Increase of the Specific Absorption Rate (SAR) by Magnetic Fractionation of Magnetic Fluids

Magnetic fractionation was applied to a common magnetic fluid based on superparamagnetic iron-oxide nano-particles with core radius of 5nm. The fractions collected were investigated with respect to particle-sizes and the influence of fractionation on the specific absorption rate, in order to optimize magnetic fluids for the application in hyperthermia.     

Antibacterial Activity and Synergistic Effect of Biosynthesized AgNPs with Antibiotics Against Multidrug-Resistant Biofilm-Forming Coagulase-Negative Staphylococci Isolated from Clinical Samples

Silver nanoparticles form promising template for designing antimicrobial agents against drug resistant pathogenic microorganisms. Thus, the development of a reliable green approach for the synthesis of nanoparticles is an important aspect of current nanotechnology research. In the present investigation, silver nanoparticles synthesized by a soil Bacillus sp. were characterized using UV–vis spectroscopy, FTIR, SEM, and EDS. The antibacterial potential of biosynthesized silver nanoparticles, standard antibiotics, and their conjugates were evaluated against multidrug-resistant biofilm-forming coagulase-negative S. epidermidis strains, S. aureus, Salmonella Typhi, Salmonella Paratyphi, and V. cholerae. Interestingly, silver nanoparticles (AgNPs) showed remarkable antibacterial activity against all the test strains with the highest activity against S. epidermidis strains 145 and 152. In addition, the highest synergistic effect of AgNPs was observed with chloramphenicol against Salmonella typhi. The results of the study clearly indicate the promising biomedical applications of biosynthesized AgNPs.     

Quantum Field Theory on Spacetimes with a Compactly Generated Cauchy Horizon

We prove two theorems which concern difficulties in the formulation of the quantum theory of a linear scalar field on a spacetime, , with a compactly generated Cauchy horizon. These theorems demonstrate the breakdown of the theory at certain base points of the Cauchy horizon, which are defined as ‘past terminal accumulation points’ of the horizon generators. Thus, the theorems may be interpreted as giving support to Hawking's ‘Chronology Protection Conjecture’, according to which the laws of physics prevent one from manufacturing a ’time machine‘. Specifically, we prove: Theorem 1. There is no extension to of the usual field algebra on the initial globally hyperbolic region which satisfies the condition of F-locality at any base point. In other words, any extension of the field algebra must, in any globally hyperbolic neighbourhood of any base point, differ from the algebra one would define on that neighbourhood according to the rules for globally hyperbolic spacetimes. Theorem 2. The two-point distribution for any Hadamard state defined on the initial globally hyperbolic region must (when extended to a distributional bisolution of the covariant Klein-Gordon equation on the full spacetime) be singular at every base point x in the sense that the difference between this two point distribution and a local Hadamard distribution cannot be given by a bounded function in any neighbourhood (in M × M) of (x,x). In consequence of Theorem 2, quantities such as the renormalized expectation value of φ² or of the stress-energy tensor are necessarily ill-defined or singular at any base point. The proof of these theorems relies on the ‘Propagation of Singularities’ theorems of Duistermaat and H?rmander. Received: 14 March 1996/Accepted: 11 June 1996     

On the possibility of a box for holding gravitational radiation in thermal equilibrium

We show that it is possible in principle to build a box which will hold gravitational radiation for a time long enough to thermalize it. The box is a thin spherical shell of charged matter with a large red shift at the surface of the shell. The radiation is kept in the box by the gravitational potential of the shell and is thermalized by the conversion between gravitational and electromagnetic radiation. We calculate the time for escape of the radiation and show that it is longer than the conversion time.     

Stability of Black Holes and Black Branes

We establish a new criterion for the dynamical stability of black holes in D ≥ 4 spacetime dimensions in general relativity with respect to axisymmetric perturbations: Dynamical stability is equivalent to the positivity of the canonical energy, ${\mathcal{E}}$ , on a subspace, ${\mathcal{T}}$ , of linearized solutions that have vanishing linearized ADM mass, momentum, and angular momentum at infinity and satisfy certain gauge conditions at the horizon. This is shown by proving that—apart from pure gauge perturbations and perturbations towards other stationary black holes— ${\mathcal{E}}$ is nondegenerate on ${\mathcal{T}}$ and that, for axisymmetric perturbations, ${\mathcal{E}}$ has positive flux properties at both infinity and the horizon. We further show that ${\mathcal{E}}$ is related to the second order variations of mass, angular momentum, and horizon area by ${\mathcal{E} = \delta^2 M -\sum_A \Omega_A \delta^2 J_A - \frac{\kappa}{8\pi}\delta^2 A}$ , thereby establishing a close connection between dynamical stability and thermodynamic stability. Thermodynamic instability of a family of black holes need not imply dynamical instability because the perturbations towards other members of the family will not, in general, have vanishing linearized ADM mass and/or angular momentum. However, we prove that for any black brane corresponding to a thermodynamically unstable black hole, sufficiently long wavelength perturbations can be found with ${\mathcal{E} < 0}$ and vanishing linearized ADM quantities. Thus, all black branes corresponding to thermodynmically unstable black holes are dynamically unstable, as conjectured by Gubser and Mitra. We also prove that positivity of ${\mathcal{E}}$ on ${\mathcal{T}}$ is equivalent to the satisfaction of a “ local Penrose inequality,” thus showing that satisfaction of this local Penrose inequality is necessary and sufficient for dynamical stability. Although we restrict our considerations in this paper to vacuum general relativity, most of the results of this paper are derived using general Lagrangian and Hamiltonian methods and therefore can be straightforwardly generalized to allow for the presence of matter fields and/or to the case of an arbitrary diffeomorphism covariant gravitational action.     

Glassy correlations and microstructures in randomly cross-linked homopolymer blends

We consider a microscopic model of a polymer blend that is prone to phase separation. Permanent cross-links are introduced between randomly chosen pairs of monomers, drawn from the Deam-Edwards distribution. Thereby, not only density but also concentration fluctuations of the melt are quenched-in in the gel state, which emerge upon sufficient cross-linking. We derive a Landau expansion in terms of the order parameters for gelation and phase separation, and analyze it on the mean-field level, including Gaussian fluctuations. The mixed gel is characterized by thermal as well as time-persistent (glassy) concentration fluctuations. Whereas the former are independent of the preparation state, the latter reflect the concentration fluctuations at the instant of cross-linking, provided the mesh size is smaller than the correlation length of phase separation. The mixed gel becomes unstable to microphase separation upon lowering the temperature in the gel phase. Whereas the length scale of microphase separation is given by the mesh size, at least close to the transition, the emergent microstructure depends on the composition and compressibility of the melt. Hexagonal structures, as well as lamellas or random structures with a unique wavelength, can be energetically favorable.     

Interactions of dispersion-managed solitons in wavelength-division-multiplexed optical transmission lines

We investigate interactions between pulses in dispersion-managed multichannel wavelength-division-multiplexed soliton systems, using an improved variational approximation. The frequency shifts are found to be smallest for moderate, i.e., relatively short-scale, dispersion management. The position shifts increase monotonically with map strength.     

Aqueous One-Pot Synthesis of Derivatized Cyclopentadienyl-Tricarbonyl Complexes of 99mTc with an In Situ CO Source: Application to a Serotonergic Receptor Ligand

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