photon and transfer energy to appropriate activators, and Tb3+-doped NaREP2O7(RE=La, Gd) are potential 172 nm excited green PDP phosphors. For Tm3+ and Eu3+-doped samples, the Tm3+-O2− charge transfer band (CTB) is observed to be at 177 nm, but the CTB of Eu3+ is observed at abnormally low energy position, which might originate from multi-position of Eu3+ ions. The similarity in luminescence properties of Ln3+ in both hosts indicates certain structural resemblance of coordination environment of Ln3+ in the two sodium rare earth diphosphates. 相似文献
193.
整体X光透镜性能实验研究 总被引:4,自引:2,他引:4
利用高计数率探测器和低功率光源,在大的能量范围内,同时测量了整体X光透镜的传输效率和焦斑直径与能量的关系。实验结果表明:透镜的焦斑直径随着能量的升高而减小;对04-5-10-5透镜而言,在高于5.8keV的能量范围内,透镜的传输效率随着能量的升高而降低,在低于5.8keV的能量范围内,透镜的传输效率随着能量的升高而增加。通过测量不同能量的X射线在透镜会聚光束中的空间分布,研究了短出口焦距透镜的光晕现象,光晕会导致透镜焦斑直径增大和传输效率测量值的增加。利用轴向扫描法研究了整体X光透镜出口焦距和能量的关系,实验结果表明:会聚透镜的出口焦距随着X射线能量的升高而增加。 相似文献
194.
小孔阵列衍射特性与应用 总被引:1,自引:4,他引:1
以单色标量波衍射理论为基础,研究了均匀平面波从不同角度入射小孔阵列的衍射特性。运用单孔衍射理论,同时考虑相邻小孔间衍射光强的相互影响,建立了小孔阵列衍射的理论模型和光强分布的数值积分式,小孔为硬边小孔。利用Matlab对500 nm波长的平面波入射微小方孔阵列衍射图样进行了计算机仿真,得到了不同几何参量下平面波从不同角度入射时的衍射图样的一维和二维光强分布图,并将仿真结果用于微型数字式太阳敏感器的光学系统中的结构参量设计和图像处理中的参量确定。太阳敏感器的成像实验结果表明,小孔阵列衍射光强分布图的仿真结果正确、太阳敏感器光学系统参量设计合理。小孔阵列衍射理论为太阳敏感器的光学系统设计和图像处理提供了可靠的理论基础。 相似文献
195.
物理隔离网络的电磁攻击手段, 其主要目标是建立与外部互联网的隐蔽连接通道。近年来跨越物理隔离网络的方法和工具被陆续公开, 相应的分析方法和检测手段也逐步被国内外安全团队提出。掌握漏洞才能掌握网络安全的主动权, 对比网络安全漏洞, 电磁漏洞定义为能对设备或系统造成损害的电磁因素。以物理隔离网络为例, 电磁漏洞主要指的是网络的硬件和系统缺陷, 利用这些缺陷可以直接建立或通过植入恶意软件建立能突破物理隔离的电磁信号的信息收、发隐蔽通道。通过广泛的漏洞挖掘与验证, 从物理信号类型、信息传递方向、信号生成与作用机理、漏洞利用方式以及漏洞检测方法上提出物理隔离网络电磁漏洞分类方法; 通过综合借鉴网络安全漏洞、电磁信息安全检测、物理隔离隐蔽通道等领域的研究方法, 提出电磁漏洞的研究方法; 从深化主动检测、群智漏洞挖掘、网络电磁安全融合、大数据监测等角度, 提出了物理隔离网络电磁漏洞库的建立方法。 相似文献
196.
