Synthesis and Study of Second-order Nonlinear Optical Properties of 3-Substituted-6- (substituted-phenylazo) coumarins

It has attracted a lot of attentions to synthesize and investigate the behaviors of organic second-order nonlinear optical (NLO) materials. [1,2] We have ever reported that acridine derivatives ,[3] 4-substituted-benzylideneoxazol-5(4H)-one[4] and 4,4′-di-styryl-biphenyl derivatives[5] possess good second-order NLO properties. Coumarin derivatives are good organic optical materials and azobenzene derivatives possess a higher second-order nonlinear polarization values, however, there are few reports about the study on the synthetic method, optical behavior, especially,second-order NLO properties of 3-substitued-6-(substituted-phenylazo) coumarin derivatives. Therefore, a series of the following compounds were prepared in order to investigate their NLO behavior.     

Investigation on Concentrated Ⅴ（Ⅳ）/Ⅴ（Ⅴ） Redox Reaction by Rotating Disc Voltammetry

The kinetic characteristics of the concentrated Ⅴ（Ⅳ）/Ⅴ（Ⅴ） couple have been studied at a glassy carbon electrode in sulfuric acid using rotating-disc electrode and cyclic voltammetry. The kinetics of the Ⅴ（Ⅳ）/Ⅴ（Ⅴ） redox couple reaction was found to be electrochemically quasi-reversible with the slower kinetics for the Ⅴ（Ⅴ） reduction than that for the Ⅴ（Ⅳ） oxidation. And, dependence of diffusion coefficients and kinetic parameters of Ⅴ（Ⅳ） species on the Ⅴ（Ⅳ） and H2SO4 concentration was investigated. It is shown that the concentration of active species Ⅴ（Ⅳ） should be over 1 mol·L^-1 for the redox flow battery application. Further, with increasing the Ⅴ（Ⅳ） and H2SO4 concentration, the diffusion coefficients of Ⅴ（Ⅳ） were gradually reduced whereas its kinetics was improved considerably, especially in the case of Ⅴ（Ⅳ） and H2SO4 up to 2 and 4 mol·L^-1.     

Electrophoretic deposition of nickel, iron and aluminum nanoparticles on carbon fibers

The electrophoretic deposition (EPD) of nickel (Ni), iron (Fe) and aluminum (Al) nanoparticles fabricated by an active hydrogen plasma evaporation method on the surface of carbon fibers was investigated, which will allow the obtained composites to be applied as practical catalysts or electrodes. SEM observations show that the Ni nanoparticles can build up a thick EPD coating with some cracks on the surface of carbon fibers, and the analyses of X-ray diffraction (XRD) and BET specific surface area indicate that fine particles from the as-received Ni powders were finally deposited after the EPD process without crystal growth. The surface oxidation of Fe and Al nanoparticles takes serious effect on the EPD process and the morphology of the as-prepared coatings.     

中子产额活化测量法中γ γ符合探测效率的模拟计算

 为了估计聚变中子产额Cu活化测量法中加速器中子源刻度与实际测量中几何条件不一致对测量结果的影响，通过对MCNP进行二次开发，用蒙特卡罗方法计算了这两种情况下有角关联的γ γ符合探测效率，通过与刻度实验结果比较，验证了计算结果的正确性，得出了几何条件的差别引起探测效率的增加小于3%的结论。     

激光推进冲量耦合系数的测量方法

 激光推进冲量耦合系数是激光推进的重要参数，反映激光能量转化为动能的能力。提出了水平双线支撑激光推进试验方法，推导了水平双线支撑激光推进时光船的运动方程和测量方程；通过高速相机测量位移，利用卡尔曼滤波计算速度的方法；解决了激光脉冲瞬间作用时速度随机起伏大和计算困难的问题。为水平激光推进冲量耦合系数的计算，提供了工程测量和计算方法。     

高气压下微晶硅薄膜的生长及微结构研究

通过射频等离子体增强化学气相沉积,在高气压条件下制备了微晶硅薄膜,并用拉曼光谱仪(Ram an)、扫描电镜(SEM)研究了微晶硅薄膜的微观结构。发现沉积速率在5Torr左右出现极大值,薄膜的晶化率随着沉积气压的升高而降低,薄膜表面的晶粒或团簇随着沉积气压的下降而增大,薄膜的粗糙度随着沉积气压的升高而降低。     

锌离子掺杂HA晶须形成过程及其热稳定性能研究

锌离子掺杂羟基磷灰石(HA)不仅影响HA的晶体结构和微观形貌,还影响材料的热稳定性和生物学性能.本文采用水热合成法制备了锌离子掺杂HA(Zn-HA)晶须,通过XRD、FTIR和SEM等测定和研究了Zn-HA的晶体结构、形成过程、结晶形貌和热稳定性.结果表明,Zn2+掺杂量<5;时,可获得单相Zn-HA晶须;当Zn2+掺量为5;时,合成产物中开始有少量的CaZn2(PO4)2·2H2O杂质相生成;当增加至8;时,开始有明显的Zn(PO3)2杂质峰出现.随水热合成温度的增加,溶液的OH-不断释放,伴随HA晶核的形成和生长,还有极少量的CaZn2(PO4)2·2H2O和Ca3(PO4)2杂质相,并通过溶解再沉淀生成Zn-HA.当Zn2+的掺杂量在0～8;时,随着Zn2+掺杂量的增加,样品的结晶度逐渐降低,晶格常数a值有所增加,c值基本不变.Zn2+掺杂HA晶须在>800℃的环境下热处理,Zn2+掺杂量的增加和热处理温度的改变都会促进HA晶须向β-TCP转化,形成双相磷酸钙.     

Synthesis of New Naphthaline-type Chromophores with Strong Green-emitting or the Blue-emitting in β-Cyclodextrin

Three new naphthaline-type chromophores end-capped with different (p-substituted amino) styryl groups on the both sides (named as BPASN, BHMASN and BMASN) have been synthesized. Under excitation of 380nm, strong green light-emitting locating at 517nm with the fluorescence quantum yield of 0.88 in CH2Cl2 has been obtained.In the presence of β-cyclodextrin (β-CD), strong blue-emitting at 456nm in DMF was also recorded.     

超高密度电学信息存储研究进展

21世纪是经济信息化、信息数字化的高科技时代，信息的爆炸式增长及电子器件持续微型化的要求需要小断研究和开发更高仔储密度、更快响应速度、更长存储寿命及可反复读、写的材料和器件。在纳米／分子尺度上实现存储功能的超高密度信息存储已成为当前信息领域一个倍受关注的研究热点。本文从存储材料和技术角度介绍了基于电学双稳态的超高密度信息存储最新研究进展。     

非对易torus上的新孤子解

利用在非对易可积torus(环)上的算子都有约化矩阵这一特点, 孤子解的求解问题可以化为求满足代数方程Q(M)=0的有限维矩阵解问题. 本文研究了当 矩阵M不可对角化时的情形, 分析这种情形,得到当势函数V(\phi)具有三阶以上的极值点时, 有限维矩阵方程V′(M)=0存在不可对角化的矩阵解. 研究了这种解的一般形式, 并通过kq表象, 构造了非对易整环上以上述矩阵解为约化矩阵 的新孤子解. 根据这种构造方法, 可以得到非对易orbifold上的新孤子解.