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171.
研制一种新型可移动式微量氧分析仪检定装置。该装置由标准气体、零点气、脱氧纯化器、减压阀、调节阀、4通阀、5通阀、不锈钢管路、流量控制系统、移动平台等组成。该装置气密性好,15 min内可将装置内氧气浓度由20.9%降至不大于0.1μmol/mol,对于0~10μmol/mol的微量氧分析仪检定结果的扩展不确定度为Urel=1.7%FS(k=2)。该装置满足气体标准物质的连续切换和在线检定的需要,检定时间短,结果准确可靠,可为在线式和非在线式微量氧分析仪的量值溯源提供有效保障。 相似文献
172.
WANG Yongtao GUO Xianwei LIN Zhiyuan YANG Yubo WU Lingqiao LIU Huan YU Haijun 《高等学校化学研究》2020,36(3):439-446
The sphene-type solid electrolyte with high ionic conductivity has been designed for solid-state lithium metal battery. However, the practical applications of solid electrolytes are still suffered by the low relative density and long sintering time of tens of hours with large energy consumption. Here, we introduced the spark plasma sintering technology for fabricating the sphene-type Li1.125Ta0.875Zr0.125SiO5 solid electrolyte. The dense electrolyte pellet with high relative density of ca. 97.4% and ionic conductivity of ca. 1.44×10-5 S/cm at 30℃ can be obtained by spark plasma sintering process within the extremely short time of only ca. 0.1 h. Also the solid electrolyte provides stable electrochemical window of ca. 6.0 V(vs. Li+/Li) and high electrochemical interface stability toward Li metal anode. With the enhanced interfacial contacts between electrodes and electrolyte pellet by the in-situ formed polymer electrolyte, the solid-state lithium metal battery with LiFePO4 cathode can deliver the initial discharge capacity of ca. 154 mA·h/g at 0.1 C and the reversible capacity of ca. 132 mA·h/g after 70 cycles with high Coulombic efficiency of 99.5% at 55℃. Therefore, this study demonstrates a rapid and energy efficient sintering strategy for fabricating the solid electrolyte with dense structure and high ionic conductivity that can be practically applied in solid-state lithium metal batteries with high energy densities and safeties. 相似文献
173.
PVC/CPE blend modified by rigid particles has good combined properties. In this paper, the effeCts of rigid particles (PMMA. PS. CaCO,) on the rheological behavior of PVC/ CPE systems were studied. The results showed that the apparent viscosity (aha) were decreased, extrusion surface smooth and Newtonian fluidity were slightly improved by filling a little amount of rigid ploymers (PS. PMMA) to PVC/CPE blends. The fluid activition energy (E,). Newtonian fluidity. extrusion surface smooth and ba of PVC/CPE blends were increased by filling CaCO3 and die swelling ratio was decreased.The newtonian fluidity. En and ηa of PVC/CPE/CaCO3 blends can be decreased by filling rigid polymers,and good extrusion surface smooth and low die swelling ratio unchanged. 相似文献
174.
Pd(OAc)2/FePc催化环己烯氧化合成环己酮的研究 总被引:6,自引:0,他引:6
考察了几种Fe-大环配合物与Pd(OAc)2组成的双组分催化体系,在乙腈酸性水溶液中环己烯经合成环己酮的催化活性,实验结果表明,其中以酞菁失(FePc)与Pd(OAc)2组成的催化体系活性最高,而FeTPPCl与Pd(OAc)2催化体系,虽然催化活性较高,但催化剂的稳定性较低,各种因素对Pd(OAc)2/FePc催化活催化影响的研究结果指出,在无水和酸存在的非水溶液中,Pd(OAc)2/FePc对 相似文献
175.
新型醋酸乙烯酯/二乙烯苯共聚物的研究(Ⅱ)──醇解物的制备、结构及其性能吴向东,郭贤权,何炳林(南开大学高分子化学研究所,天津,300071)关键词皂化反应,醇解物,芳香族氨基酸,孔结构参数,吸附性能氨基酸失衡是指肝性脑病患者血液中芳香族氨基酸的浓度... 相似文献
176.
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179.
YueMingLIU FengMeiZHANG HaiHongWU HaiJiaoZHANG JianGuoYANG XingTianSHU MingYuanHE 《中国化学快报》2004,15(10):1258-1260
A SAPO-11 silicoaluminophosphate molecular sieve with stable crystal structure was synthesized for the first time. After removing template by calcination, its crystal space group still retains Icm2 which the as-synthesized has. The catalyst deriving from the present SAPO-I 1 materials shows higher isomerization selectivity and higher paraffin hydroisomerization yield than those reported elsewhere. 相似文献
180.
DFT Study on the (S)-Proline-catalyzed Direct Aldol Reaction between Acetone and 4-Nitrobenzaldehyde
1 INTRODUCTION Aldol reaction, one of the most important C–C bond-formation reactions, is widely utilized in orga- nic synthesis[1]. Extensive efforts have been donated to the development of catalytic stereo-selective va- riants of this reaction[2]. However, the direct aldol reaction between unmodified carbonyles would be the most attractive synthetic alternative. Proline-catalyzed intermolecular direct aldol reac- tion between acetone and 4-nitrobenzaldehyde was first reported by List… 相似文献