Orlicz空间中Kantorovi(c)算子逼近等价定理

以带权函数的连续模为工具,讨论了Ｋａｎｔｏｒｏｖｉｃ算子在Ｏｒｌｉｃｚ空间中逼近的正、逆定理,进而得到其等价刻划。     

铁磁链Landau-Lifshitz方程的显式差分法

正如在研究流体动力学时,Ｎａｖｉｅｒ－Ｓｔｏｋｅｓ方程起着十分重要的作用一样,在对于非平衡态磁学的研究中,描述连续铁磁体自旋场发展过程的 Ｌａｎｄａｎ－Ｌｉｆｓｈｉｔｚ方程［１］起着十分重要的作用［２］．一九九三年,美国和印度签署了一个大约 ２８０万美元的合作研究计划,在三年的时间里,对Ｌａｎｄａｕ－Ｌｉｆｓｈｉｔｚ铁磁链方程进行研究．在无阻尼的情况下,它为一完全可积的孤立子系统［３,４,５］。很多物理学家研究了它的孤立子解的存在性、逆散射方法以及相互碰撞［３,４,５］．关于解的存在性, Ａｌｏｎ…     

Nanofibrous Membranes Containing Carbon Nanotubes: Electrospun for Redox Enzyme Immobilization

Summary: Nanofibrous membranes that possess reactive groups are fabricated by the electrospinning process from PANCAA solutions that contain MWCNTs. Field emission scanning electron microscopy is used to evaluate the morphology and diameter of the nanofibers. Potentials for applying these nanofibrous membranes to immobilize redox enzymes by covalent bonding are explored. It is envisaged that the electrospun nanofibrous membranes could provide a large specific area and the MWCNTs could donate/accept electrons for the immobilized redox enzymes. Results indicate that, after blending with MWCNTs, the diameter of the PANCAA nanofiber increases slightly. The PANCAA/MWCNT nanofibrous membranes immobilize more enzymes than that without MWCNTs. Moreover, as the concentration of the MWCNTs increases, the activity of the immobilized catalase is enhanced by about 42%, which is mainly attributed to the promoted electron transfer through charge‐transfer complexes and the π system of MWCNTs.

The covalent immobilization of redox enzymes, such as catalase, on a PANCAA/MWCNTs nanofiber.     

新型手性双核Salen Zn(II)配合物的分子识别研究

采用新型Salen中间体合成了新型Salen Zn(II)配合物. 用紫外-可见光谱滴定法研究了主体双核Salen Zn(II)与咪唑、二胺类等含氮小分子的分子识别行为, 测定了它们的缔合常数. 对咪唑类客体的缔合常数顺序为K^θ(Im)＞K^θ(2-MeIm)＞K^θ(EMeIm); 对二胺类客体缔合常数顺序为K^θ(DAP)＞K^θ(DAE). 主体与咪唑类和二胺类客体的配位数分别是2和1. 主体与这些客体的识别过程为放热、熵减的焓驱动反应. 利用圆二色光谱研究了识别过程的Cotton效应. 用分子力学方法研究了主客体体系的最低能量构型, 通过量化计算对实验事实做了进一步解释.     

长江中游地区战国青铜箭镞的锈蚀形态

利用扫描电子显微镜（SEM）、能谱仪（EDS）、显微硬度等分析测试技术从材料科学和物理学的角度对长江中游地区战国晚期占楚墓中出土地的青铜箭镞的锈蚀现象进行了较为全面的研究和分析．发现由于锈蚀程度不同,青铜箭镞的组织结构可分为完全矿化层、过渡层和心部原始材料等3个特征层,其中主要成分为氧化物的完全矿化层的结构最疏松,硬度最低;另外,由于埋藏环境的不同,不同地区的锈蚀分层又有差异．实验还对两种类型的开裂裂纹进行了分析,认为一种裂纹是由矿化层氧化物膨胀引起的剥离开裂,进一步发展形成所谓的“粉状锈”;另一种裂纹是当圆柱形箭镞杆膨胀时,矿化层的塑性差,抗变形能力低而产生的开裂．     

