全文获取类型
收费全文 | 16825篇 |
免费 | 3315篇 |
国内免费 | 6197篇 |
专业分类
化学 | 12283篇 |
晶体学 | 716篇 |
力学 | 1265篇 |
综合类 | 865篇 |
数学 | 2645篇 |
物理学 | 8563篇 |
出版年
2024年 | 43篇 |
2023年 | 154篇 |
2022年 | 605篇 |
2021年 | 545篇 |
2020年 | 541篇 |
2019年 | 532篇 |
2018年 | 510篇 |
2017年 | 875篇 |
2016年 | 587篇 |
2015年 | 793篇 |
2014年 | 1014篇 |
2013年 | 1290篇 |
2012年 | 1261篇 |
2011年 | 1402篇 |
2010年 | 1443篇 |
2009年 | 1456篇 |
2008年 | 1712篇 |
2007年 | 1488篇 |
2006年 | 1551篇 |
2005年 | 1363篇 |
2004年 | 1018篇 |
2003年 | 737篇 |
2002年 | 735篇 |
2001年 | 826篇 |
2000年 | 818篇 |
1999年 | 496篇 |
1998年 | 280篇 |
1997年 | 214篇 |
1996年 | 231篇 |
1995年 | 177篇 |
1994年 | 185篇 |
1993年 | 157篇 |
1992年 | 185篇 |
1991年 | 117篇 |
1990年 | 130篇 |
1989年 | 108篇 |
1988年 | 104篇 |
1987年 | 124篇 |
1986年 | 82篇 |
1985年 | 62篇 |
1984年 | 78篇 |
1983年 | 66篇 |
1982年 | 49篇 |
1981年 | 44篇 |
1980年 | 30篇 |
1979年 | 34篇 |
1978年 | 17篇 |
1977年 | 10篇 |
1965年 | 13篇 |
1964年 | 14篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
261.
The Fourier transform far infrared spectra of oxalate hydrates of whole rare-earth series except Pm and Sc are investigated in the range of 100-400 cm~(-1). The assignment of vibrational frequencies is made on the basis of normal coordinate analysis using our NORVIB program. The model used for the hghter elements of the lanthanide series (La to Eu) is based on the crystal structure of Nd_2(C_2O_4)_3. 10H_2O, in which each lanthanide ion is surrounded by nine O atoms, six from three oxalate ions and three from Water molecules.The model adopted for the heavier elements of the lanthanide series (Gd to Lu) and Ytterbium is based on the crystal structure of Yb_2(C_2O_4)_3· 6H_2O, in which each ion is surrounded by eight atoms, six from three oxalate ions and two from water molecules. The variation of the metal-ligand frequencies and force constants with the atomic numbers of lanthanides is plotted and discussed. 相似文献
262.
263.
研究了4-位苯基取代基旋转受阻和旋转自由的2,4,6-三苯基氧盐的光物理性质。实验结果表明,当4-位苯基取代基旋转受阻时,氧盐化合物在激发态时引起的分子内极化程度比4-位取代基旋转自由的氧盐化合物大,即在激发态时旋转受阻氧盐化合物发生的分子内电荷转移能力较强;4-位取代基旋转自由的化合物的荧光量子产率随溶剂粘度的增大而有所增大,但旋转受阻化合物在相同的条件下则出现相反的结果。实验结果还表明,4-位取代苯基旋转受阻对化合物的荧光发射不利。 相似文献
264.
265.
The paper reports the formation and crystal structure of dihydronitidine, expounds thereasons and conditions of easily formed oxynitidine, and discusses anticancer mechanism ofnitidine (cation). The crystallographic parameters of dihydronitidine are: space group P2_(1/n),a= 12.54(1), b = 9. 148(5), c = 14.748(8)A, β= 92. 12(6)°,Z =4. 4108 independent reflec-tions were collected within the range of 3°≤2θ≤54°, of which 2137 intensity data with I≥3σ(I) were used in the structural determination. The crystal structure has been refined byfull matrix least-square method to a final R of 0.050. 相似文献
266.
267.
268.
A wholly-aromatic thermotropic liquid crystalline polymer (WATLCP) composed ofp-hydroxybenzoic acid (HBA), 4,4'-dihydroxy bisphenyl (BP), terephthalic acid (TPA),m-phthalic acid (MPA) was synthesized. It was symbolized by BP-LCP. Using a simi-lar method, a new copolymer BP-PSF was prepared. BP-PSF has a semi-flexible chainpolysulfone and a rigid-rod chain like BP-LCP. By FT-IR, polarizing microscope and DSCtechnique, the structures and properties of BP-LCP and BP-PSF were studied. 相似文献
269.
Chen Xia DU Zhi Qiang WANG Qi XIN Yang Jie WU Wen Lian LI Department of Chemistry Zhengzhou University Zhengzhou Changchun institute of optics Fine Mechanics Physics Chinese Academy of Sciences Changchun 《中国化学快报》2005,(5)
In recent years, the interest in developing luminescent lanthanide complexes has been greatly stimulated by their potential use in electroluminescent displays1. Europium complexes appear most attractive in view of the high photoluminescent efficiency and the high monochromatic red light that are widely exploited in full-color displays2. It has been approved that the second ligand plays an important role in europium complexes, the synergistic complexation of the second ligand can not only lead … 相似文献
270.
A Kinetic Evidence for the Nitroxyl Radicals Recycling Mechanism in the Photostabilizing Process of HALS 总被引:1,自引:0,他引:1
XiaoXuanLIU XingHongZHANG GuangGuoWU JianWenYANG ZhaoHuaZENG YongLieCHEN 《中国化学快报》2003,14(10):1085-1088
The photoinduced bulk polymerization of a reactive-hindered amine fight stabilizers(r-HALS), 4-acryloyl-2, 2, 6, 6-tetramethylpiperidinyl (ATMP), was performed at 80℃ by using a DPC technique. An unique periodic exponential attenuation-type oscillating curve was found when the polymerization was carried out in air, but this phenomenon was not found in nitrogen.It is supposed that this unique kinetic performance may be attributed to nitroxyl radicals that are produced in situ from the oxidation of ATMP. ATMP polymer with narrow polydispersity (d =1.03) can be obtained by photoinduced solution polymerization of ATMP. The signal detected in ESR may be assigned to the nitroxyl radicals in the matrix of ATMP polymer. Since this kind of recycling of nitroxyl radicals is well documented for the photostabilizing mechanism of HALS, the present results may serve as a kinetic evidence for this mechanism. 相似文献