Niedermolekulare diorganozinn-sauerstoff-verbindungen: di-t-butyl- und di-t-amylzinnoxid

Di-t-butyltin oxide (t-Bu₂SnO)₃ and di-t-amyltin oxide (t-Am₂SnO)₃ were synthesized by hydrolysis of the diorganotin dichlorides. Their molecular and crystal structures were investigated by X-ray diffraction techniques and vibrational spectroscopy. Both compounds form isolated molecules with planar six-membered tin-oxygen rings.     

Increase of the Specific Absorption Rate (SAR) by Magnetic Fractionation of Magnetic Fluids

Magnetic fractionation was applied to a common magnetic fluid based on superparamagnetic iron-oxide nano-particles with core radius of 5nm. The fractions collected were investigated with respect to particle-sizes and the influence of fractionation on the specific absorption rate, in order to optimize magnetic fluids for the application in hyperthermia.     

Stability of Black Holes and Black Branes

We establish a new criterion for the dynamical stability of black holes in D ≥ 4 spacetime dimensions in general relativity with respect to axisymmetric perturbations: Dynamical stability is equivalent to the positivity of the canonical energy, ${\mathcal{E}}$ , on a subspace, ${\mathcal{T}}$ , of linearized solutions that have vanishing linearized ADM mass, momentum, and angular momentum at infinity and satisfy certain gauge conditions at the horizon. This is shown by proving that—apart from pure gauge perturbations and perturbations towards other stationary black holes— ${\mathcal{E}}$ is nondegenerate on ${\mathcal{T}}$ and that, for axisymmetric perturbations, ${\mathcal{E}}$ has positive flux properties at both infinity and the horizon. We further show that ${\mathcal{E}}$ is related to the second order variations of mass, angular momentum, and horizon area by ${\mathcal{E} = \delta^2 M -\sum_A \Omega_A \delta^2 J_A - \frac{\kappa}{8\pi}\delta^2 A}$ , thereby establishing a close connection between dynamical stability and thermodynamic stability. Thermodynamic instability of a family of black holes need not imply dynamical instability because the perturbations towards other members of the family will not, in general, have vanishing linearized ADM mass and/or angular momentum. However, we prove that for any black brane corresponding to a thermodynamically unstable black hole, sufficiently long wavelength perturbations can be found with ${\mathcal{E} < 0}$ and vanishing linearized ADM quantities. Thus, all black branes corresponding to thermodynmically unstable black holes are dynamically unstable, as conjectured by Gubser and Mitra. We also prove that positivity of ${\mathcal{E}}$ on ${\mathcal{T}}$ is equivalent to the satisfaction of a “ local Penrose inequality,” thus showing that satisfaction of this local Penrose inequality is necessary and sufficient for dynamical stability. Although we restrict our considerations in this paper to vacuum general relativity, most of the results of this paper are derived using general Lagrangian and Hamiltonian methods and therefore can be straightforwardly generalized to allow for the presence of matter fields and/or to the case of an arbitrary diffeomorphism covariant gravitational action.     

Essay: Quantum Field Theory Is Not Merely Quantum Mechanics Applied to Low Energy Effective Degrees of Freedom

It is commonly assumed that quantum field theory arises by applying ordinary quantum mechanics to the low energy effective degrees of freedom of a more fundamental theory defined at ultra-high-energy/short-wavelength scales. We shall argue here that, even for free quantum fields, there are holistic aspects of quantum field theory that cannot be properly understood in this manner. Specifically, the subtractions needed to define nonlinear polynomial functions of a free quantum field in curved spacetime are quite simple and natural from the quantum field theoretic point of view, but are at best extremely ad hoc and unnatural if viewed as independent renormalizations of individual modes of the field. We illustrate this point by contrasting the analysis of the Casimir effect, the renormalization of the stress-energy tensor in time-dependent spacetimes, and anomalies from the point of quantum field theory and from the point of view of quantum mechanics applied to the independent low energy modes of the field. Some implications for the cosmological constant problem are discussed.     

On the Rigidity Theorem for Spacetimes with a Stationary Event Horizon or a Compact Cauchy Horizon

We consider smooth electrovac spacetimes which represent either (A) an asymptotically flat, stationary black hole or (B) a cosmological spacetime with a compact Cauchy horizon ruled by closed null geodesics. The black hole event horizon or, respectively, the compact Cauchy horizon of these spacetimes is assumed to be a smooth null hypersurface which is non-degenerate in the sense that its null geodesic generators are geodesically incomplete in one direction. In both cases, it is shown that there exists a Killing vector field in a one-sided neighborhood of the horizon which is normal to the horizon. We thereby generalize theorems of Hawking (for case (A)) and Isenberg and Moncrief (for case (B)) to the non-analytic case. Received: 4 November 1998 / Accepted: 13 February 1999     

Aqueous One-Pot Synthesis of Derivatized Cyclopentadienyl-Tricarbonyl Complexes of 99mTc with an In Situ CO Source: Application to a Serotonergic Receptor Ligand

No Abstract     

Axiomatik des Zwischenbegriffes in metrischen Räumen

Ohne Zusammenfassung