OMS-2/Al2O3/堇青石整体式催化剂的制备及其催化性能研究

以Al₂O₃/堇青石蜂窝陶瓷为载体,氧化锰八面体分子筛(OMS-2)为活性组分,采用涂覆法制备了系列整体式催化剂。考察了黏合剂种类和活性组分涂覆次数对二甲醚(DME)催化燃烧性能的影响,并对催化剂进行XRD、BET、SEM、H₂-TPR、O₂-TPD等表征。结果表明,以甲氧基聚乙二醇为黏合剂经一次涂覆制备的整体式催化剂的性能最佳,活性组分OMS-2以相互交织的簇体均匀分布在载体上,并与Al₂O₃之间存在较强的相互作用。涂层的添加有效增加了催化剂的比表面积,提高了催化剂的性能,最佳催化活性t₉₀为257 ℃。     

三维开放骨架镧系金属有机配位聚合物Tm(BTC)(DMF)(DMSO)的合成、结构和性质

以稀土元素铥(Tm) 作为金属中心, 均苯三甲酸(H3BTC)作为有机配体制备了一个新型的三维配位聚合物 Tm(BTC)(DMF)(DMSO), 并通过X射线单晶衍射、元素分析、热重分析、吸附测试等手段对其进行了表征.     

含有脂肪族侧链的聚醚醚酮的合成、表征及结构与性能关系

以苯酚和含有不同链长的长链脂肪酮作为原料, 制备了与双酚A结构相似的双酚单体, 并与4, 4'-二氟二苯酮共聚, 合成了几种含有不同长度脂肪族侧链结构的聚醚醚酮类(PEEKs)聚合物. 利用元素分析和核磁共振氢谱(1H NMR)对所合成的双酚单体进行了表征, 并用红外光谱(FTIR)\, 示差量热扫描仪(DSC)、热失重分析仪(TGA)和电子拉力机对所合成的聚合物结构和性能的关系进行了研究.     

聚烯烃共混物注射制品的形态控制与多层次结构

从注射制品形态控制和结构表征的角度探讨高分子材料加工-形态-性能之间的关系.研究中采用动态保压成型方法来制备注射样品,在注射成型过程中引入剪切应力场的作用,制得的样品表现出明显的多层次结构,从外向里分别为皮层、剪切层、芯层,表现出不同的相形态、结晶形貌以及取向行为.研究发现,剪切应力对聚烯烃的形态发展和结构变化具有重要影响.在剪切应力的作用下,聚烯烃共混物中分散相会发生变形、取向,从而导致共混物的相转变点发生移动;结晶形态从球晶转变为shish-kebab结构;聚烯烃共混物在高剪切应力下相容,低剪切下发生相分离;HDPE/PP共混物的注射制品中出现附生结晶等现象.     

Angular distributions of muon pairs produced by 194 GeV/c negative pions

We present the angular distributions of muon pairs obtained in a high-statistics experiment using a 194-GeV/c π^- impinging on a tungsten target. Our results are based on the analysis of 145,000 events with positive Feynmanx and mass above 4.07 GeV/c², excluding the ? region. Simple first-order QCD relations allow us to determine the ratio of annihilation with hard-gluon emission to the sum of annihilation with hard-gluon emission and hard-gluon Compton scattering, which is found to be about 58% to 75%. We determine the parton square intrinsic transverse momenta to be of the order of 0.6 (GeV/c)², and about 30% larger in the pion than in the nucleon. At largex ₁, our data agree with the higher-twist hypothesis, and support the interpretation of the relevant scale parameter as the dimuon square transverse momentum.     

Optical characterization of xTiO2-(60 − x)SiO2-40Na2O glasses: II. Absorption edge, Fermi level, electronic polarizability and optical basicity

In the present work different optical properties of xTiO₂-(60 − x)SiO₂-40Na₂O (wt%) optical glasses are determined. The characterization is done over a wide energy range, 0.41-6.2 eV. The refractive index and the extinction coefficient data are used to measure the absorption coefficient of the different glass compositions. Studying the UV-absorption edge, both direct and indirect allowed transitions with their optical energy gaps are carried out. In the same time, the Urbach energy is evaluated. From the extinction coefficient data, the Fermi energy of the glasses is calculated. The molar refraction, electronic polarizability and the optical basicity are obtained using the measured glass refractive indices.     

Experimental results on proton diffractive dissociation

Properties of proton diffractive dissociation have been investigated for four-prong final states in proton-proton reactions at 360 GeV/c, in particular forpp→ppπ ⁺π^? mπ ⁰(m=0,1,2). Mass distributions and decay angular distributions are given. The decay of the diffractive system is seen to be very anisotropic, and largep _T is suppressed at higher masses. It is found that the “pomeron” couples with a single valence quark of the incident proton, but indications for a diquark-pomeron coupling are also found. Similarities with fragmentation in lepton-hadron deep inelastic scattering are underlined.     

Mode of layer displacements in MX2-type crystals

Using van der Waals potential, the relative strengths of interlayer and intralayer bonds have been estimated in the halides of cadmium and lead. The results have been compared with the recent Raman studies of rigid layer modes in MX₂-type layer compounds and X-ray diffraction studies of fused cadmium iodide. It is found that the interlayer bond is relatively much weaker than the intralayer bond. Accordingly, it is concluded that in the polytypic MX₂-type compounds CdI₂, CdBr₂ and PbI₂, only X-X glide takes place in the polytypic transformations observed during crystal growth and during high temperature treatment of the polytypes. The nature of the X-X glide has been examined in detail.     

具有几个光振荡周期的飞秒激光脉冲

从麦克斯韦方程组出发 ,推导出了具有几个光振荡周期的飞秒激光脉冲在非线性光纤中传输的方程和非线性光纤的折射率。给出了描述具有几个光振荡周期的飞秒激光脉冲在非线性光纤中传输方程的解。研究了在非线性光纤中自相位调制导致具有几个光振荡周期的飞秒激光脉冲频谱展宽 (脉宽压缩 )的详细物理过程。研究了非线性光纤中飞秒光孤子产生的条件