Essay: An Alternative to Inflation

Inflationary models are generally credited with explaining the large scale homogeneity, isotropy, and flatness of our universe as well as accounting for the origin of structure (i.e., the deviations from exact homogeneity) in our universe. We argue that the explanations provided by inflation for the homogeneity, isotropy, and flatness of our universe are not satisfactory, and that a proper explanation of these features will require a much deeper understanding of the initial state of our universe. On the other hand, inflationary models are spectacularly successful in providing an explanation of the deviations from homogeneity. We point out here that the fundamental mechanism responsible for providing deviations from homogeneity—namely, the evolutionary behavior of quantum modes with wavelength larger than the Hubble radius—will operate whether or not inflation itself occurs. However, if inflation did not occur, one must directly confront the issue of the initial state of modes whose wavelength was larger than the Hubble radius at the time at which they were born. Under some simple hypotheses concerning the birth time and initial state of these modes (but without any fine tuning), it is shown that non-inflationary fluid models in the extremely early universe would result in the same density perturbation spectrum and amplitude as inflationary models, although there would be no slow roll enhancement of the scalar modes.     

Über das Verhalten von Metall-Äthylendiamintetraessigsäure-Komplexen an Anionenaustauschersäulen; II. Thorium-Komplexe

Ohne ZusammenfassungMit 3 Abbildungen     

"Contact voltage" in nanoparticle/molecule connections

This work presents conclusive evidence that connecting Pt and Co nanoparticles stabilized by an aluminum-organic shell with molecular spacers interacting with this shell can induce notable changes in the electronic structure of the metal. X-ray absorption spectroscopy measurements at the Al K-, the Pt L(III)-, and the Co K-edge provide consistent evidence for this effect. The changes induced by cross-linking with an acidic spacer are discussed in detail as an example to elucidate the mechanism of this effect. It turns out that a reconfiguration of the protection shell that occurs upon networking is responsible for the observed changes.     

Heating in the MRI environment due to superparamagnetic fluid suspensions in a rotating magnetic field

In the presence of alternating-sinusoidal or rotating magnetic fields, magnetic nanoparticles will act to realign their magnetic moment with the applied magnetic field. The realignment is characterized by the nanoparticle's time constant, τ. As the magnetic field frequency is increased, the nanoparticle's magnetic moment lags the applied magnetic field at a constant angle for a given frequency, Ω, in rad/s. Associated with this misalignment is a power dissipation that increases the bulk magnetic fluid's temperature which has been utilized as a method of magnetic nanoparticle hyperthermia, particularly suited for cancer in low-perfusion tissue (e.g., breast) where temperature increases of between 4 and 7 degree Centigrade above the ambient in vivo temperature cause tumor hyperthermia. This work examines the rise in the magnetic fluid's temperature in the MRI environment which is characterized by a large DC field, B₀. Theoretical analysis and simulation is used to predict the effect of both alternating-sinusoidal and rotating magnetic fields transverse to B₀. Results are presented for the expected temperature increase in small tumors (approximately 1 cm radius) over an appropriate range of magnetic fluid concentrations (0.002-0.01 solid volume fraction) and nanoparticle radii (1-10 nm). The results indicate that significant heating can take place, even in low-field MRI systems where magnetic fluid saturation is not significant, with careful selection of the rotating or sinusoidal field parameters (field frequency and amplitude). The work indicates that it may be feasible to combine low-field MRI with a magnetic hyperthermia system using superparamagnetic iron oxide nanoparticles.     

Protein adhesion on dental surfaces—a combined surface analytical approach

Protein adsorption is a field of huge interest in a number of application fields. Information on protein adhesion is accessible by a variety of methods. However, the results obtained are significantly influenced by the applied technique. The objective of this work was to understand the role of adhesion forces (obtained by scanning force spectroscopy, SFS) in the process of protein adsorption and desorption. In SFS, the protein is forced to and retracted from the surface, even under unfavorable conditions, in contrast to the natural situation. Furthermore, adhesion forces are correlated with adhesion energies, neglecting the entropic part in the Gibbs enthalpy. In this context, dynamic contact angle (DCA) measurements were performed to identify the potential of this method to complement SFS data. In DCA measurements, the protein diffuses voluntarily to the surface and information on surface coverage and reversibility of adsorption is obtained, including entropic effects (conformational changes and hydrophobic effect). It could be shown that the surface coverage (by DCA) of bovine serum albumin on dental materials correlates well with the adhesion forces (by SFS) if no hydrophobic surface is involved. On those, the entropic hydrophobic effect plays a major role. As a second task, the reversibility of the protein adsorption, i.e., the voluntary desorption as studied by DCA, was compared to the adhesion forces. Here, a correlation between low adhesion forces and good reversibility could be found as long as no covalent bonds were involved. The comparative study of DCA and SFS, thus, leads to a more detailed picture of the complete adsorption/desorption cycle.     

How to mine energy from a black hole

We describe a process by which energy literally can be mined from a black hole. We argue that the only limit placed by fundamental considerations on the rate at which energy can be extracted from a black hole by this process isdE/dt ～ 1 in Planck unitsG = c = ? = 1. This is far greater than the ratedE/dt ～ 1/M² at which the black hole spontaneously loses energy by Hawking radiation.