Yu Ding Ruggero Micheletto Hiroaki Hanada Toshihiko Nagamura Satoshi Okazaki Koji Otsuka 《Optical Review》2002,9(6):277-281
This work describes a groundbreaking process that provides a direct highly localized measurement of the atomic mass on surfaces at room temperature. Employing an original system that joins a scanning tunneling microscopy (STM) device and a time of flight (TOF) mass analyzer, we could previously ionize surface atoms by the combination of an optical laser pulse and an electric pulse at the STM tip. Desorbed ions from a localized area were accelerated and detected by a TOF chamber. We will demonstrate in this paper that high localization and mass discrimination can be obtained even without the aid of an electric pulse from the tip. We reduced the angle of incidence of the laser beam to zero (laser beam parallel to the sample surface). In this condition we were able to demonstrate for the first time ionic desorption at a confinement level of the order of 5-10nm, an order of magnitude better than previous configurations.This paper was originally presented at the 11th Optical Near Field Workshop, which was held on June 28, 2002 at Tokyo Institute of Technology, Yokohama, organized by the Optical Near Field Group of the Optical Society of Japan, an affiliate of the Japan Society of Applied Physics. 相似文献
197.
198.
A microscopic theory is presented for the observed electronic disorder in superconducting Bi2Sr2CaCu2O8+delta. The essential phenomenology is shown to be consistent with the existence of two types of interstitial oxygen dopants: those serving primarily as charge reservoirs and those close to the apical plane contributing both carriers and electrostatic potential to the CuO2 plane. The nonlinear screening of the latter produces nanoscale variations in the doped hole concentration, leading to electronic inhomogeneity. Based on an unrestricted Gutzwiller approximation of the extended t-J model, we provide a consistent explanation of the correlation between the observed dopant location and the pairing gap and its spatial evolutions. We show that the oxygen dopants are the primary cause of both the pairing gap disorder and the quasiparticle interference pattern. 相似文献
199.
I. K. Bensafa P. Achenbach M. Ases Antelo C. Ayerbe D. Baumann R. Böhm D. Bosnar E. Burtin X. Defaÿ N. D'Hose M. Ding M. O. Distler L. Doria H. Fonvieille J. M. Friedrich J. Friedrich J. García Llongo P. Janssens G. Jover Mañas M. Kohl G. Laveissière M. Lloyd M. Makek J. Marroncle H. Merkel P. Merle U. Müller L. Nungesser B. Pasquini R. Pérez Benito J. Pochodzalla M. Potokar G. Rosner S. Sánchez Majos M. Seimetz S. Širca T. Spitzenberg G. Tamas R. Van de Vyver L. Van Hoorebeke Th. Walcher M. Weis 《The European Physical Journal A - Hadrons and Nuclei》2007,32(1):69-75
The beam-helicity asymmetry has been measured simultaneously for the reactions
p→epγ and
p→epπ
0 in the Δ(1232)-resonance region at Q
2 = 0.35(GeV/c)2. The experiment was performed at MAMI with a longitudinally polarized beam and an out-of-plane detection of the proton. The
results are compared with calculations based on dispersion relations for virtual Compton scattering and with the MAID model
for pion electroproduction. There is an overall good agreement between experiment and theoretical calculations. The remaining
discrepancies may be ascribed to an imperfect parametrization of some γ
(*)
N→πN multipoles, mainly contributing to the non-resonant background. The beam-helicity asymmetry in both channels (γ and π
0) shows a good sensitivity to these multipoles and should allow future improvement in their parametrization. 相似文献
200.
Responsive mechanism of 2-(2'-hydroxyphenyl)benzoxazole-based two-photon fluorescent probes for zinc and hydroxide ions 下载免费PDF全文
Response theory is used to investigate one- and two-photon absorption(TPA) as well as the emission properties of a series of potential zinc ion and pH sensitive materials containing 2-(2’-hydroxyphenyl)benzoxazole(HPBO) end groups.Special emphasis is placed on the evolution of their optical properties upon combining with zinc ions or deprotonation.Our calculated results indicate that upon combining with zinc ions or deprotonation,these HPBO derivatives show drastic changes in their one-photon absorption(OPA),emission,and TPA properties.Moreover,the mechanisms of the probes are analyzed and found to be an intramolecular charge transfer.These compounds are thus proved to be excellent candidates for two-photon fluorescent zinc and pH probes. 相似文献