现场拉曼光谱研究乙腈在金电极上的解离吸附行为

利用共焦显微拉曼系统、结合合适的电极表面粗糙方法研究了非水体系 0 1mol/LLiClO4 /CH3CN溶液中 ,乙腈分子在金表面的吸附和解离行为。结果表明非水体系中乙腈可在金表面发生还原反应 ,产物CN- 离子与电极表面作用形成的表面配合物可在较宽的电位区间吸附于电极表面。溶液中的微量水、激光照射以及电极电位均对该反应有较大的影响。通过拉曼谱图的比较得出乙腈分子解离出的CN- 在金电极表面比在银电极表面有更强的吸附作用。     

Acoustic vector sensor signal processing

Acoustic vector sensor simultaneously, colocately and directly measures orthogonal components of particle velocity as well as pressure at single point in acoustic field so that is possible to improve performance of traditional underwater acoustic measurement devices or detection systems and extends new ideas for solving practical underwater acoustic engineering problems. Although acoustic vector sensor history of appearing in underwater acoustic area is no long, but with huge and potential military demands, acoustic vector sensor has strong development trend in last decade, it is evolving into a one of important underwater acoustic technology. Under this background, we try to review recent progress in study on acoustic vector sensor signal processing, such as signal detection, DOA estimation, beamforming, and so on.     

Ab Initio Study on the Isomerization and Dehydrogenation of Methylnitrene

The ab initio calculations were performed at the RHF/4-31G level with the reaction pathways of the iso-merization and dehydrogenation of methylnitrene by the intrinsic reaction coordinate method. The results show that the transformation from methylnitrene to methylenimine would be very easy. This accountes for the experimental fact that one couldn' t find the methylnitrene, but only obtained the methylenimine in the pyrolysis of methyl azide. The mode-selective study reveals the reaction coordinates (IRC) of isomerization and dehydrogenation of methylnitrene are associated with the molecular deformation mode of 1191 cm-1 and the methyl group unsymmetrical stretch mode, respectively. The coupling between normal coordinates is favourable to select the reaction channel of isomerization.     

Ce3+-冠醚配合物的紫外有机电致发光

采用5d-4f跃迁的稀土Ce³⁺-冠醚配合物(Ce-二环己基并-18-冠-6,Ce-DC18C6)作为发光掺杂剂,4,4'-二(9-咔唑基)联苯(CBP)为基质,设计制备了紫外发光器件:ITO/CuPc/Ce-DC18C6:CBP/Bu-PBD/LiF/Al,首次观测到峰位于376nm的Ce³⁺离子的紫外电致发光。通过对比器件的EL谱与Ce³⁺-冠醚配合物薄膜的PL谱发现,EL光谱中有部分来自Ce³⁺配合物中的Ce³⁺离子的。这种5d-4f电子跃迁的掺杂质量分数为3%时,该UV-发光器件的最大辐射功率为13μW/cm²。     

部分相干光束通过硬边光阑的推广光束传输M2因子

给出部分相干光通过硬边光阑后的强度二阶矩的计算公式，由此可得到部分相干光通过硬边光阑后的推广光束传输M^2因子。以部分相干高斯－谢尔模型光束为例，推导出相应的M^2因子，并作了数值计算和分析讨论。     

新疆红景天红色素的提取及理化性质的研究

对用索氏提取法和乙醇浸取法提取红景天红色素进行了比较，并探讨浸取的浓度，浸取温度等因素，指出了最佳生产工艺条件，从红景天中提取的天红色素是一种安全无毒的食用色素，本文还研究了几种食品添加剂对红景天红色素稳定性的影响，并对色素的耐氧化性进行了探讨，旨在为红景天红色素的开发利用提供有实用价值的信息。     

气体放电等离子体特性测量I-V曲线不对称性的研究

利用气体放电双探针法研究了等离子体的I-V曲线中的电流I相对于电压V轴交点的不对称性,并提出2种可能的解释:一认为是由于两探针表面积不同引起的;二认为是由于探针所在处等离子体电位不等引起的.本文利用仪器的工艺误差和调换放电管电压的方法,对提出的2种可能原因分别进行验证,并指出第二种解释的合理性,并对其进行了理论分析.     

汽车行驶的时间问题

就d>2R的情形解决如下组合几何极值问题:某平原地区有一个很大的湖泊.湖泊周围有两个村庄A,B.村庄A到村庄B的直线距离为已知.一辆汽车从A村庄出发以已知匀速速度驶向村B庄.问:若这辆汽车以最短路径行驶到达B村庄至多需要多少时间?     

Solutions in Sobolev spaces of vector refinement equations with a general dilation matrix

In this paper, we present a necessary and sufficient condition for the existence of solutions in a Sobolev space W_p^k(ℝ^s) (1≤p≤∞) to a vector refinement equation with a general dilation matrix. The criterion is constructive and can be implemented. Rate of convergence of vector cascade algorithms in a Sobolev space W_p^k(ℝ^s) will be investigated. When the dilation matrix is isotropic, a characterization will be given for the L_p (1≤p≤∞) critical smoothness exponent of a refinable function vector without the assumption of stability on the refinable function vector. As a consequence, we show that if a compactly supported function vector φ∈L_p(ℝ^s) (φ∈C(ℝ^s) when p=∞) satisfies a refinement equation with a finitely supported matrix mask, then all the components of φ must belong to a Lipschitz space Lip(ν,L_p(ℝ^s)) for some ν>0. This paper generalizes the results in R.Q. Jia, K.S. Lau and D.X. Zhou (J. Fourier Anal. Appl. 7 (2001) 143–167) in the univariate setting to the multivariate setting. Dedicated to Professor Charles A. Micchelli on the occasion of his 60th birthday Mathematics subject classifications (2000) 42C20, 41A25, 39B12. Research was supported in part by the Natural Sciences and Engineering Research Council of Canada (NSERC Canada) under Grant G121210654.     

自组装有机分子薄膜的可逆超高密度信息存储

信息技术的迅速发展对信息存储密度提出了越来越高的要求，采用自组装方法研究了有机分子4’-氰基-2，6-二甲基-4-羟基偶氮苯（4’cyano-2，6-dimethyl-4-hydroxy azobenzene）的成膜特性．通过在扫描隧道显微镜的针尖和基底之间加脉冲电压在薄膜上进行信息点的写入，得到了直径为1．8nm的信息点，并分析了信息点形成的机理．