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31.
A new echo type with free electrons in a slight inhomogeneous magnetic field excited by one electric and one magnetic pulse is calculated. Thus features of cyclotron echos and spin echoes are combined. The first electric pulse accelerates all (cold) particles to the same velocity as in the case of usual cyclotron echoes. The second magnetic pulse (at t = τ) rotates the plane of precession in phase space, quite in analogy to the motion of magnetic moments in the case of spin echoes. The echo arises at t = 2τ. The E-H echoes make relaxation and diffusion measurements in plasmas possible, using the methods proved useful in spin echo technique. There are no complications as in the case of E-E cyclotron echoes which are based on the fact that a velocity-dependent collision frequency is necessary for the nonlinearity of that echo mechanism. 相似文献
32.
A one-dimensional model is developed for the [111] transverse modes of the mixed crystal NaC?1?xBrx. The frequencies and eigenvectors of the normal modes of vibration are calculated for ten random configurations at each of a number of compositions. The imaginary part of the dielectric function is calculated for the average configuration at each composition. The behavior of the system cannot be classified in terms of the usual one-mode or two-mode categories. Representative eigenvectors are displayed, and the random element isodisplacement model is discussed in the light of our results. 相似文献
33.
Geng J Mantovani G Tao L Nicolas J Chen G Wallis R Mitchell DA Johnson BR Evans SD Haddleton DM 《Journal of the American Chemical Society》2007,129(49):15156-15163
Synthesis of well-defined neoglycopolymer-protein biohybrid materials and a preliminary study focused on their ability of binding mammalian lectins and inducing immunological function is reported. Crucial intermediates for their preparation are well-defined maleimide-terminated neoglycopolymers (M(n) = 8-30 kDa; M(w)/M(n) = 1.20-1.28) presenting multiple copies of mannose epitope units, obtained by combination of transition-metal-mediated living radical polymerization (TMM LRP) and Huisgen [2+3] cycloaddition. Bovine serum albumin (BSA) was employed as single thiol-containing model protein, and the resulting bioconjugates were purified following two independent protocols and characterized by circular dichroism (CD) spectroscopy, SDS PAGE, and SEC HPLC. The versatility of the synthetic strategy presented in this work was demonstrated by preparing a small library of conjugating glycopolymers that only differ from each other for their relative epitope density were prepared by coclicking of appropriate mixtures of mannopyranoside and galactopyranoside azides to the same polyalkyne scaffold intermediate. Surface plasmon resonance binding studies carried out using recombinant rat mannose-binding lectin (MBL) showed clear and dose-dependent MBL binding to glycopolymer-conjugated BSA. In addition, enzyme-linked immunosorbent assay (ELISA) revealed that the neoglycopolymer-protein materials described in this work possess significantly enhanced capacity to activate complement via the lectin pathway when compared with native unmodified BSA. 相似文献
34.
New Compounds in the System CaO/SiO2/CaCl2/H2O The hydrothermal formation of novel calcium silicate hydrates of compositions 5 CaO · 2 SiO2 · CaCl2 · 4 H2O, 5 CaO · 2 SiO2 · CaCl2 · 2 H2O and 4 CaO · 2 SiO2 · CaCl2 · H2O from Ca3SiO5 and mixtures of CaO and SiO2, respectively, in presence of calciumchloride at 200°–350 °C is described. From molybdate-reaction, 29Si MAS NMR, DTA and TG measurements it is concluded that these compounds are based on disilicate anions and are to be interpreted as calcium hydroxide disilicate chlorides. 相似文献
35.
Denise Wallis 《Journal of organometallic chemistry》2009,694(6):828-6143
From the reaction of Super Hydride (LiBEt3H) with 6-(4-methoxyphenyl) fulvene (1a), 6-(2-fluoro-4-methoxyphenyl) fulvene (1b), and 6-(4-N,N-dimethylaminophenyl) fulvene (1c) lithiated cyclopentadienide intermediates (2a-c) were synthesised. These intermediates were then transmetallated to zirconium with ZrCl4 to give benzyl-substituted zirconocenes bis-[(4-methoxybenzyl)cyclopentadienyl] zirconium(IV) dichloride (3a), bis-[(2-fluoro-4-methoxybenzyl)cyclopentadienyl] zirconium(IV) dichloride (3b) and bis-[(4-N,N-dimethylaminobenzyl)cyclopentadienyl] zirconium(IV) dichloride (3c). All three zirconocenes were characterised by single crystal X-ray diffraction and preliminary in vitro cell tests were performed with the zirconocene derivatives on the LLC-PK cell line in order to determine their cytotoxicity. Zirconocenes 3b and 3c did not show cytotoxicity up to a concentration of 170 μM, while 3a exhibited an IC50 value of 57 μM against LLC-PK. 相似文献
36.
The solid-state conformations of five peri-disubstituted naphthalenes bearing a methylthio group and an electron-deficient alkene indicate a weak attractive interaction between the functional groups in four cases in which out-of-plane displacements lead to a common orientation of the MeSsp(2)-C vector to the alkene bond. In some cases the interaction is not strong enough to outweigh the tendency of the alkene to conjugate with the aromatic ring, and in one case this optimisation of conjugation alone controls the molecular conformation. The methylthio group lies close to the aromatic plane in all but one example for which the plane of the sulfide group is presented to the alkene. 相似文献
37.
A Lari MB Pitak SJ Coles GJ Rees SP Day ME Smith JV Hanna JD Wallis 《Organic & biomolecular chemistry》2012,10(38):7763-7779
The X-ray crystal structures of salts and zwitterionic Knoevenagel products from 1-dimethylamino-naphthalene-8-carbaldehyde show long N-C bonds between peri-groups which provide models for incomplete nucleophilic attack on a protonated carbonyl group and electron-deficient alkenes respectively. For the salts the N-C bonds lie in the range 1.625-1.638 ? with C-OH bonds intermediate in length between single and double bonds, while for the zwitterions the N-C bonds lie in the range 1.612-1.660 ?. The structural assignment of the former is supported by solid state (13)C and (15)N NMR studies on doubly isotopically-labelled material. Several zwitterions were converted to naphtha[1,8-bc]azepines by a mechanism involving the tertiary amino effect. 相似文献
38.
A Mukherjee M Dasgupta DJ Hinde CR Morton AC Berriman RD Butt JO Newton H Timmers 《Pramana》2001,57(1):195-198
Fusion cross-sections for the 7Li + 12C reaction have been measured at energies above the Coulomb barrier by the direct detection of evaporation residues. The heavy
evaporation residues with energies below 3 MeV could not be separated out from the α-particles in the spectrum and hence their
contribution was estimated using statistical model calculations. The present work indicates that suppression of fusion cross-sections
due to the breakup of 7Li may not be significant for 7Li + 12C reaction at energies around the barrier. 相似文献
39.
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