单A直和子空间

引入单直和子空间的概念,证明了线性空间可唯一分解为单直和子空间的直和,并且给出了计算方法.     

SiO2包覆铕(Ⅲ)配合物的荧光纳米粒子合成与性质

以前驱物pAB-DTPAA-APTEOS、正硅酸乙酯(TEOS)和三氯化铕(EuCl3)等为原料,采用油包水(W/O)的反相微乳液法,在正硅酸乙酯(TEOS)和3-氨丙基三乙氧基硅烷(APTEOS)的共同水解下,制备出新型的SiO2包覆铕配合物荧光纳米粒子Eu-pAB-DTPAA-AP-SiO2。运用TEM、IR、UV-Vis、荧光光谱等技术对荧光纳米粒子进行了表征。TEM结果表明:包覆体呈球形,分散均匀,平均粒径为40nm。纳米粒子与配体、前驱物的紫外吸收谱相比较,峰位发生了一定的红移,表明通过反相微乳液法得到的固体粉末与EuCl3反应后,已经生成配合物Eu-pAB-DTPAA-AP-SiO2。红外光谱研究表明,在801cm-1出现νSi—C的伸缩振动峰,471cm-1处出现νEu—O的伸缩振动峰。由此证实Eu-pAB-DTPAA-AP-SiO2配合物的存在。荧光光谱分析表明,纳米粒子Eu-pAB-DTPAA-AP-SiO2表现出较好的荧光性能,位于592,615,689nm的发射峰分别归属于Eu3 离子的5D0→7F1、5D0→7F2和5D0→7F4跃迁,其中最强峰615nm属于Eu3 的特征跃迁发射。作为一种新型的荧光试剂,该纳米粒子具有粒径小,亲水性强,荧光强度大,且表面的氨基能方便地与生物分子偶联,故可作为优良的时间分辨荧光标记物用于各种高灵敏生物检测技术中。     

埋地热油管道正常运行的数值模拟研究

对高凝原油管道输送的水力热力问题进行分析研究,掌握管线运行规律,保证管线安全经济运行有着重要意义.本文建立了埋地热油管道正常运行的数学模型,采用非结构化网格和有限容积法对该问题进行了研究,计算结果与实验测量值吻合良好.     

瞬态平面热源法测量硅胶混合吸附剂导热系数

利用瞬态平面热源法对制冷吸附剂的导热性能进行测试.所研究的吸附剂包括:硅胶颗粒、硅胶-水、硅胶-氯化钙混合多孔介质、硅胶-氯化钙-膨胀石墨固化混合吸附剂.实验结果表明:硅胶颗粒的孔隙率对其导热性能的影响比较大;此外,当硅胶的吸水量增大时,导热系数呈线性增大.当氯化钙质量分数大于0.2时,混合多孔介质的导热系数随氯化钙质量分数的增大而显著增加.利用膨胀石墨可以明显地提高硅胶颗粒的导热系数,固化的混合吸附剂的导热系数可以达到2.942W/mK,相对于硅胶颗粒的导热系数提高约30倍.     

薄层色谱-紫外可见分光光度法测定食品中的苏丹红Ⅰ号

建立了测定食品中苏丹红Ⅰ号新方法:薄层色谱-紫外可见分光光度法.方法的线性回归方程为:A=0.00583 0.15105ρ,在0.50～10.0 μg/mL之间苏丹红Ⅰ号的浓度与吸光度之间呈线性关系,相关系数R=0.9992,检出限为0.05 μg/mL.测定结果与国家标准HPLC法对照,令人满意.可用于食品中苏丹红Ⅰ号的测定.     

α-氨基膦酸酯的合成方法研究进展

从Lewis催化剂合成法、非Lewis催化剂合成法、绿色合成法3个方面综述了近年来国内外在α-氨基膦酸酯合成研究领域的最新进展.参考文献33篇.     

Extended Riccati Equation Rational Expansion Method and Its Application to Nonlinear Stochastic Evolution Equations

In this work, by means of a new more general ansatz and the symbolic computation system Maple, we extend the Riccati equation rational expansion method [Chaos, Solitons & Fractals 25 (2005) 1019] to uniformly construct a series of stochastic nontravelling wave solutions for nonlinear stochastic evolution equation. To illustrate the effectiveness of our method, we take the stochastic mKdV equation as an example, and successfully construct some new and more general solutions including a series of rational formal nontraveling wave and coefficient functions' soliton-like solutions and trigonometric-like function solutions. The method can also be applied to solve other nonlinear stochastic evolution equation or equations.     

Noether-Mei Symmetry of Mechanical System in Phase Space

In this paper, a new kind of symmetry and its conserved quantities of a mechanical system in phase space are studied. The definition of this new symmetry, i.e., a Noether-Mei symmetry, is presented, and the criterion of this symmetry is also given. The Noether conserved quantity and the Mei conserved quantity deduced from the Noether-Mei symmetry of the system are obtained. Finally, two examples are given to illustrate the application of the results.     

Study Hankel Transforms and Properties of Bessel Function via Entangled State Representation Transformation in Quantum Mechanics

In Phys. Lett. A 313 (2003) 343 we have found that the self-reciprocal Hankel transformation (HT) is embodied in quantum mechanics by a transform between two entangled state representations of continuum variables. In this work we study Hankel transforms and properties of Bessel function via entangled state representations' transformation in quantum mechanics.     

Secure Direct Communication Using Ensembles with the Same Compressed Density Matrix

In this paper, a quantum secure direct communication protocol using ensembles with the same density matrix is proposed. The two communication parties can realize the message transmission using this method through a quantum channel, each bit of information can be transmitted using an ensemble and read out through global measurement.The eavesdropping behavior can be detected through the channel diagnoses.