Electrically Conductive Poly(DL‐lactide)/Chitosan/Polypyrrole Complexes

Summary: The fabrication of novel conductive poly(DL ‐lactide)/chitosan/polypyrrole complex membranes is reported. Using poly(DL ‐lactide)/chitosan blends as matrices and polypyrrole as a conductive component, several kinds of membranes with various compositions are prepared. A percolation threshold of polypyrrole as low as 1.8 wt.‐% is achieved for some membranes by controlling the chitosan proportion between 40 and 50 wt.‐%. SEM images exhibit that the membranes with a low percolation threshold show a two‐phase structure which consists of poly(DL ‐lactide) and chitosan phases. Dielectric measurements indicate that there is limited miscibility between the poly(DL ‐lactide) and chitosan but polypyrrole is nearly immiscible with the other two components. Based on the structural characteristics of the membranes, the polypyrrole particles are suggested to be localized at the interface between two phases.

Dependence of conductivity of complex membranes on the PPy content. (○) PDLLA/PPy, (▪) PDLLA/ch(10)/PPy, (▵) PDLLA/ch(20)/PPy, (•) PDLLA/ch(30)/PPy, (□) PDLLA/ch(40)/PPy, and (▴) PDLLA/ch(50)‐PPy.     

Hydrophobicity of Polyaniline Microspheres Deposited on a Glass Substrate

Summary: A highly hydrophobic surface with a water contact angle of 148.0° has been constructed by depositing salicylic acid‐doped polyaniline (PANI‐SA) spheres on a glass substrate using a template‐free method. The hydrophobicity originates from the contribution of the air trapped in the inter‐space of a rough surface aggregated by micro‐ and nanospheres. Moreover, the deposition time strongly affects the hydrophobicity of the PANI‐SA spheres deposited on the substrate. The formation mechanism and hydrophobic origin of the PANI‐SA spheres deposited on the substrate are discussed.

The PANI films prepared at 60 min polymerization time is composed of co‐existing nano‐ and microspheres (left). The ability of the layers to trap large amounts of air makes the surface highly hydrophobic and results in a water contact angle of 148.0° (right).     

过氧化氢水溶液作用下甲烷水合物分解特性的分子动力学模拟研究

采用分子动力学模拟方法研究过氧化氢水(HP)溶液作用下结构I型(SI)甲烷水合物晶体分解特性. 系统分析甲烷水合物在过氧化氢水溶液作用下由晶态向液态转变过程的机理, 对比相同摩尔浓度乙二醇(EG)溶液作用下甲烷水合物分解变化规律, 得出HP与水合物热力学抑制剂EG一样对甲烷水合物分解具有促进作用, 为HP溶液促进甲烷水合物分解实验研究提供参考.     

Ab-initio and modeling study of some amino acid-tRNA: NMR shielding and thermodynamic of solvent effect (Poster Presentation)

The tRNA molecule takes suitable amino acid to the ribosome for the formation of peptide bonds. In starting the peptide chain, the first amino acid which is taken to the ribosome is methionine. We have simulated methionine-amino acid bonding and amino acid-tRNA bonding, using a mixed study of quantum mechanics ab-initio and molecular mechanics. NMR shielding tensors and thermodynamic parameters and total energies are also calculated. It is important to understand the physical properties and the environmental conditions in which the dipeptides cause the tRNA to attach to a wrong amino acid. One of the properties studied is the dielectric environment of in which the bonding occurs. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Multigrid fictitious boundary and grid deformation methods for flow-induced rotation of wing

Numerical simulations of flow-induced rotation of wing by multigrid fictitious boundary and grid deformation methods are presented. The flow is computed by a special ALE formulation with a multigrid finite element solver. The solid wing is allowed to move freely through the computational mesh which is adaptively aligned by a special mesh deformation method. The advantage of this approach is that no expensive remeshing has to be performed. (© 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)